(c) Consider the following electrochemical cell: Zn (s) | ZnCl2 | Hg2Cl2 (s) Hg(l) for which the cell reaction is Hg2Cl2 (s) + Zn(s) → 2 Hg(l) + 2 Cl(aq) + Zn²+(aq) Given that Eº (Zn2+; Zn) = -0.8044 V, E (Hg2Cl2, Hg) = +0.3577 V, and that the emf is E = 1.4055 V. (i) Determine AG, AG and the equilibrium constant, K for the cell reaction. (ii) Interpret the value for ArG based on question (i) above

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Chapter19: Electrochemistry
Section: Chapter Questions
Problem 19.140QP
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(c)
Consider the following electrochemical cell:
Zn (s) | ZnCl2 | Hg2Cl2 (s) Hg(l)
for which the cell reaction is
Hg2Cl2 (s) + Zn(s) → 2 Hg(l) + 2 Cl(aq) + Zn²+(aq)
Given that Eº (Zn2+; Zn) = -0.8044 V,
E (Hg2Cl2, Hg) = +0.3577 V,
and that the emf is E = 1.4055 V.
(i) Determine AG, AG and the equilibrium constant, K for the cell reaction.
(ii) Interpret the value for ArG based on question (i) above
Transcribed Image Text:(c) Consider the following electrochemical cell: Zn (s) | ZnCl2 | Hg2Cl2 (s) Hg(l) for which the cell reaction is Hg2Cl2 (s) + Zn(s) → 2 Hg(l) + 2 Cl(aq) + Zn²+(aq) Given that Eº (Zn2+; Zn) = -0.8044 V, E (Hg2Cl2, Hg) = +0.3577 V, and that the emf is E = 1.4055 V. (i) Determine AG, AG and the equilibrium constant, K for the cell reaction. (ii) Interpret the value for ArG based on question (i) above
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