Module 7 Problem Set_ Principles of Organic Chemistry with Lab-2021-Gallaher
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Module 7 Problem Set: Principles of Organic Chemistry with Lab-2021-Gallaher
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Module 7 Problem Set
Due
No due date
Points
10
Questions
16
Time Limit
None
Attempt History
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Attempt 1
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10 out of 10
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This attempt took 26 minutes.
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Question 1
Your Answer:
Define the term
heterocycle
as it applies to organic molecules.
Heterocycles (heterocyclic compounds)
are cyclic organic molecules in
which one or more carbon atoms are replaced by
heteroatoms
– elements
other than carbon or hydrogen.
Answer:
Heterocycles (heterocyclic compounds)
are cyclic organic
molecules in which one or more carbon atoms are replaced by
heteroatoms
– elements other than carbon or hydrogen.
0 / 0 pts
Question 2
12/14/23, 8:43 PM
Module 7 Problem Set: Principles of Organic Chemistry with Lab-2021-Gallaher
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2/9
Your Answer:
What are the two main sub-groups of heterocyclic compounds?
aromatic and non-aromatic
Answer:
Aliphatic and Aromatic
0 / 0 pts
Question 3
Your Answer:
Explain why pyridine is soluble in water.
Pyridine can accept hydrogen bonding interactions due to the lone pair of
electrons in nitrogen. And the electronegative N creates a relatively strong
dipole moment, making it a polar compound.
Answer:
There are several factors that explain the ability of pyridine to
dissolve in water. First is the ability of pyridine to accept
hydrogen bonding interactions from water molecules due to
the lone pair of electrons on the nitrogen atom. In addition,
the electronegative nitrogen creates a relatively strong dipole
moment in the pyridine molecule, thus making pyridine a
polar compound overall.
12/14/23, 8:43 PM
Module 7 Problem Set: Principles of Organic Chemistry with Lab-2021-Gallaher
https://portagelearning.instructure.com/courses/1430/quizzes/35812?module_item_id=151533
3/9
0 / 0 pts
Question 4
Your Answer:
Is pyridine more likely to act as an acid or a base? Briefly
explain
.
Weak base
Answer:
Pyridine, like all amines, is a weak base. Amines use the lone
pair on the nitrogen atom to accept protons and thus, act as
bases.
0 / 0 pts
Question 5
Your Answer:
Name the two main classes of reactions that the pyridine molecule will
undergo.
Nucleophilic Aromatic Substitution, electrophilic aromatic substitution
Answer:
EAS – electrophilic aromatic substitution
And
NAS – nucleophilic aromatic substitution
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12/14/23, 8:43 PM
Module 7 Problem Set: Principles of Organic Chemistry with Lab-2021-Gallaher
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4/9
0 / 0 pts
Question 6
Your Answer:
Heterocyclic six-membered rings with two or more nitrogen atoms present
as part of the ring system are known as what type of heterocycles?
Azines
Answer:
Azines
0 / 0 pts
Question 7
Your Answer:
Why are the pyrimidines the most biologically important members of the
diazine family of molecules?
Derivatives of pyrimidines are important bases in the nucleic acids DNA
and RNA, namely, cytosine, thymine, and uracil.
Answer:
Derivatives of pyrimidines are important bases in the nucleic
acids DNA and RNA, namely, cytosine, thymine, and uracil.
0 / 0 pts
Question 8
12/14/23, 8:43 PM
Module 7 Problem Set: Principles of Organic Chemistry with Lab-2021-Gallaher
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5/9
Your Answer:
Name the most important five-membered heterocyclic compounds
containing a single heteroatom substitution and state which element is the
heteroatom in each.
furan, pyrrole, and thiophene
Answer:
The most important heterocyclic molecules with five-membered
rings are
furan
(oxygen-based),
pyrrole
(nitrogen-based), and
thiophene
(sulfur-based).
0 / 0 pts
Question 9
Your Answer:
What is the most important difference between five and six-membered
heterocycles in terms of the bonding at the heteroatom?
the heteroatom of a five-membered ring contributes two electrons (one
lone pair) to the aromatic
system of the ring to make the molecule
aromatic. This is in sharp contrast to six-membered heterocycles where
the heteroatom only contributes one electron to the aromatic
system.
12/14/23, 8:43 PM
Module 7 Problem Set: Principles of Organic Chemistry with Lab-2021-Gallaher
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6/9
Answer:
The heteroatom of a five-membered ring contributes two
electrons (one lone pair) to the aromatic
system of the ring
to make the molecule aromatic. This is in sharp contrast to
six-membered heterocycles where the heteroatom only
contributes one electron to the aromatic
system.
0 / 0 pts
Question 10
Your Answer:
Explain why pyrrole is a weaker base than pyridine, even though both are
aromatic, heterocyclic amines.
the availability of the lone pair. In pyridine, the lone pair is available (not
part of the aromatic
system) to accept an acidic proton. In pyrrole, this
is not the case
.
Answer:
This is due to the availability of the lone pair. In pyridine, the
lone pair is available (not part of the aromatic
system) to
accept an acidic proton. In pyrrole, this is not the case
.
Protonation of the lone pair of pyrrole destroys the aromatic
system
and the special stability of aromaticity; thus, pyrrole
is much less likely to accept an acidic proton on its nitrogen
atom.
0 / 0 pts
Question 11
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12/14/23, 8:43 PM
Module 7 Problem Set: Principles of Organic Chemistry with Lab-2021-Gallaher
https://portagelearning.instructure.com/courses/1430/quizzes/35812?module_item_id=151533
7/9
Your Answer:
Introduction of a nitrogen to the ring of furan, pyrrole, or thiophene creates
a family of heterocyclic compounds known as what?
azoles
.
Answer:
Azoles
0 / 0 pts
Question 12
Your Answer:
What is the definition of a
fused ring system
?
Two (or more) rings are fused together to form a larger molecule.
Answer:
In a fused-ring system, two (or more) rings are fused together
to form a larger molecule. To be
fused
means that each ring
shares two (or more) common atoms as a part of the structure
of each ring.
0 / 0 pts
Question 13
The molecule
indole has what ring fused to the C2-C3 bond of a pyrrole
ring?
12/14/23, 8:43 PM
Module 7 Problem Set: Principles of Organic Chemistry with Lab-2021-Gallaher
https://portagelearning.instructure.com/courses/1430/quizzes/35812?module_item_id=151533
8/9
Your Answer:
Fusing a benzene ring to the C2-C3 bond of pyrrole results in a bicyclic,
fused-ring compound known as
indole
Answer:
Benzene
0 / 0 pts
Question 14
Your Answer:
Adenine and guanine, two of the nitrogenous bases present in RNA and
DNA, contain what fused ring heterocycle?
Purines contain a pyrimidine ring fused to an imidazole ring
Answer:
Purine
0 / 0 pts
Question 15
Identify each of the following heterocycles by name:
12/14/23, 8:43 PM
Module 7 Problem Set: Principles of Organic Chemistry with Lab-2021-Gallaher
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9/9
Your Answer:
A. indole
B. imidazole
C. pyrrole
D. pyridine
Answer:
a. Indole
b. Imidazole
c. Pyrrole
d. Pyridine
10 / 10 pts
Question 16
Your Answer:
As a reminder, the questions in this review quiz are a requirement of the
course and the best way to prepare for the module exam. Did you
complete all questions in their entirety?
Yes
Quiz Score:
10
out of 10
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AIV-20: Getting Connected (Writing lonic Compounds)
Part 1: Putting together lonic Compounds
lonic compound
Metal
Number of
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valence
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8.
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7
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8
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O CHEMICAL REACTIONS
David V
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Solving for a reactant using a chemical equation
Green plants use light from the Sun to drive photosynthesis. Photosynthesis is a chemical reaction in which water (H,0) and carbon dioxide (CO, chemically
react to form the simple sugar glucose (C,H1206) and oxygen gas (0,).
What mass of carbon dioxide is consumed by the reaction of 8,82 g of water?
Be sure your answer has the correct number of significant digits.
Explanadon
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