In the space provided, draw the structure of valine (val) at each of the following pH values. Valine has a pl of 5.97. a) pH = 4.34 CH3 CH-CH, H2N-C-COOH Valine (Val) b) pH = 5.97 %3D

Chemistry: Principles and Practice
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Chapter15: Solutions Of Acids And Bases
Section: Chapter Questions
Problem 15.135QE
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### Understanding the Structure of Valine at Different pH Levels

**Valine** is an essential amino acid with a pI (isoelectric point) of 5.97. The structure of valine will vary depending on the pH of the environment. Below are the structures of valine at the given pH levels.

#### Structure of Valine

The chemical structure of valine (Val) is shown below:
```
      CH3
       |
H2N—C—CH
   |     |
   H   CH3
       |
   COOH
```

#### a) pH = 4.34
At a pH below the isoelectric point (pI = 5.97), valine will tend to gain protons (H+) due to the acidic environment. The amino group (NH2) will become positively charged (NH3+).

#### b) pH = 5.97
At a pH equal to the isoelectric point, valine is in its zwitterionic form. In this state, the amino group (NH2) is protonated to NH3+, and the carboxyl group (COOH) is deprotonated to COO-.

---

### Explanation of Diagrams

The provided diagrams and structures would illustrate the specific forms of valine at the indicated pH levels:

- **pH = 4.34:** 
  Here, the valine will have the following form:
  ```
        CH3
         |
  H3N—C—CH
     |     |
     H   CH3
         |
     COOH
  ```

- **pH = 5.97:**
  Here, the valine will have the following zwitterionic form:
  ```
        CH3
         |
  H3N—C—CH
     |     |
     H   CH3
         |
     COO-
  ```

By understanding these structures, students can better grasp how amino acids behave in different pH environments, which is crucial for their roles in biological systems and protein structures.
Transcribed Image Text:### Understanding the Structure of Valine at Different pH Levels **Valine** is an essential amino acid with a pI (isoelectric point) of 5.97. The structure of valine will vary depending on the pH of the environment. Below are the structures of valine at the given pH levels. #### Structure of Valine The chemical structure of valine (Val) is shown below: ``` CH3 | H2N—C—CH | | H CH3 | COOH ``` #### a) pH = 4.34 At a pH below the isoelectric point (pI = 5.97), valine will tend to gain protons (H+) due to the acidic environment. The amino group (NH2) will become positively charged (NH3+). #### b) pH = 5.97 At a pH equal to the isoelectric point, valine is in its zwitterionic form. In this state, the amino group (NH2) is protonated to NH3+, and the carboxyl group (COOH) is deprotonated to COO-. --- ### Explanation of Diagrams The provided diagrams and structures would illustrate the specific forms of valine at the indicated pH levels: - **pH = 4.34:** Here, the valine will have the following form: ``` CH3 | H3N—C—CH | | H CH3 | COOH ``` - **pH = 5.97:** Here, the valine will have the following zwitterionic form: ``` CH3 | H3N—C—CH | | H CH3 | COO- ``` By understanding these structures, students can better grasp how amino acids behave in different pH environments, which is crucial for their roles in biological systems and protein structures.
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