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University of Toronto *

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MSE318

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Chemistry

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Oct 30, 2023

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Modules B1-B3: Atomic Mechanisms of Diffusion, Interstitial Diffusion, Substitutional Diffusion There are namely two mechanisms of diffusion: (i) interstitial diffusion and (ii) substitutional diffusion. As the name implies, interstitial diffusion refers to movement of solute atoms that are occupying the interstitial sites between the solvent atoms, as schematically shown in Figure 1. In order for the interstitial atoms to jump to another interstitial site, it must overcome the activation barrier for atom migration, as shown in Figure 2. In the lecture, we will describe the equations that describe the diffusivity of interstitial atoms. Figure 1: Interstitial atom diffusing by interstitial mechanism. Figure 2: Free energy of the lattice as a function of interstitial atom position For substitutional diffusion, there is an additional requirement that the neighbour site must be vacant, in addition to having the sufficient energy to force atoms apart before the substitutional atom jump to vacant site, as schematically shown in Figure 3. Figure 3: Substitutional diffusion next to a vacancy Suggested reading: Porter and Easterling, Section 2.1, 2.2.1, 2.2.2, 2.3.1, 2.3.2
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