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W2019 practice
General Chemistry: Change and Equilibrium (University of Calgary)
Studocu is not sponsored or endorsed by any college or university
W2019 practice
General Chemistry: Change and Equilibrium (University of Calgary)
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THE UNIVERSITY OF CALGARY
FACULTY OF SCIENCE
Chemistry 203 (Winter 2019)
Modified Practice exam
There are
12 double-sided
pages
in this exam
including
this cover page
and the 2 formula/data sheets.
Please check that you have all pages.
Practice exam adapted primarily from W19 exam
Time Allotted: 3 hours
FIRST NAME:
LAST NAME:
Circle your
lecture section
L01
MWF 1:00 PM
Dr. Yuen-ying Carpenter
L02
MWF 2:00 PM
Dr. Bronwen Wheatley
L03
TuTh 9:30 AM
Dr. Bronwen Wheatley
This is a closed-book examination.
The use of resources including cameras, audio players and headphones, or wireless access devices such
as cell phones, Blackberries, etc., during the examination will not be allowed. Only non-programmable calculators are permitted.
A formula
sheet and a data sheet are provided on the last two pages of the exam.
This exam consists of:
17 single-answer multiple choice
questions (total 34 marks)
6 mixed-multiple choice
scenarios (total 27 marks)
3 written answer
question (total 17 marks)
for a total of 78 marks.
All questions must be answered to obtain full
marks. The answers to
both
multiple-choice
sections (
Sections I and II
) must be entered on the
optical score sheet.
The answers to the written
answer questions in Section III must be written in
the space provided and all work should be shown.
The time limit for the exam includes the time necessary to fill in the answers for the multiple-choice questions on the optical score sheet provided.
AT THE END OF THE EXAMINATION, HAND IN THE OPTICAL SCORE SHEET AND THE ENTIRE EXAM PAPER
Failing to encode both this Exam Booklet and your Optical Score Sheet correctly,
with your name, lecture section, and student ID (
inside the cover
),
will result in the loss of two marks
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CHEM 203 Winter 2019
Final Exam
Page 2 of 24
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CHEM 203 Winter 2019
Final Exam
Page 3 of 24
Do not write in this table.
For administration only.
Q34
Q35
Q36
Sigfigs/Units
(Section III)
*****************************************************************************************************************
Student ID #:
SECTION I – Single-answer multiple choice
(
2 marks per question
)
Select the
single best answer
and encode it on the Optical Score Sheet
1.
A researcher collected data on the decomposition of hydrazine, N
2
H
4
(
ℓ
):
3 N
2
H
4
(
ℓ
)
→
4 NH
3
(
g
) + N
2
(
g
)
Δ
r
H =
−
334 kJ
During an experiment under constant pressure conditions, 67 kJ of heat was released
by the system. How many moles of ammonia gas (NH
3
) were produced by this
experiment?
a.
0.20 mol
b.
0.80 mol
c.
1.2 mol
d.
4.0 mol
e.
5.0 mol
This space can be used for rough work
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CHEM 203 Winter 2019
Final Exam
Page 4 of 24
You add
excess
chlorine gas C
ℓ
2
(g) to rigid flask containing an aqueous solution of
ammonium bromide NH
4
Br (aq) in order to produce NC
ℓ
3
(g), as shown in this
balanced chemical equation:
NH
4
Br (aq) + 3 C
ℓ
2
(
g
)
→
NC
ℓ
3
(g) + 3 HC
ℓ
(g) + 1 HBr (g)
Δ
rxn
H°
< 0
The flask initially contains:
1.0 L of a 0.30 M solution of NH
4
Br (aq), and
1.00 mol of C
ℓ
2
(
g
).
Assume that
the temperature stays constant
throughout the reaction.
Answer questions on this page
and
the next (
Q2 to Q6
) based on this scenario.
2.
How many moles of chlorine atoms are in the flask
before
the reaction?
a.
0.500 mol
b.
1.00 mol
c.
2.00 mol
d.
3.00 mol
e.
6.00 mol
3.
After a certain amount of time, you check on the progress of the reaction. At this
time, there are 0.20 moles of NH
4
Br (aq) left in the flask.
How much C
ℓ
2
(
g
) is in the flask
at this time
?
a.
0.30 mol
b.
0.60 mol
c.
0.70 mol
d.
0.90 mol
e.
1.1 mol
– Questions for this scenario continue on next page –
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Final Exam
Page 5 of 25
– Questions continued from scenario on previous page –
4.
How will the
total pressure
before
the reaction compare to the total pressure
after
the reaction goes to completion
?
a.
Pressure is
equal
both before and after because mass is conserved.
b.
Pressure is higher
before
because the aqueous solution occupies volume.
c.
Pressure is higher
after
because there are more types of gases present.
d.
Pressure is higher
after
because there are more moles of gas present.
e.
Pressure is higher
after
because the excess reactant is a gas
5.
Considering only the gases present, what is the
total number of moles of gas
present
after the reaction goes to completion
?
a.
1.00 mol
b.
1.30 mol
c.
1.50 mol
d.
1.60 mol
e.
1.67 mol
6.
If the reaction produced
NC
ℓ
3
(
ℓ
) instead
of producing this same compound as a
gas, the system would…
a.
… release a larger amount of energy in the form of heat.
b.
… release a smaller amount of energy in the form of heat.
c.
… absorb a larger amount of energy in the form of heat.
d.
… absorb a smaller amount of energy in the form of heat.
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CHEM 203 Winter 2019
Final Exam
Page 6 of 24
Consider the two graphs below, which compare the energy of the reactant molecules
before
and
after
a scientist makes some change to the reaction conditions. Use these
graphs to answer the
next two questions
.
7.
What change could the scientist have made to result in the
After
curve shown?
a.
The reactants could be at a
higher
temperature
after.
b.
The scientist could be using
lighter molecules
in their reaction after.
c.
The scientist could have
added a catalyst
to their reaction.
d.
More than one
of these changes could explain the observations.
e.
None of these
changes could explain the observations.
8.
Which regions (i-iv) represent the number of molecules
only
had sufficient energy to
react after the change was made (
not before
)?
a.
Region (i) only
b.
Regions (i) and (ii)
c.
Region (iii) and (iv)
d.
Region (iv) only
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CHEM 203 Winter 2019
Final Exam
Page 7 of 24
9.
Predict the
pH at 298 K
at the following points in the titration:
At the
half-equivalence
point…
At the
equivalence
point…
a.
pH < 7
pH > 7
b.
pH < 7
pH = 7
c.
pH > 7
pH > 7
d.
pH > 7
pH = 7
e.
More information is needed to determine the pH at both points.
10.
When only
one-third
of the initial weak acid
had been neutralized
, what do you
predict for this solution at 298K?
In the solution, there would be a…
…therefore…
a.
3:1 ratio of weak acid to strong base
pH < 7 since there is more acid than base
b.
3:1 ratio of weak acid to strong base
pH > 7 since there is strong base present
c.
2:1 ratio of weak acid to weak base
pH < 7 since there is more acid than base
d.
2:1 ratio of weak acid to weak base
pH > 7 since pH is
±
1 unit from the p
K
a
This space can be used for rough work
For the next two questions
, consider the
titration of the weak acid NH
4
+
with a
strong base
, similar to your laboratory Experiment 4. (
K
b
for NH
3
=
1.8
×
10
−
5
)
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Final Exam
Page 8 of 25
12.
How many
of the scenarios described below would result in a
Δ
S
sys
< 0
?
•
Freezing of water at 0
°
C.
•
Compressing 1 mol of nitrogen gas.
Warming up liquid water
a.
0
b.
1
c.
2
d.
3
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Final Exam
Page 9 of 25
13.
If we add more chloride ions to this reaction in progress, what will we observe?
Which reaction becomes
more favourable?
How will
Δ
G change?
a.
Forward reaction
Decreases (more negative)
b.
Forward reaction
Increases (more positive)
c.
Reverse reaction
Decreases (more negative)
d.
Reverse reaction
Increases (more positive)
14.
Given the standard potential E
°
< 0 at 298 K, what else must be true about this
reaction?
At 298 K, the reaction is…
When E = E
°…
a.
Product-favoured, K > 1
…the reaction is at equilibrium
b.
Product-favoured, K > 1
… aqueous ion concentrations are 1 M.
c.
Reactant-favoured, K < 1
…the reaction is at equilibrium
d.
Reactant-favoured, K < 1
… aqueous ion concentrations are 1 M.
15.
If the reaction was allowed to proceed
in the spontaneous direction
, what would
we observe?
a.
The
magnitude
of E
cell
will become smaller until it reaches E
°
cell
b.
The
magnitude
of E
cell
will become larger until it reaches E
°
cell
c.
The
magnitude
of E
cell
will become smaller until it reaches zero
d.
The
magnitude
of E
cell
will become larger until it reaches zero
This space can be used for rough work
For the next three questions
, consider the following equilibrium reaction:
Br
2
(
ℓ
) + 2 C
ℓ
–
(aq)
±
C
ℓ
2
(g) + 2 Br
–
(aq)
E
°
< 0
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Final Exam
Page 10 of 25
16.
For a specific reaction, you determine that
Δ
rxn
G
°
is
negative
below some temperature
T
1
and that
Δ
rxn
G
°
is
positive
above T
1
.
Based on this data, we know that under standard state conditions…
a.
Δ
rxn
S° < 0 and the reaction is only spontaneous at high temperatures.
b.
Δ
rxn
S° < 0 and the reaction is only spontaneous at low temperatures.
c.
Δ
rxn
S° > 0 and the reaction is only spontaneous at high temperatures.
d.
Δ
rxn
S° > 0 and the reaction is only spontaneous at low temperatures.
This space can be used for rough work
**************END OF SINGLE-ANSWER MULITIPLE CHOICE SECTION**************
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CHEM 203 Winter 2019
Final Exam
Page 11 of 24
SECTION II: Mixed multiple choice
(6 scenarios, 16 questions, 27marks)
Select the correct answers and encode it on the Optical Score Sheet
Partial credit is possible in some questions.
If the question asks you to ‘Select All’, selecting any incorrect statements will result in a deduction from the points
earned in that question
18.
If this reaction is performed in a
closed
,
flexible
container under
constant pressure
, is
work being done by or on the system during the reaction? What is the sign for w?
Select only one option.
a.
On the system and w > 0
b.
On the system and w < 0
c.
By the system and w > 0
d.
By the system and w < 0
e.
No work is being done and w = 0
19.
Explain why
you selected the answer that you did in the previous question.
Select all that apply
a.
… since the reaction is exothermic, so energy is released.
b.
… since the reaction is endothermic, so energy is absorbed.
c.
… since for every 7 mol before the reaction and there are only 4 mol after.
d.
… since for every 6 mol of gas before the reaction and there are only 4 mol after.
e.
… because it is a closed system no energy can be transferred to the surroundings.
This space can be used for rough work
Scenario 1
: Let’s revisit that balanced chemical equation from Tutorial 2 again.
P
4
(s) + 6 H
2
(g)
→
4 PH
3
(g)
Δ
rxn
H
° > 0
Use this information to answer
both
of the next two questions.
Marks
1
Marks
2
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Final Exam
Page 12 of 25
19.
Student explanation 1:
“Solutions of Br
–
are
basic
. Br
–
is the conjugate of the acid HBr; since all conjugates
of acids are basic, Br
–
must also be basic.”
20.
Student explanation 2:
“Solutions of C
ℓ
O
4
–
are
acidic
because it reacts with water to produce the strong acid
HC
ℓ
O
4
as shown in this reaction”:
C
ℓ
O
4
–
+ H
2
O
⇌
HC
ℓ
O
4
+ OH
–
21.
Student explanation 3:
“Solutions of CH
3
NH
3
+
are
acidic
because this ion will donate a proton (H
+
).”
This space can be used for rough work
Scenario 2
: In a CHEM 203 tutorial, students were asked to predict if certain ions
were acidic, basic or pH-neutral, and then explain their reasoning.
You must evaluate each answer based on the
claim-evidence-reasoning
framework you
used in your laboratories and tutorials to determine if their answer would receive full
credit, and if not, where their answer needed improvement.
Answer each question by selecting all the options from this list which apply.
a.
This student’s answer is correct and complete.
b.
The student’s
claim
is wrong –
e.g, they said the ion is acidic when it is not
.
c.
The student’s answer is
missing
either
evidence
or
reasoning
.
d.
The student’s
evidence
is not relevant to their claim or explanation.
e.
There is an error in the student’s
reasoning
–
in their ‘therefore’ or ‘why’
.
Refer to the data tables & formula sheet at the back of the exam as needed.
Marks
6
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CHEM 203 Winter 2019
Final Exam
Page 13 of 24
2
2
.
To find the
average rate of the reaction over the first 3 h
… (
select only one
)
..the student should use the slope of…
and their final answer must be…
a. Line 1
Positive
b. Line 1
Negative
c. Line 2
Positive
d. Line 2
Negative
2
3
.
To calculate the
average rate of appearance of Z over the first 3 h
, the student should
multiply their slope by what value to find the
magnitude
(absolute value) of that rate?
× 2
× 5
×
1
3
×
1
5
×
2
15
×
5
6
×
5
2
×
2
5
AB
AC
AD
AE
BC
BD
BE
CD
This space can be used for rough work
Scenario 3
: Consider the following data a student collected for compound X in the
hypothetical reaction
2 X (g)
→
Y (g) + 5 Z (
g
)
The student has already begun
their analysis by drawing the two
dashed lines and finding the
slopes of both Line 1 and Line 2.
Tell the student how to use these
slopes to calculate the two rates
they need to find on this page.
Marks
4
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Final Exam
Page 14 of 25
For each reaction at 298 K,
choose the appropriate value for the exponent
(w, x, y, or z)
from the answer choices listed in the table above.
25.
Reaction 1:
HCO
3
–
(
aq
) + H
2
O (
ℓ
)
⇌
CO
3
2–
(
aq
) + H
3
O
+
(
aq
)
K
1
≈
10
w
26.
Reaction 2:
HCO
3
–
(
aq
) + OH
–
(
aq
)
⇌
CO
3
2–
(
aq
) + H
2
O (
ℓ
)
K
2
≈
10
x
27.
Reaction 3:
CO
3
2–
(
aq
) + HF (
aq
)
⇌
HCO
3
–
(
aq
) + F
–
(
aq
)
K
4
≈
10
z
This space can be used for rough work
Scenario 4
: Your task is to estimate the
order of magnitude
for the equilibrium
constant,
K
, for each of the reactions below.
For this question, assume all reactions
can be described as equilibrium reactions, even if K >> 1 and we might normally
describe the reaction as going to completion.
Useful data at 298 K
:
K
b
for CO
3
2–
≈
10
– 4
K
a
for HF
≈
10
– 4
Answer
choices
–10
–9
–8
–6
–4
4
6
8
9
10
AB
AC
AD
AE
BC
BD
BE
CD
CE
DE
Marks
6
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CHEM 203 Winter 2019
Final Exam
Page 15 of 24
30.
Which of the following mixtures will produce a buffer solution?
Select all that apply.
a.
200.0 mL of water with 0.10 mol HC
ℓ
plus
0.20 mol NaOH
b.
200.0 mL 0.10 M HC
ℓ
(aq)
plus
0.20 mol NH
3
c.
200.0 mL 0.10 M HC
ℓ
(aq)
plus
0.20 mol NH
4
+
d.
200.0 mL 1.0 M HC
ℓ
(aq)
plus
0.20 mol NH
3
e.
200.0 mL 0.10 M NH
4
⁺
(aq)
plus
0.20 mol NH
3
31.
Suppose you select one of the buffers from the previous question and dilute it to by
adding more water as shown in the solutions below
What must be true about these three solutions, W, X and Y?
(select
all
that apply)
a.
Solutions W and X have the same pH.
b.
Solutions W and X can neutralize equal moles of strong acid.
c.
Solutions W and Y have the same buffer ratio.
d.
Solutions W and Y can neutralize equal moles of strong base.
This space can be used for rough work
Scenario 5
: Properties of buffers
Marks
4
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Final Exam
Page 16 of 25
Scenario 6:
A student plans to test the solubility of AgNO
2
(s).
When this salt is added to water, it dissociates and produces Ag
+
(aq) and NO
2
−
(aq),
according to the equilibrium reaction shown below
AgNO
2
(s)
±
Ag
+
(aq) + NO
2
−
(aq)
K
C
= 1.8
×
10
−
10
To perform their tests, the student has prepared 5 separate beakers, each containing
100 mL of one of the following solutions to test:
A. water
B.
0.01 M Ca(NO
2
)
2
(aq)
(which fully dissociates in water)
C.
0.01 M NaNO
2
(aq)
(which fully dissociates in water)
D.
0.01 M HC
ℓ
(aq)
E.
0.1 M HC
ℓ
(aq)
Additional information:
HNO
2
is a
weak acid
.
Use this information for the next two questions.
30.
Assuming the same amount of AgNO
2
(s) was added to each beaker, which solution
(A-E) will have the
highest
concentration of silver ions at equilibrium?
Select more than one if two solutions have equal concentrations [Ag
+
]
E
.
31.
Assuming the same amount of AgNO
2
(s) was added to each beaker, which solution
(A-E) will have the
lowest
concentration of silver ions at equilibrium?
Select more than one if two solutions have equal concentrations [Ag
+
]
E
.
This space can be used for rough work
Marks
4
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Final Exam
Page 17 of 25
32.
Which of these calculation(s) would result in a correct value for the solution pH?
Select all that apply.
a.
For a HNO
3
(aq) solution, pH =
−
log[HNO
3
], since HNO
3
is a strong acid.
b.
For a H
2
S (aq) solution, pH =
−
log[H
2
S], since H
2
S is a weak acid.
c.
For a CH
3
COOH (aq) solution, pH = p
K
a
, since CH
3
COOH is a weak acid.
d.
For a NaOH (aq) solution, pH = pKw + log[NaOH], since NaOH is a strong
base.
e.
For a Ca(OH)
2
(aq) solution, pH = 14.00 + log[Ca(OH)
2
] at 298K, since
Ca(OH)
2
is a strong base.
This space can be used for rough work
******************END OF MIXED MULTIPLE CHOICE SECTION**************
Marks
2
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CHEM 203 Winter 2019
Final Exam
Page 17 of 24
This side of the page can be used as scrap paper.
Section III WRITTEN ANSWER BEGINS NEXT PAGE
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Final Exam
Page 19 of 25
SECTION III: Written Answers.
(16 marks + 1 mark sigfigs/units)
Show all work for full credit and write final numerical answers in the boxes.
33.
A researcher takes an empty 1.0 L flask and adds…
•
5.0
×
10
−
4
mol of NH
4
F (
s
)
•
2.0
×
10
−
5
mol of NH
3
(
g
), and,
•
1.0
×
10
−
5
mol of HF (
g
).
These compounds have the potential to react according to the following balanced
equilibrium reaction:
NH
4
F (
s
)
⇌
NH
3
(
g
)
+
HF (
g
)
K
C
= 7.7
×
10
−
7
(a) When the experiment reaches equilibrium
, will there be more / less / same amount
of
NH
4
F (
s
) compared to the start of the reaction.
Circle one and support your answer with at
least one numerical value and a clear explanation of your reasoning.
(b)
After
the mixture reaches equilibrium, the researcher
adds more NH
4
F (
s
)
to the flask.
Assuming that the solid still occupies negligible volume in the flask,
predict what will
happen
and
explain your reasoning
. (
1-2 sentences max
)
This space can be used for rough work.
This area will NOT be graded unless you
ask us to do so in the question area.
Marks
4
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Adapted from CHEM 203 Winter 2019
Final Exam
Page 20 of 25
34.
(a) Determine the pH at 298 K of a solution prepared by mixing 20.00 mL of 0.10 M
dimethylamine (CH
3
NH
2
, aq) with 10.00 mL of 0.20 M of HBr (aq).
(b) Determine the pH at 298 K of a solution prepared by mixing 20.00 mL of 0.10 M
dimethylamine (CH
3
NH
2
, aq) with 20.00 mL of 0.20 M of HBr.
This space can be used for rough work.
This area will NOT be graded unless you
ask us to do so in the question area.
pH =
pH =
Marks
7
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Adapted from CHEM 203 Winter 2019
Final Exam
Page 21 of 25
35.
A student prepares a
pH 6.40 buffer
by mixing one of the acids in the data table at
the back of the exam with some of its conjugate base.
(a)
Which acid must the student have used?
Explain your reasoning in 1-sentence.
(b)
If they started with a 50.0 mL of an 0.050 M solution of their acid, how many
moles
of their conjugate base
did they need to add to reach their target pH?
(c)
The student tests their 50.0 mL sample of buffer solution by
adding 1.5 mmol of
NaOH
. Calculate the expected pH of the buffer
after
this addition.
This space can be used for rough work.
This area will NOT be graded unless you
ask us to do so in the question area.
***END OF LONG ANSWER
SECTION***
pH =
n
conjugate
=
Marks
5
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Related Questions
Activated complex
400
(b)
300
Products
Potential
Energy
(a)
200
(c)
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Reactants
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Activated complex
400
(b)
300
Products
Potential
Energy
(a)
200
(c)
100
Reactants
Reaction Pathway
Alex thinks that the graph above represents an exothermic reaction and the AH =
+400kJ and energy will be released in this reaction. Is Alex correct? If not, find his
error and then correct it with explanation.
%3D
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Construct the expression for Kc for the following reaction.
Drag the tiles into the numerator or denominator to form the expression. Each reaction participant must be represented by one tile.
Do not combine terms.
PLOY
JOHY
24.01
H.O (1) H (aq) + OH (aq)
K₂ =
HOP
P+1
201
pry
JOH
RESET
201
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Name:
Date:
Section:
Prelaboratory Assignment: Spectrophotometric Determination of an
Equilibrium Constant.
1. At 227°C, carbon monoxide gas reacts with hydrogen gas to form one mole of methanol,
CH,OH. At equilibrium, the partial pressures of the gases are Pco= 0.295 atm, PH2 1.25 atm,
and PCH3OH = 2.18 atm.
a) Write a balanced equation for the reaction
b) Calculate the equilibrium constant for the reaction.
2. Consider the reaction:
A+B=C+ 3D
A solution was prepared by mixing 50.00 mL of 1.00 x 10³ M A, 100 mL of 2.00 x 10 MB,
10.0 mL of 1.0 M C and 75 mL of 1.50 x 10³M D. At equilibrium, the concentration of D was
measured to be 6.0 x 10 M.
a) Calculate the equilibrium concentrations of each species
b) Calculate the equilibrium constant.
3. Consider the reaction:
#
2NO2(g) + Cl2(g) 2NOCI
The initial pressure of NO, was 1.577 atm and the initial pressure of Cl₂ was 0.427 atm. At
equilibrium, the partial pressure of NOCI is 0.624 atm. Calculate K.
arrow_forward
he
10.2. Suppose that a reaction A + 2B = 2Y + 2Z is
believed to occur according to the mechanism
k₁
A
2X
(very rapid equilibrium)
k₂
X+BY+Z
(slow)
Obtain an expression for the rate of formation of the
product Y.
arrow_forward
For the reaction
N2(9) + O2(9) = 2NO(g)
classify each of the following actions by whether it causes a leftward shift, a rightward shift, or no shift in the direction of the reaction.
Drag the appropriate items to their respective bins.
• View Available Hint(s)
Reset
Help
halve Po2
halve
double PN2
double
halve PN2
double Po2
PNO
PNO
Leftward shift
Rightward shift
No shift
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The equilibium constants of the reactions
FeO(s) + CO(g) = Fe(s) + CO2(g) ; K1
FeO (s) + H2(g) = Fe(s) + H2O (g) ; K2
Temp (oC) 600 700 800 900 1000
-------------------------------------------
K1 0.900 0.673 0.535 0.453 0.396
K2 0.332 0.422 0.499 0.594 0.668
Calculate the Equilibium constant of the reaction
CO (g) + H2O (g) = CO2(g) + H2(g)
at the above temperature Also calculate the heat of the reaction for the production of hydrogen from carbon monoxide and water vapour, assuming it to be independent of temperature
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PLAY
General Chemistry I Laboratory Manual, 2019 Revision
119
2) Calculate AH for the reaction below using Hess' law.
and the
C2H6(g) → C2H2(g) + H2(g)
Introde
AH=?
Youhe
C2H2(g) +5/202(g) → 2CO2(g) + H2O(1)
AH = -1300 kJ
2H2(g) + O2(g) → 2H2O(1)
ΔΗ--572 kJ
2C2H6(g) + 7O2(g) → 4CO2(g) + 6H2O(1)
AH = -3120 kJ
ithin
atom
-16022 10
Wen
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Consider the acid catalyzed reaction;
AH + H+ ----> AH,+
rate = k1[AH][H*] (fast)
AH2+
----> AH + H+
rate =
k2[АН2*] (fast)
AH,+ + B ----> BH+ + AH
rate = k3[AH2*[B] (slow)
Using the pre-equilibrium approximation derive the rate law.
rate =
(kık3/k2)[H*][B]
rate =
(kık2/k3)[HA][H*[B]
rate =
(kık3/k2)[HA][H+][B]
rate =
(kık3/k2)[HA][B]
If the only source of H+ is from HA show that it is possible to derive a rate law that is independent of H+. What is the
rate law?
Hint: Add the fast equilibrium HA H+ + A¯ to the proposed mechanism in part a).
(kık3Ka/2/k2)[HA]!/2[B]
(kık3Ka1/2/k2)[HA]3/2[B]
rate = (kık3/k2K1/2)[HA][B]
rate = (kık3/k2Ka1/2)[HA]3/2[B]
rate =
rate =
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C. BaCl2(aq)+ K2CrO4(aq)<---> BaCrO4(s)+ 2K+(aq)+ 2Cl-(aq)
and 2CrO42-(aq)+ 2H+(aq)<---> Cr2O72-(aq)+ H2O(l)
For the questions indicate where reaction will shift towards reactant or product and tell the color observed.
1. Place approximately 5 mL of 0.1 M BaCl2(barium chloride) solution in a test tube.(Note color) Add several drops of 1 M K2CrO4and note the result.
2. Add 6 M HCl until you observe a significant change in the above solutio
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ID=182385216
Kinetics
For Practice 14.4 - Enhanced - with Feedback
I Review | Constants
Cyclopropane rearranges to form propene in the gas
phase.
v Part A
If the initial cyclopropane concetration is 0.0415 M, what is the cyclopropane concentration after 280 minutes?
Express your answer with the appropriate units.
CH2
CH3-CH=CH,
Value
Units
H2C-CH2
The reaction is first order in cyclopropane and has a
at 720 K.
Submit
Request Answer
measured rate constant of 3.36 x 10-5
You may want to reference (Pages 598 - 605) Section
14.5 while completing this problem.
Dreuid.
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Potential energy (k)
Potential energy (kJ)
cument identifier=D7b0cf258-fde2-45f0-ba86-cffe2fe86028&filename%38.03%20Collision%20Theory%20and%20Read
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Application: Chemical Kinetics
1) The graph below is a potential energy
diagram for the hypothetical reaction:
2) On the graph below, draw a potential
energy diagram for the following
reaction:
A + B C + D
Q + R S + T
given the following information:
PE of Q+ R= 150 kJ
PE of S+ T = 250 kJ
PE of the activated complex = 375 kJ
06
09
40.
30,
2 350
Reaction coordinate
000
Is the forward reaction
endothermic or exothermic?
Calculate the value of AH for this
reaction.
Reaction coordinate
b. What is the value of the potential
energy of the activated complex?
a. Is the forward reaction
endothermic or exothermic?
Calculate the value of AH for this
reaction.
c. Calculate the activation energy
(EA) for the forward reaction.
b. Calculate the EA for the forward
reaction..
d. Draw a dashed line to show the
effect of adding a…
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Differential EQN:
Bruce Wayne analyzes a kryptonite in order to prepare if ever Clark Kent becomes rogue. The former studieda kryptonite and found that it decomposes at a rate proportional to the quantity of kryptonite present.Suppose that it is found that in 25 years approximately 1.1% of a certain quantity of kryptonite hasdecomposed. Determine how long it will take until 50% of the original amount of kryptonite dissipates.
pls. provide complete solution with explenation.
the formula we use is : dx/dt=kx
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Drag the appropriate labels to their respective targets in the energy profile diagram.
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sub= 1 urgent please
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19
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1) Use Hess's Law to determine AH for the following target reaction.
3 CO₂(g) + 4 H₂O(g)
b) C3Hg(g) + 5 O₂(g)
C(s) + O₂(g) -CO₂(g)
2 H₂(g) + O₂(g)
3 C(s) + 4 H₂(g)
→→→ 2 H₂O(g)
C3H8(g)
AH =
AH =
ΔΗ
ΔΗ = ???
-2043 kJ
-393.5 kJ
-483.6 kJ
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Apple Google Disney ESPN Yahoo!
☆
Consider the reaction:
Substance
Ca(OH)2 (aq)
HCl(aq)
CaCl₂ (s)
H₂O(1)
ASO =
system
Submit Answer
Biomedical Careers Program
J/K
B
prod03-cnow-owl.cengagenow.com
Sº (J/K mol)
-74.5
56.5
104.6
69.9
Retry Entire Group
Apple iCloud Yahoo Images Bing Google Wikipedia
b
☆
G
[Review Topics]
D2L
D2L
4 more group attempts remaining
D2L
[References]
Use the References to access important values if needed for this question.
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Ca(OH) 2 (aq) + 2HCl(aq) → CaCl₂ (s) + 2H₂O(1)
Using standard absolute entropies at 298 K, calculate the entropy change for the system when 1.73 moles of Ca(OH)2 (aq) react at
standard conditions.
COWLv2...
D2L
b
The Weather Channel
Yelp TripAdvisor
C D2L M G
+ 88
M
?
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Where:
[A]o
1
[A]
=
=
[A] = of reactant
A
initial
kt+
concentration
1
[A]o
concentration
of reactant
A
1
[AO]
k = rate constant
t = time
In order to solve for the time, t, in two steps you must:
Step One
Add the same expression to each side of the equation to leave the term that includes the variable by itself on the
right-hand side of the expression:
(Be sure that the answer field changes from light yellow to dark yellow before releasing your answer.)
1
[A]o
Drag and drop your selection from the following list to complete the answer:
+
1
[A]
=
[Ao]
1
[Ao]
+kt+
-[Ao]
Previous
Next
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Draw a dashed line to show the effect of adding a catalyst to the system
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A reaction at 21.0 °C evolves 552. mmol of dinitrogen difluoride gas.
Calculate the volume of dinitrogen difluoride gas that is collected. You can assume the pressure in the room is exactly 1 atm. Round your answer to 3 significant
digits.
volume: L
x10
Submit Assignmer
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1
2
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Construct the expression for Kc for the following reaction.
2 Sb(s) + 5 CL(g) =2 SbCls(g)
Drag the tiles into the numerator or denominator to form the expression.
O RESET
2[SDCL]
2[SbClj?
[CL]
5[CL]
[Sb]
2[Sb]
[SbF
2[Sb]
46°F
a
earch
近
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