1) In lecture #9, it was noted that about 20% of the O* atoms produced from ozone photolysis will form OH radicals. Verify that conclusion based on the following analysis. a) Write an expression for the yield of OH radicals from the two O* reactions; k1 O* + M → 0 + M O* + H2O → 2 OH where the yield will be the rate of OH radical production divided by the total O* loss rate due to the two reactions. b) At a pressure of 1 atmosphere and 50% RH (which corresponds to a mixing ratio of 1%), calculate the OH yield given that k2~ 10×k1.

Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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1) In lecture #9, it was noted that about 20% of the O* atoms produced from ozone photolysis will form
OH radicals. Verify that conclusion based on the following analysis.
a) Write an expression for the yield of OH radicals from the two O* reactions;
k1
O* + M → 0 + M
k2
O* + H2O
2 OH
where the yield will be the rate of OH radical production divided by the total O* loss rate due to
the two reactions.
b) At a pressure of 1 atmosphere and 50% RH (which corresponds to a mixing ratio of 1%),
calculate the OH yield given that k2 - 10×k1.
Transcribed Image Text:1) In lecture #9, it was noted that about 20% of the O* atoms produced from ozone photolysis will form OH radicals. Verify that conclusion based on the following analysis. a) Write an expression for the yield of OH radicals from the two O* reactions; k1 O* + M → 0 + M k2 O* + H2O 2 OH where the yield will be the rate of OH radical production divided by the total O* loss rate due to the two reactions. b) At a pressure of 1 atmosphere and 50% RH (which corresponds to a mixing ratio of 1%), calculate the OH yield given that k2 - 10×k1.
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