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02. 03. 04. CH3 Li OH H3C CH3 CH3 Nucleophilic addition to the ketone; note a stereogenic center is created; the product is necessarily racemic. OH OCH 3 PhMgBr Ph Ph OCH3 OCH3 Grignard addition to the ester FG (the ether FG does not react); addition is always twice with esters. 04. CO₂H i) SOCI₂ ii) (CH3CH2)2NH 05. H3C CH3 06. H+ H3CO LiAlH4 2

02. 03. 04. CH3 Li OH H3C CH3 CH3 Nucleophilic addition to the ketone; note a stereogenic center is created; the product is necessarily racemic. OH OCH 3 PhMgBr Ph Ph OCH3 OCH3 Grignard addition to the ester FG (the ether FG does not react); addition is always twice with esters. 04. CO₂H i) SOCI₂ ii) (CH3CH2)2NH 05. H3C CH3 06. H+ H3CO LiAlH4 2

Introductory Chemistry: A Foundation
Introductory Chemistry: A Foundation
9th Edition
ISBN:9781337399425
Author:Steven S. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Donald J. DeCoste
Chapter15: Solutions
Section: Chapter Questions
Problem 10CR
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02. 03. 04. CH3 Li OH H3C CH3 CH3 Nucleophilic addition to the ketone; note a stereogenic center is created; the product is necessarily racemic. OH OCH 3 PhMgBr Ph Ph OCH3 OCH3 Grignard addition to the ester FG (the ether FG does not react); addition is always twice with esters.
Transcribed Image Text:02. 03. 04. CH3 Li OH H3C CH3 CH3 Nucleophilic addition to the ketone; note a stereogenic center is created; the product is necessarily racemic. OH OCH 3 PhMgBr Ph Ph OCH3 OCH3 Grignard addition to the ester FG (the ether FG does not react); addition is always twice with esters.
04. CO₂H i) SOCI₂ ii) (CH3CH2)2NH 05. H3C CH3 06. H+ H3CO LiAlH4 2
Transcribed Image Text:04. CO₂H i) SOCI₂ ii) (CH3CH2)2NH 05. H3C CH3 06. H+ H3CO LiAlH4 2
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