2023 F CH202-4-6 - M1 Review Lecture Worksheet
pdf
keyboard_arrow_up
School
Toronto Metropolitan University *
*We aren’t endorsed by this school
Course
CHEM010
Subject
Chemistry
Date
Jan 9, 2024
Type
Pages
12
Uploaded by GrandBarracudaMaster308
Page 1
of 12
1.
Nicotine is an addictive substance found in tobacco. Identify (1) the hybridization state and (2) the geometry of each of the two nitrogen atoms in nicotine. 2.
Does the following compound have a net dipole moment? 3.
Indicate the formal charge on the nitrogen atom in the following Lewis structure: 4.
What intermolecular forces are operative between molecules of methanol and water? A.
London dispersion forces
B.
Dipole-dipole forces
C.
Hydrogen bonding
D.
All of the above
Page 2
of 12
5.
Predict whether vitamin C is water soluble or not. The structure of vitamin C is shown below. 6.
All of the following are representations of cis-1,2-dimethylcyclohexane, EXCEPT: A B C D 7.
Draw the bond-line structure for vitamin C. 8.
How many hydrogen atoms are connected to the carbon atom that bears the negative charge in the structure below?
Page 3
of 12
9.
Draw all lone pairs in the following compound (add lone pairs to the following structure): 10.
Draw the resonance structure that results from the arrow pushing scheme below: 11.
Which of the following has the correct curved arrow(s) placement? A
B
C
D
12.
Which of the resonance structures below is least significant or invalid?
Your preview ends here
Eager to read complete document? Join bartleby learn and gain access to the full version
- Access to all documents
- Unlimited textbook solutions
- 24/7 expert homework help
Page 4
of 12
13.
Which of the following best represents the resonance hybrid of the given anion? A
B
C
D
14.
Consider the nitrogen atoms (labeled A, B and C) in the molecule of vitamin B1 shown below. Which of these nitrogen atoms possess a delocalized lone pair of electrons? A.
Nitrogen A
B.
Nitrogen B
C.
Nitrogen C
D.
None of the indicated lone pairs are delocalized
Page 5
of 12
15.
Which mechanism below represents the correct curved arrow(s) for a nucleophilic attack? A.
B.
C.
16.
Predict which side of the reaction is favored under equilibrium conditions, and provide a brief explanation. ①
②
③
④
A.
Forward direction is favored, because resonance stabilization makes ③
a stronger base than ②
.
B.
Forward direction is favored, because resonance stabilization makes ③
a weaker base than ②
.
C.
Reverse direction is favored, because resonance stabilization makes ③
a stronger base than ②
.
D.
Reverse direction is favored, because resonance stabilization makes ③
a weaker base than ②
.
Page 6
of 12
17.
Which of the indicated protons in the given compound is the most acidic? A.
Proton A
B.
Proton B
C.
Proton C
D.
Proton D
18.
Consider the following acid-base reaction: A.
Identify the acid and base between the two reactants. B.
Draw the curved arrows showing the reaction. C.
Identify the counterion. D.
Draw the two products of the proton-transfer reaction.
Your preview ends here
Eager to read complete document? Join bartleby learn and gain access to the full version
- Access to all documents
- Unlimited textbook solutions
- 24/7 expert homework help
Page 7
of 12
19.
Give the IUPAC name for the following compound: 20.
Which of the following is a constitutional isomer of heptane? A B C D 21.
Below are several constitutional isomers with the molecular formula C
6
H
14
. Which of these isomers will have the largest heat of combustion? A B C D 22.
Which cycloalkane has the greatest angle strain? A B C D
Page 8
of 12
23.
Which of the following conformations of pentane is highest in energy? A B C D 24.
Draw the bond-line structure of the compound represented by the Newman projection below: 25.
Which conformation of cyclohexane has the most strain? A B C D
Page 9
of 12
26.
Which of the following represents the most stable conformation of cis-1,4-
dimethylcyclohexane? A B C D 27.
Give the IUPAC name for the following compound: A.
cis-1,2-Dimethylcyclohexane
B.
cis-1,6-Dimethylcyclohexane
C.
trans-1,2-Dimethylcyclohexane
D.
trans-1,6-Dimethylcyclohexane
28.
Identify the relationship between the following compounds: A.
identical
B.
stereoisomers
C.
constitutional isomers
D.
compounds with different molecular formulas
29.
Identify the relationship between the following compounds: A.
identical
B.
stereoisomers
C.
constitutional isomers
D.
compounds with different molecular formulas
Your preview ends here
Eager to read complete document? Join bartleby learn and gain access to the full version
- Access to all documents
- Unlimited textbook solutions
- 24/7 expert homework help
Page 10
of 12
30.
Mark all the chiral centers (circle the individual atoms) present in the following structure: 31.
Assign the configuration of each chiral center (stereocenter) in the following compound: A.
2R,3R
B.
2R,3S
C.
2S,3R
D.
2S,3S
3-bromo-2-butanol 32.
What is the relationship between the following two compounds? A.
enantiomers
B.
diastereomers
C.
constitutional isomers
D.
identical compounds
33.
What is the relationship between the following two compounds? A.
enantiomers
B.
diastereomers
C.
constitutional isomers
D.
identical compounds
Page 11
of 12
34.
Identify the configuration of the following alkene: A.
(E)
B.
(Z)
C.
(cis)
D.
(trans)
35.
For each of the following compounds (
A-C
), identify whether it is compound a)
chiral b)
meso, or c)
achiral but not meso A B C
Page 12
of 12
36.
Consider the following S
N
2 reaction, and answer questions: A.
Draw a complete mechanism. B.
Identify the nucleophile and leaving group. Nucleophile: leaving group: 37.
For the following multistep (steps A
-
D
) reaction, read the curved arrows and identify the sequence of arrow-pushing patterns: Step a)
loss of leaving group, b)
nucleophilic attack, c)
proton transfer, or d)
rearrangement. A B C D
Your preview ends here
Eager to read complete document? Join bartleby learn and gain access to the full version
- Access to all documents
- Unlimited textbook solutions
- 24/7 expert homework help
Related Documents
Related Questions
Is the compound soluble or insoluble in water?
What is the geometry around each carbon atom?
What is the bond angle around each carbon atom?
What is the hybridization of each carbon atom?
arrow_forward
11. ВеСI,
а.
Lewis structure
b. Drawing of shape (label angles)
Name of shape
C.
d. Polar or nonpolar?
e. Hybridization
12. BF,
a.
Lewis structure
b. Drawing of shape (label angles)
Name of shape
С.
d. Polar or nonpolar?
e. Hybridization
arrow_forward
What information does the molecular representation provide? (more than one option)1. The number and type of atoms2. Two-dimensional structure of molecules3. The type of link4. How Atoms Bond5. The intermolecular force6. Three-dimensional structure of molecules7. Polarity8. More realistic representation of molecules
arrow_forward
24
arrow_forward
Please refer to the photo! Thank you so much!
arrow_forward
1. Draw a single valid Lewis structure for the molecule. 2. Identify the number of charge clouds around the central atom. 3. Identify the approximate bond angle of the charge clouds around the central atom.4. Identify the molecular geometry corresponding to the bond angles.5. classify as polar or nonpolar
arrow_forward
What is the electron -group geometry and
molecular geometry around the oxygen in
the structure to the right?
A linear, linear
B. linear, angular
C. tetrahedral, linear
D. tetrahedral, angular
tetrahedral, tetrahedral
H—
I—0—I
-0-H
arrow_forward
6. Circle the molecule below with the lower boiling point
Explain why
NH2
arrow_forward
5. Answer the following questions about the molecules CH2S (C is the centralatom).a. Draw the Lewis structure.b. Write the valence shell electron configuration for C.c. Draw the valence orbital diagram for C.d. Draw the hybridized orbital diagram for C.e. Give a bond description for each bond in the molecule.
arrow_forward
Please help with this last question thank you.
arrow_forward
. Draw the Lewis diagram for acetamide. ( CH3CONH2) a. What is the electron geometry around each of the two carbon atoms. b. What is the hybridization type of each of the carbon atoms. c. What are the bond types and orbitals involved in bonding for all bonds between the C and O atoms.
arrow_forward
8. SO3
а.
Lewis structure
b. Drawing of shape (label angles)
С.
Name of shape
d. Polar or nonpolar?
e. Hybridization
9. NO,
Lewis structure
a.
b. Drawing of shape (label angles)
c. Name of shape
d. Polar or nonpolar?
e. Hybridization
10. ΗΝΟ,
а.
Lewis structure
b. Drawing of shape (label angles)
Name of shape
С.
d. Polar or nonpolar? ,
e. Hybridization
11
RoCl
arrow_forward
1) Consider the following 2 molecules: arsane which has the molecular formula AsH3, and dimethylether, an ether which has the molecular formula C2H6O.Which of these molecules is polar?
a. Dimethylether is polar but arsane is not.
b. Both are polar.
c. Neither are polar.
d. Arsane is polar but dimethylether is not.
Consider a pure sample of silane which has the formula SiH4. Of the options listed below, what is the strongest attractive force in this sample?
a. Ionic bonding
b. Ion-dipole forces
c. Hydrogen bonding
d. Dispersion forces
e. Dipole-dipole forces
arrow_forward
Number of
Molecule
valence electrons
Formal Charge
Electron-Group Geometry
Molecular Geometry
Resonance
HSO4
S:
S: Select one .
S: Select one ..
Select one
XeTe4
Хе:
Xe: Select one ...
Xe: Select one ..
Select one
PHO
P:
P: Select one ...
P: Select one ..
Select one ... v
PCIO
P:
P: Select one ...
P: Select one ..
Select one ..
arrow_forward
CH3F is a polar molecule, even though the tetrahedral geometry often leads to nonpolar molecules. Which of the following reasons below explains why CH3F is a polar molecule?
A. None of the above gives a valid explanation.
B. Even though CH3F has a tetrahedral geometry, the hydrogen atoms in the molecule are more electronegative than the fluorine resulting in the molecule being polar.
C. Even though CH3F has a tetrahedral geometry, the carbon atom in the molecule, being the central atom, is more electronegative than the hydrogen and fluorine atoms in the molecule resulting in the molecule being polar.
D. Even though CH3F has a tetrahedral geometry, the fluorine atom in the molecule, being the central atom, is more electronegative than the hydrogen and carbon atoms in the molecule resulting in the molecule being polar.
E. Even though CH3F has a tetrahedral geometry, the molecule is not symmetric due to the presence of the fluorine atom in the structure resulting in the…
arrow_forward
Which model best describes why bonds form between some atoms, but not others? A. Valence bond diagram
b. Molecular orbital diagram
c. Potential energy diagram
arrow_forward
9
A molecule (or ion) has _______ electrons. It is composed of a central atom surrounded by
identical atoms. Draw a generic Lewis structure using A for the central atom and X for the outer
atoms.
Identify at least one molecule and one ion that have the above electron configuration.
The electron geometry is
The molecular shape is
The bond angles are
The hybridization of the central atom is
MacBook Pro
arrow_forward
Please help me answer this questions
arrow_forward
Need help on a-d
arrow_forward
Use the following Lewis diagram for 1-propanol to answer the questions:
H H
H
1
H
H
2
H
13
H
H
Remember that geometry refers to the geometry defined by the atoms, not the electron pairs.
The geometry about atom C₁ is
The ideal value of the C-C-C angle at atom C₂ is
The geometry about atom 03 is
degrees.
arrow_forward
1 and 2 answer only
arrow_forward
23. Which molecules is/are polar?
A. H2O
B. NH3
C. All are polar
D. CH3F
arrow_forward
Number of
Molecule
valence electrons
Formal Charge
Electron-Group Geometry
Molecular Geometry
Resonance
COSe
C:
C: Select one ...
C: Select one..
Select one ..
SH412
S:
S: Select one ..
S: Select one ..
Select one ...
SeHĄBr2
Se:
Se: Select one...
Se: Select one ...
Select one ...
AtGeN
Ge:
Ge: Select one ...
Ge: Select one ...
Select one ...
CIGEP
Ge:
Ge: Select one...
Ge: Select one ...
Select one ... V
10000
arrow_forward
6. Questions pertain to the structure shown below:
CH
HC
H3C.
CH
H3C
H3C
6.1 Which of the following is the strongest bond?
A. A carbon to carbon single bond
B. A carbon to carbon double bond
C. A carbon to carbon triple bond
D. None of the above, the all have the same strength
6.2The total number of sp3 hybridized carbon(s) is/are:
6.3 The total number of sp2 hybridized carbon(s) is/are
6.4 The total number of sp hybridized carbon(s) is/are:
6.5 The total number of T bonds are:
arrow_forward
10. Shown below are the structures of six molecules. For each molecule:
i.) Indicate whether the molecule features delocalized n bonding.
ii.) Indicate which atoms in each molecule possessp orbitals that are not hybridized.
iii.) If the molecule does feature delocalized n bonding, draw at least one resonance structure
that exists for the molecule.
F.
NH2
D.
Е.
`NH2
arrow_forward
SEE MORE QUESTIONS
Recommended textbooks for you

Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning

Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning

Chemistry for Engineering Students
Chemistry
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Cengage Learning

Related Questions
- Is the compound soluble or insoluble in water? What is the geometry around each carbon atom? What is the bond angle around each carbon atom? What is the hybridization of each carbon atom?arrow_forward11. ВеСI, а. Lewis structure b. Drawing of shape (label angles) Name of shape C. d. Polar or nonpolar? e. Hybridization 12. BF, a. Lewis structure b. Drawing of shape (label angles) Name of shape С. d. Polar or nonpolar? e. Hybridizationarrow_forwardWhat information does the molecular representation provide? (more than one option)1. The number and type of atoms2. Two-dimensional structure of molecules3. The type of link4. How Atoms Bond5. The intermolecular force6. Three-dimensional structure of molecules7. Polarity8. More realistic representation of moleculesarrow_forward
- 24arrow_forwardPlease refer to the photo! Thank you so much!arrow_forward1. Draw a single valid Lewis structure for the molecule. 2. Identify the number of charge clouds around the central atom. 3. Identify the approximate bond angle of the charge clouds around the central atom.4. Identify the molecular geometry corresponding to the bond angles.5. classify as polar or nonpolararrow_forward
- What is the electron -group geometry and molecular geometry around the oxygen in the structure to the right? A linear, linear B. linear, angular C. tetrahedral, linear D. tetrahedral, angular tetrahedral, tetrahedral H— I—0—I -0-Harrow_forward6. Circle the molecule below with the lower boiling point Explain why NH2arrow_forward5. Answer the following questions about the molecules CH2S (C is the centralatom).a. Draw the Lewis structure.b. Write the valence shell electron configuration for C.c. Draw the valence orbital diagram for C.d. Draw the hybridized orbital diagram for C.e. Give a bond description for each bond in the molecule.arrow_forward
- Please help with this last question thank you.arrow_forward. Draw the Lewis diagram for acetamide. ( CH3CONH2) a. What is the electron geometry around each of the two carbon atoms. b. What is the hybridization type of each of the carbon atoms. c. What are the bond types and orbitals involved in bonding for all bonds between the C and O atoms.arrow_forward8. SO3 а. Lewis structure b. Drawing of shape (label angles) С. Name of shape d. Polar or nonpolar? e. Hybridization 9. NO, Lewis structure a. b. Drawing of shape (label angles) c. Name of shape d. Polar or nonpolar? e. Hybridization 10. ΗΝΟ, а. Lewis structure b. Drawing of shape (label angles) Name of shape С. d. Polar or nonpolar? , e. Hybridization 11 RoClarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry for Engineering StudentsChemistryISBN:9781337398909Author:Lawrence S. Brown, Tom HolmePublisher:Cengage Learning

Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning

Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning

Chemistry for Engineering Students
Chemistry
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Cengage Learning
