. A mixture of CO2 and water vapor is at 100 kPa, 200°C. As the mixture is cooled at a constant pressure, water vapor begins to condense when the temperature reaches 70°C. Determine (a) the mole fraction and (b) the mass fraction of CO2 CO2 in the mixture. Model: Ideal Gas Properties of Nitrogen (N2)" for the value of molar specific enthalpy at temperature of 277.778 K. T 270 K 277.778 K 280 K h -820 kJ/kmol h -528 kJ/kmol The molar specific enthalpy of nitrogen at 277.778 K is -592.88 kJ/kmol. DON'T GIVE AI SOLUTION, FOLLOW THE HANDWRITTEN FORMAT.
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- (7) Combustion of CH4 and H₂. For 100 g mol of a gas mixture of 75 mol % CH4 and 25 mol % H₂, calculate the total heat of combustion of the mixture at 298 K and 101.32 kPa, assuming that combustion is complete.the ionic compound L2O3(s) is the ionic compound formed from oxygen and a metal with the form L(s) at 1.00 bar and 298 K. (a) Draw the Lewis structure for L2O3. Assume that all the valence electrons from L are required. (b) Use the following information to determine the enthalpy of formation for L2O3(s). Express your answer in kJZ(mol L2O3(s)). Lattice energy for L2O3(s) = -14836 kJ mol1 AHsub for L(s) = 358 kJ mol 1 First ionization energy for L(g) = 577 kJ mol 1 Second ionization energy for L(g) = 1794 kJ mol 1 Third ionization energy for L(g) = 3820 kJ mol 1 Bond dissociation energy for O2(g) = 498 kJ mol 1 %3D First electron affinity for O = -141 kJ mol 1 Second electron affinity for O = 744 kJ mol 1F 6. A rigid vessel of volume 0.4 m^3 containing H2 at 21.25°C and a pressure of 715x10^3 Pa is connected to a second rigid vessel of volume 0.75m^3 containing Argon at 30.15°C at a pressure of 203x10^3. A valve separating the two vessels is opened and the mixed gases allowed to cool to a temperature of 12.2°C. What is the final pressure of the gas mixture in the connected vessel in atm? (1 atm = 101325 Pa) Please show all steps.
- The molar heat capacity CPm of H2(g) is described by the following equation.: CPm = 29.064 -0.8363x10-3 TIK + 20.111x10-7 (TIK)? In this equation, T is the absolute temperature in kelvin. The ratios (TIKY" ensure that Cpm has the correct dimension. Assuming ideal gas behavior, calculate q, w, AU, and AH if 2.5 moles of H2(g) is heated from 25 °C to 800 °C at a constant pressure of 1 bar. q (in J) = w (in J) = AU (in J) = AH (in J) =What is AG (in kJ) for 2 SO2(g) + O2lg) 2 SO3(g) at 700 K, under standard conditions of 1 bar partial pressure for all gases, given that K = 3.0x104 at 700 K? O0.0 -36 O-60. +36 O +60.2. Three perfect gases, all at a temperature of 25°C, are placed into a box with sides of length 1m, 2m, and 3m. There are 4 kg of carbon dioxide, 2 kg nitrogen, and 1 kg of hydrogen. Assuming the gases are allowed to mix, calculate: a) The molecular weight of the resultant mixture. b) The constant pressure specific heat of the mixture. c) The ratio of specific heats for the mixture. d) The density of the mixture. e) The pressure of the mixture.
- 3. One mole of liquid water at 100 °C is heated until the liquid is converted entirely to vapor at 100 °C and 1 atm pressure. Calculate q, w, AE and AH for each of the following. (a) The vaporization is carried out in a cylinder where the external pressure on the piston is maintained at 1 atm throughout. (b) The cylinder is first expanded against vacuum (Pext = 0) to the same volume as in part (a), and then sufficient heat is added to vaporize the liquid completely to 1 atm pressure.please answer all the following: How much energy per mole does it take to boil each of the following molecules from starting at standard state ambient temperature, 298 K. Boiling means increase temperature to the boiling point and then converting the liquid to a gas. Assume constant pressure conditions. Use Table 2C.1 to find Tboil and ΔHvap. Use Table 2C.7 to find Cpm values. a. Methanol (CH3OH) b. Ethanol (C2H5OH) c. Water (H2O) d. Which needs the largest amount of energy? What factor has the greater impact on this value?Assume you are interested in exploring the use of ammonium nitrate (NH4NO3) as the active ingredient in an inexpensive home-made cold pack. You decide that a practical cold pack should be able to depress the temperature of 1 kg of human muscle tissue by 5 oC. Now you need to know the amount of NH4NO3 required to achieve this. Ammonium nitrate is a highly water soluble solid. You believe the enthalpy of dissolution for NH4NO3 must be determined. To this end, you add 2.339 g of NH4NO3 to 99.7 mL of water at 23.7 °C in a constant-pressure calorimeter and close the calorimeter. The temperature of the water decreases to a minimum of 21.9 °C 1) The specific heat of human muscle tissue (smuscle) is 3.47 kJ/kg oC. Given this value, how many grams of ammonium nitrate (NH4NO3) is required to depress the temperature of 1.00 kg of human muscle by 5.00 oC? Please remember, show all work in a legible, highly organized manner
- Assume you are interested in exploring the use of ammonium nitrate (NH4NO3) as the active ingredient in an inexpensive home-made cold pack. You decide that a practical cold pack should be able to depress the temperature of 1 kg of human muscle tissue by 5 oC. Now you need to know the amount of NH4NO3 required to achieve this. Ammonium nitrate is a highly water soluble solid. You believe the enthalpy of dissolution for NH4NO3 must be determined. To this end, you add 2.339 g of NH4NO3 to 99.7 mL of water at 23.7 °C in a constant-pressure calorimeter and close the calorimeter. The temperature of the water decreases to a minimum of 21.9 °C. 1a. Assume the density and specific heat of water is 1.00 g/mL and 4.184 J/g °C, respectively. Using the data above, determine the for ammonium nitrate in water. Assume the heat capacity of the calorimeter is negligible.Write the remarks about the KP of ideal-gas mixtures ?Calculate the value of cp at 298 K and 1 atm pressure predicted for Cl, and NO, by the classical equipartition theorem. (Enter your answers to at least two decimal places.) Cp(Cl)) = J mol 1 K1 Cp(NO,) = J mol K1 The actual heat capacities of C and NO, are 33.91 and 36.97 J molK, respectively. Calculate the fraction (expressed as a percentage) of the measured value that arises from vibrational motions. vibrational contribution to cp(Cl,) = vibrational contribution to cp(NO,) =