CHEM 1161-S22-Final Exam Form A

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CHEM 1161 Spring 2022 Final Exam D. Matthew Page 1 of 12 CHEM 1161 Final Exam Thursday, May 5, 2022 Name: ____________________________ ***Enter Section # on here and bubble sheet!*** WůĂĐĞ ĂŶ ͚y͛ in the box for your recitation: (Even though I am not handing them back, I still want this info.) Leticia: Dr. Dan: Patrick: Ben: [ ] M 4:35 pm [ ] Tu 11:45 am [ ] W 3:25 pm [ ] Th 9:15 am [ ] W 3:25 pm [ ] Tu 1:35 pm [ ] W 4:35 pm [ ] W 4:35 pm This is a closed book/notes exam. You have 120 minutes to complete it. While you can use a calculator (graphing calculators are acceptable) on the exam, you are not allowed to use a calculator with internet access or one on your phone, computer, etc. Note that there are 10 pages with questions on them, so be sure to look at them all. For all non-multiple-choice questions, you must show all work for full credit ͘ /Ĩ LJŽƵ ŚĂǀĞ ĂŶLJ ƋƵĞƐƚŝŽŶƐ ĂƐ LJŽƵ ŐŽ ƚŚƌŽƵŐŚ ƚŚĞ ĞdžĂŵ͕ ƉůĞĂƐĞ ĚŽŶ͛ƚ ŚĞƐŝƚĂƚĞ to ask. Lastly, there is a sheet of potentially useful information along with a periodic table at the end of the exam that you are welcome to tear off, if needed. Extra paper is also available upon request. Good luck!!! Problem(s) Possible Points Your Score 1-27 108 28 18 29 15 30 4 31 8 32 5 (Bonus) TOTAL 150 Form: A Sect:
CHEM 1161 Spring 2022 Final Exam D. Matthew Page 2 of 12 Answer each of the following multiple-choice questions on your bubble sheet . I recommend ĐŝƌĐůŝŶŐ LJŽƵƌ ĂŶƐǁĞƌƐ ŚĞƌĞ͕ ƚŽŽ͕ ũƵƐƚ ĂƐ Ă ďĂĐŬƵƉ͕ ďƵƚ ŶŽƚĞ ƚŚĂƚ / ǁŽŶ͛ƚ ďĞ ŐƌĂĚŝŶŐ ƚŚĞ ǁŽƌŬ ŚĞƌĞ͘ Note: Each multiple-choice question is worth 4 points . 1. Which of these molecules has only single bonds? a. ܥܱ b. ܥܱ c. ܱܨ d. ܱܵ e. ܪܥܰ 2. Copper was the first metal to be produced from its ore because it is the easiest to smelt, that is, to refine by heating in the presence of carbon. The ore was likely malachite, which has the formula ܥݑ ሺܱܪሻ ܥܱ . What is the mass percent of copper in malachite? a. 28.7% b. 74.6% c. 40.3% d. 45.2% e. 57.5% 3. The empirical formula for buckminsterfullerene is ܥ (yes, that is correctly written), and its molar mass is 720.6 g/mol. What is its molecular formula? a. ܥ b. ܥ ଺଴ c. ܥ ଻ଶ଴ d. ܥ ଵଶ e. ܥ ଻ଶ 4. What is the chemical name of ܱܵ ? a. sulfate b. sulfur trioxide c. sulfite d. sulfur oxide e. sulfur(III) oxide 5. A solution that contains a weak acid and its conjugate base in roughly equal ĐŽŶĐĞŶƚƌĂƚŝŽŶƐ ŝƐ͙ a. ͙Ă ďƵĨĨĞƌ͘ b. ͙ŶĞƵƚƌĂů͘ c. ͙Ă ŚĞƚĞƌŽŐĞŶĞŽƵƐ ŵŝdžƚƵƌĞ͘ d. ͙Ă ŚĂůĨ -acid solution. e. ͙ŶĞŝƚŚĞƌ ĂĐŝĚŝĐ ŶŽƌ basic.
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CHEM 1161 Spring 2022 Final Exam D. Matthew Page 3 of 12 6. Which of these compounds has the highest boiling point? a. ܥ݈ b. ܤݎ c. ܫ d. ܣݐ e. ܨ 7. Mercury lamps emit blue light with ߣ ൌ Ͷ͵͸ ݊݉ . What is the energy of these photons in joules? Note: ͳ ݊݉ ൌ ͳͲ ିଽ ݉ a. ͶǤͷ͸ ൈ ͳͲ ିଵଽ ܬ b. ͶǤͷ͸ ൈ ͳͲ ିଶ଼ ܬ c. ʹǤͳͻ ൈ ͳͲ ିଵ଼ ܬ d. ʹǤͳͻ ൈ ͳͲ ିଵ଼ ܬ e. ͳǤͻ͹ ൈ ͳͲ ସସ ܬ 8. Fill in the blanks: A ܥݏ ହହ ଵଷଷ ion has _____ protons, _____ neutrons, and _____ electrons. a. 54; 133; 55 b. 55; 133; 54 c. 54; 78; 55 d. 55; 78; 54 e. 55; 78; 55 9. What is the correct condensed electron configuration for a neutral germanium (Ge) atom in its ground state? a. ሾܣݎሿͶݏ ͵݀ Ͷ݌ b. ሾܣݎሿͶݏ ͵݀ ଵ଴ Ͷ݌ c. ሾܣݎሿ͵݀ ଵ଴ Ͷ݌ d. ሾܣݎሿͶݏ ͵݀ Ͷ݌ e. ሾܣݎሿͶݏ ͵݀ ଵ଴ Ͷ݌ 10. What is the hybridization of both central carbon atoms in ܥ ܪ ? a. ݏ݌ b. ݏ݌ c. ݏ ݌ d. ݏ݌ e. ݏ݌
CHEM 1161 Spring 2022 Final Exam D. Matthew Page 4 of 12 11. Nitrite ( ܱܰ ି ) is an important nutrient in the euphotic zone in the ocean. Which set of resonance structures best describes the bonding in this ion? If none are correct, choose answer e. 12. Radio waves have very long wavelengths while UV waves have much shorter wavelengths. What can you tell about the frequencies of radio and UV waves? a. The frequency of radio waves is much lower than the frequency of UV waves. b. If you multiply the frequency of either wave by the speed of light, you can calculate wavelength. c. They have the same frequencies. d. Wavelength and frequency are unrelated. e. The frequency of UV waves is much lower than the frequency of radio waves. 13. Calculate the final concentration of a ܭܱܰ solution that was prepared by adding ʹͷǤ͸ ݉ܮ of a ͳǤͲʹ ܯ ܭܱܰ solution to ͶͺǤ͹ ݉ܮ of a ͲǤͺ͹ͷ ܯ ܭܱܰ solution. a. 0.925 M b. 0.654 M c. 0.778 M d. 0.996 M e. 1.09 M 14. What is the correct name of ܪ ܱܵ ? a. dihydrogen sulfurtrioxide acid b. hydrosulfuric acid c. sulfurous acid d. sulfuric acid e. hydrosulfurous acid 15. Which statement about a chemical reaction at equilibrium is true? a. Only the reverse reaction stops. b. The rate constants for the forward and reverse reactions are equal. c. Both the forward and reverse reactions stop. d. The rates of the forward and reverse reactions are equal. e. Only the forward reaction stops.
CHEM 1161 Spring 2022 Final Exam D. Matthew Page 5 of 12 16. Potassium perchlorate ሺܭܥ݈ܱ oxidizes sucrose ሺܥ ଵଶ ܪ ଶଶ ܱ ଵଵ according to the unbalanced reaction below. What are the coefficients in the balanced reaction in the order in which it is written? ̴̴̴ ܭܥ݈ܱ ሺݏሻ ൅ ̴̴̴ ܥ ଵଶ ܪ ଶଶ ܱ ଵଵ ሺݏሻ ՜ ̴̴̴ ܭܥ݈ሺݏሻ ൅ ̴̴̴ ܥܱ ሺ݃ሻ ൅ ̴̴̴ ܪ ܱሺκሻ a. 4, 1, 4, 12, 22 b. 2, 1, 2, 12, 11 c. 8, 2, 8, 12, 11 d. 8, 1, 8, 12, 11 e. 4, 1, 4, 12, 11 17. What is the chemical formula of the compound formed by ions of the elements magnesium and nitrogen? a. ܯ݃ ܰ b. ܯ݃ ܰ c. ܯ݃ܰ d. ܯ݃ܰ e. ܯ݃ ܰ 18. Fill in the blanks: In the following aqueous reaction, the acid reactant is ________ and its conjugate base is ________. ܥܪ ܰܪ ሺܽݍሻ ൅ ܪܱܵ ି ሺܽݍሻ ֖ ܥܪ ܰܪ ሺܽݍሻ ൅ ܱܵ ଶି ሺܽݍሻ a. ܥܪ ܰܪ ; ܱܵ ଶି b. ܪܱܵ ି ; ܱܵ ଶି c. ܪܱܵ ି Ǣ ܪ ܱ d. ܥܪ ܰܪ ; ܥܪ ܰܪ e. ܪܱܵ ି ; ܥܪ ܰܪ 19. Nitrogen dioxide undergoes thermal decomposition according to the second-order reaction below. When ͲǤͷͲͲ ܯ ܱܰ is allowed to react for ͻͲǤͲ seconds, its concentration falls to ͲǤͲͳͻ͸ ܯ . What is the rate constant for this reaction? ʹ ܱܰ ሺ݃ሻ ՜ ʹ ܱܰሺ݃ሻ ൅ ܱ ሺ݃ሻ a. ͲǤͲͲͷ͵Ͷ ܯ ିଵ ݏ ିଵ b. ͲǤͲʹͳͶ ܯ ିଵ ݏ ିଵ c. ͲǤͷͶͷ ܯ ିଵ ݏ ିଵ d. ͲǤͷͺͻ ܯ ିଵ ݏ ିଵ e. ͲǤͲʹ͵ͳ ܯ ିଵ ݏ ିଵ
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CHEM 1161 Spring 2022 Final Exam D. Matthew Page 6 of 12 20. For the equilibrium reaction shown below, ܭ ൌ ͲǤʹͶͶ at ͳͶͲͲ ܭ . ʹ ܱܰሺ݃ሻ ൅ ͵ ܪ ܱ ሺ݃ሻ ֖ ʹ ܰܪ ሺ݃ሻ ൅ Ͷ ܱ ሺ݃ሻ At a given point, the partial pressures of the gases are ܲ ேை ൌ ͲǤͲ͵ͺʹ ܽݐ݉ǡ ܲ ͲǤͲͻ͹Ͷ ܽݐ݉ǡ ܲ ேு ൌ ͲǤʹ͸Ͷ ܽݐ݉ǡ and ܲ ൌ ͲǤͳʹ͸ ܽݐ݉ . Which statement below is true ? a. Q > K, so the reaction will consume products to make more reactants. b. Q = K, so the reaction is at equilibrium. c. The value of K will increase until it is equal to Q. d. The value of K will decrease until it is equal to Q. e. Q < K, so the reaction will continue to make more products. 21. Given the following initial rate data, determine the reaction order with respect to ܫܥ݈ . Note: I am looking for just the order of ܫܥ݈ and not the entire reaction! ܪ ሺ݃ሻ ൅ ʹ ܫܥ݈ሺ݃ሻ ՜ ܫ ሺ݃ሻ ൅ ʹ ܪܥ݈ሺ݃ሻ Run ሾࡴ ሿ ሺࡹሻ ሾࡵ࡯࢒ሿ ሺࡹሻ Rate ( ࡹȀ࢙ ) 1 ͲǤʹͷͲ ͲǤ͵ʹͷ ͳǤ͵Ͷ 2 ͲǤʹͷͲ ͲǤͲͺͳ ͲǤ͵͵ͳ 3 ͲǤͲͷͲ ͲǤ͵ʹͷ ͲǤʹ͸͸ a. First b. Three-halves c. Second d. Third e. One-half 22. Determine ȟܩ ௥௫௡ for the reaction below using the provided thermodynamic data. ܥ ܪ ଵ଴ ሺκሻ ൅ ͳ͵ ʹ ܱ ሺ݃ሻ ՜ Ͷ ܥܱ ሺ݃ሻ ൅ ͷ ܪ ܱሺ݃ሻ Substance ઢࡳ ሺ࢑ࡶȀ࢓࢕࢒ሻ ܥ ܪ ଵ଴ ሺκሻ െͳͷǤͲ ܥܱ ሺ݃ሻ െ͵ͻͶǤͶ ܪ ܱሺ݃ሻ െʹʹͺǤͷ͹ a. െ͸ͲͺǤͲ ݇ܬȀ݉݋݈ b. െͳ͹ͻͳǤͲ ݇ܬȀ݉݋݈ c. െʹ͹͵ͷǤͷ ݇ܬȀ݉݋݈ d. ൅͸ͲͺǤͲ ݇ܬȀ݉݋݈ e. െʹ͹ͲͷǤͷ ݇ܬȀ݉݋݈
CHEM 1161 Spring 2022 Final Exam D. Matthew Page 7 of 12 23. In the following reaction, which species is oxidized? ܥݑሺݏሻ ൅ ܨܱ݁ܵ ሺܽݍሻ ՜ ܨ݁ሺݏሻ ൅ ܥݑܱܵ ሺܽݍሻ a. ܵ b. ܥݑ c. ܱ d. ܨ݁ e. None, this is not a redox reaction. 24. Fill in the blanks: The electron geometry of the molecule ܣݏܪ is ________, and its molecular geometry is ________. a. tetrahedral; tetrahedral b. trigonal pyramidal; trigonal pyramidal c. tetrahedral; trigonal pyramidal d. tetrahedral; trigonal planar e. trigonal planar; trigonal planar 25. Which of the following elements has the smallest neutral atomic radius? a. ܥ݈ b. ܴܾ c. ܥܽ d. ܰܽ e. ܣ݈ 26. Which set of quantum numbers could be correct for the highest energy electron in a ground state neutral atom of tin, ܵ݊ ? a. ݊ ൌ ͷǡ κ ൌ Ͳǡ ݉ κ ൌ Ͳǡ ݉ ൌ െͳȀʹ b. ݊ ൌ Ͷǡ κ ൌ Ͳǡ ݉ κ ൌ Ͳǡ ݉ ൌ ൅ͳȀʹ c. ݊ ൌ ͷǡ κ ൌ ͳǡ ݉ κ ൌ Ͳǡ ݉ ൌ െͳȀʹ d. ݊ ൌ ͷǡ κ ൌ ʹǡ ݉ κ ൌ Ͳǡ ݉ ൌ ൅ͳȀʹ e. ݊ ൌ Ͷǡ κ ൌ ͳǡ ݉ κ ൌ െͳǡ ݉ ൌ െͳȀʹ 27. Manganese(IV) oxide is a brown insoluble solid often found as a product of reactions of potassium permanganate. What is the formula of manganese(IV) oxide? a. ܯܱ݊ b. ܯ݊ ܱ c. ܯܱ݊ d. ܯ݊ ܱ e. ܯܱ݊
CHEM 1161 Spring 2022 Final Exam D. Matthew Page 8 of 12 Answer the remaining problems in the space provided. Be sure to show all work for full credit! If you need extra paper, let us know! 28. (18 Points Total) The reaction below shows the synthesis of ammonia, commonly used in fertilizers, in a procedure called the Haber-Bosch process that involves reacting atmospheric nitrogen with hydrogen gas using a metal catalyst. ܰ ሺ݃ሻ ൅ ͵ ܪ ሺ݃ሻ ՜ ʹ ܰܪ ሺ݃ሻ This reaction was started with 5.00 g of each of the two reactants. Calculate the mass, in grams, of each of the three species present in the reaction vessel once the reaction is complete, assuming it reacts to 100% completion. In other words, how much of each reactant remain and how much product will there be once the reaction is complete? Important: Enter your answers in the space provided at the bottom of the page for full credit! Amount at end of reaction, in grams: ܰ ሺ݃ሻǣ ܪ ሺ݃ሻǣ ܰܪ ሺ݃ሻǣ
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CHEM 1161 Spring 2022 Final Exam D. Matthew Page 9 of 12 29. (15 Points) Use ƚŚĞƐĞ ƌĞĂĐƚŝŽŶƐ͙ ܰܽሺݏሻ ൅ ܪ ሺ݃ሻ ൅ ܱ ሺ݃ሻ ՜ ܱܰܽܪሺݏሻ ȟܪ ൌ െͶʹ͹ ݇ܬȀ݉݋݈ ܰܽሺݏሻ ൅ ܪ ܱሺκሻ ՜ ܱܰܽܪሺܽݍሻ ൅ ܪ ሺ݃ሻ ȟܪ ൌ െͳͺͶ ݇ܬȀ݉݋݈ ʹ ܪ ሺ݃ሻ ൅ ܱ ሺ݃ሻ ՜ ʹ ܪ ܱሺκሻ ȟܪ ൌ െͷ͹ʹ ݇ܬȀ݉݋݈ ͙ƚŽ ĐĂůĐƵůĂƚĞ ȟܪ ௥௫௡ for the dissolution of solid sodium hydroxide in water, which is: ܱܰܽܪሺݏሻ ՜ ܱܰܽܪሺܽݍሻ
CHEM 1161 Spring 2022 Final Exam D. Matthew Page 10 of 12 30. (4 Points) Aniline is a weak organic base that reacts with water according to the reaction below. Calculate the pH of a 2.5 M solution of aniline, given its ܭ value is ͶǤͲ ൈ ͳͲ ିଵ଴ . ܥ ܪ ܰܪ ሺܽݍሻ ൅ ܪ ܱሺκሻ ֖ ܥ ܪ ܰܪ ሺܽݍሻ ൅ ܱܪ ି ሺܽݍሻ 31. (8 Points) A reaction was studied to have the following rate constants, measured at different temperatures: ݇ ሺܯ ିଵ ή ݏ ିଵ ܶ݁݉݌݁ݎܽݐݑݎ݁ ሺܭሻ ͶǤͷ ൈ ͳͲ ିଷ ͵ͲͶ ͵Ǥ͹ ൈ ͳͲ ିଶ ͵ʹͷ Using this information, what is the activation energy for this reaction in kJ/mol ?
CHEM 1161 Spring 2022 Final Exam D. Matthew Page 11 of 12 32. (5 Bonus Points) This bonus question is a free for all. Provide anything you want and I will give you points. It can be a picture, a joke, a riddle, a story, anything you have time to put that you would like to share with me and the TAs as we grade. It was a pleasure having you in class this semester. I hope that you have a fantastic summer! Okay, one last reminder (sorry, not sorry): If you have yet to complete your TRACE evaluations for lecture and/or your recitation (or your other classes!), please take a moment to do that today , as they close tomorrow. I, and my future students, thank you!
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CHEM 1161 Spring 2022 Final Exam D. Matthew Page 12 of 12 Potentially Useful Constants and Conversions: ܰ ൌ ͸ǤͲʹʹ ൈ ͳͲ ଶଷ ݉݋݈ ିଵ ܿ ൌ ͵ǤͲͲ ൈ ͳͲ ݉Ȁݏ ݄ ൌ ͸Ǥ͸ʹ͸ ൈ ͳͲ ିଷସ ܬ ή ݏ ܴ ൌ ͺǤ͵ͳͶ ܬȀሺ݉݋݈ ڄ ܭሻ ͳ ܽ݉ݑ ൌ ͳǤ͸͸ͲͷͶ ൈ ͳͲ ିଶ଻ ݇݃ ͳ ݇݃ ൌ ʹǤʹͲͶ͸ ݈ܾ ͳ ݉ ൌ ͳǤͲͻ͵͸ ݕ݀ ͳ ݅݊ ൌ ʹǤͷͶ ܿ݉ ሺ݁ݔܽܿݐሻ ͳ ݄ݎ ൌ ͵͸ͲͲ ݏ݁ܿ Potentially Useful Equations: ܭ ൌ Ԩ ൅ ʹ͹͵Ǥͳͷ ሺ݁ݔܽܿݐሻ Ԩ ൌ Ԭ െ ͵ʹ ͳǤͺ ߥ ൌ ܿ ߣ ܧ ൌ ݄ߥ ܧ ൌ ݄ܿ ߣ ܧ ൌ െʹǤͳͺ ൈ ͳͲ ିଵ଼ ܬ ൬ ͳ ݊ ሺ݊ ൌ ͳǡʹǡ͵ǡ ǥ ሻ ȟܪι ௥௫௡ ൌ ෍ ݊ ȟܪι ௙ǡ௣ െ ෍ ݊ ȟܪι ௙ǡ௥ ȟܧ ൌ ݍ ൅ ݓ ȟܩ ൌ ȟܪ െ ܶȟܵ ȟܩ ൌ ȟܩι ൅ ܴܶ ܳ ȟܩι ൌ െܴܶ ܭ ݇ ൌ െ ܧ ܴ ͳ ܶ ൰ ൅ ܣ ݇ ݇ ൌ െ ܧ ܴ ͳ ܶ ͳ ܶ ݌ܪ ൌ െ ሾܪ ܱ ሾܪ ܱ ሿ ൌ ͳͲ ି௣ு Reaction Order Rate Law Integrated Rate Law (Linear Form) Half-Life Equation Ͳ ܴܽݐ݁ ൌ ݇ሾܣሿ ሾܣሿ ൌ െ݇ݐ ൅ ሾܣሿ ݐ ଵȀଶ ሾܣሿ ʹ݇ ͳ ܴܽݐ݁ ൌ ݇ሾܣሿ ሾܣሿ ൌ െ݇ݐ ൅ ሾܣሿ ݐ ଵȀଶ ʹ ݇ ʹ ܴܽݐ݁ ൌ ݇ሾܣሿ ͳ ሾܣሿ ൌ ݇ݐ ൅ ͳ ሾܣሿ ݐ ଵȀଶ ͳ ݇ሾܣሿ