VCU CHEM301 Su21 Midterm #1 CHEM-301-002-SU2021 - ORGANIC CHEMISTRY I
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Virginia Commonwealth University *
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301
Subject
Chemistry
Date
Feb 20, 2024
Type
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Uploaded by MateThunderPartridge30
VCU CHEM301 Su21 Midterm #1
Due
Jun 27 at 11:59pm
Points
115.17
Questions
33
Available
Jun 25 at 6pm - Jun 29 at 11:59pm 4 days
Time Limit
75 Minutes
Instructions
This quiz was locked Jun 29 at 11:59pm.
Attempt History
Attempt
Time
Score
LATEST
Attempt 1
73 minutes
69.8 out of 115.17
Score for this quiz: 69.8
out of 115.17
Submitted Jun 27 at 11:38pm
This attempt took 73 minutes.
The Chemistry Department supports the VCU HONOR SYSTEM and operates within its guidelines.
The Honor System must be upheld and enforced by each member of the Virginia Commonwealth
University community. The fundamental attributes of our community are honor and integrity.
By taking this exam, you are agreeing to abide by the full VCU Honor Policy. You may NOT have help of any kind on this exam. All work submitted, must be your own.
You may NOT give any help to another student on this exam.
You are NOT allowed to use your notes, Lecture Slides, textbook, or similar material. You are NOT
allowed to use any online resource.
You are allowed to use a calculator that DOES NOT connect to Wi-Fi, cellular, etc. and scrap paper
as needed.
3.49 / 3.49 pts
Question 1
The compound methylamine, CH
NH
, contains a C-N bond. In this
3
2
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bond, which of the following best describes the charge on the carbon
atom?
partial positive charge
Correct!
Correct!
3.49 / 3.49 pts
Question 2
Which of the following are acceptable Lewis structures, including formal
charges, for nitric acid, HNO
?
3
B only
Correct!
Correct!
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3.49 / 3.49 pts
Question 3
Which of the following bonding patterns of carbon is not allowed in the
formation of an organic compound?
F
Correct!
Correct!
3.49 / 3.49 pts
Question 4
Which of the following structures (a-d) is another resonance structure of
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the following organic molecule?
B
Correct!
Correct!
0 / 3.49 pts
Question 5
Which of the following choices represent(s) a pair of resonance forms?
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C
ou Answered
ou Answered
both B and C
orrect Answer
orrect Answer
3.49 / 3.49 pts
Question 6
Which of the following condensed formulas represents the same
compound as the line-angle structure shown?
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CH CH OCH N(CH CH )
Correct!
Correct!
3
2
2
2
3 2
0 / 3.49 pts
Question 7
When methanol (CH
OH) acts as a base, its conjugate acid is
________.
3
CH O
ou Answered
ou Answered
3
─
CH OH
orrect Answer
orrect Answer
3
2
+
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3.49 / 3.49 pts
Question 8
Which of the following pairs of bases lists the stronger base first?
H
N
> CH
COO
Correct!
Correct!
2
─
3
─
3.49 / 3.49 pts
Question 9
Which proton is the most acidic in the compound below?
2
Correct!
Correct!
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0 / 3.49 pts
Question 10
How many carbon-carbon σ bonds are present in the molecule shown?
3
ou Answered
ou Answered
5
orrect Answer
orrect Answer
3.49 / 3.49 pts
Question 11
Which of the following statements about π bonds is/are correct?
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Most of the electron density in a π bond is centered above and below
the internuclear axis.
Correct!
Correct!
0 / 3.49 pts
Question 12
Based on the structure below, what is the value for the H-N-CH
bond
angle?
3
120 degrees
orrect Answer
orrect Answer
109 degrees
ou Answered
ou Answered
0 / 3.49 pts
Question 13
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In the structure below, the hybridization of the oxygen is ________ and
the C-O-C bond angle is ________.
sp
; <109.5°
orrect Answer
orrect Answer
3
sp; 120°
ou Answered
ou Answered
3.49 / 3.49 pts
Question 14
Shown below is one of the sex pheremones from the butterfly family.
How many sp
hybridized carbon atoms
are present in this molecule?
2
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5
Correct!
Correct!
0 / 3.49 pts
Question 15
Triethylamine [(CH
CH
)
N] is a molecule in which the nitrogen atom is
________ hybridized and the C-N-C bond angle is ________.
HINT: Draw this compound...
3
2 3
sp
; <109.5°
orrect Answer
orrect Answer
3
sp
; >109.5°
ou Answered
ou Answered
2
3.49 / 3.49 pts
Question 16
Which of the labeled atoms in the following structure are
sp
hybridized?
2
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2 & 3
Correct!
Correct!
3.49 / 3.49 pts
Question 17
Which one of the molecules shown below has a net molecular dipole
moment?
CH CCl
Correct!
Correct!
3
3
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3.49 / 3.49 pts
Question 18
What intermolecular forces are present among molecules in dimethyl
ether, CH
OCH ?
3
3
both London dispersion forces and dipole-dipole forces
Correct!
Correct!
0 / 3.49 pts
Question 19
Which of the following functional groups is not present in the HIV
protease inhibitor drug called Saquinavir, shown below?
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amine
ou Answered
ou Answered
ketone
orrect Answer
orrect Answer
0 / 3.49 pts
Question 20
Rank the following compounds in order of acidity (strongest acid to
weakest acid).
I>III>IV>II
orrect Answer
orrect Answer
II>IV>III>I
ou Answered
ou Answered
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Question 21
How many secondary (2°) carbons are found in 5-ethyl-3,3,4-
trimethylheptane?
HINT: Draw out this compound, it will be MUCH easier to solve.
3
Correct!
Correct!
3.49 / 3.49 pts
Question 22
Consider the three isomeric alkanes n
-hexane, 2,3-dimethylbutane, and
2-methylpentane. Which of the following correctly lists these
compounds in order of increasing boiling point (lowest boiling point to
highest)?
HINT: Draw out these three compounds, it will be MUCH easier to
solve.
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2,3-dimethylbutane < 2-methylpentane < n
-hexane
Correct!
Correct!
0 / 3.49 pts
Question 23
The structures below are ________.
structural isomers
orrect Answer
orrect Answer
not isomers
ou Answered
ou Answered
3.49 / 3.49 pts
Question 24
Which of the following statements concerning the C
-C
2
3
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conformers (rotation around the C
-C
bond) of butane is true?
2
3
The gauche and anti conformers differ primarily in the amount of steric
strain present.
Correct!
Correct!
0 / 3.49 pts
Question 25
Identify the correct IUPAC name for the structure shown below.
HINT: This is a little tricky...
1-
tert
-butyl-2-chloro-5-bromocycloheptane
ou Answered
ou Answered
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5-bromo-1-
tert
-butyl-2-chlorocycloheptane
orrect Answer
orrect Answer
3.49 / 3.49 pts
Question 26
Which of the following correctly ranks the cycloalkanes (cyclobutane,
cyclohexane, cyclopentane, and cyclopropane) in order of increasing
(lowest to highest) ring strain?
HINT: Draw out these four compounds...
cyclohexane < cyclopentane < cyclobutane < cyclopropane
Correct!
Correct!
0 / 3.49 pts
Question 27
In the lowest energy chair conformation of cis
-1,3-dimethylcyclohexane,
how many axial positions are occupied by hydrogen atoms?
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HINT: To start, draw the chair conformations of cis-1,3-
dimethylcyclohexane...
6
orrect Answer
orrect Answer
3
ou Answered
ou Answered
0 / 3.49 pts
Question 28
Which of the statements below correctly describes the chair
conformations of trans
-1,4-dimethylcyclohexane?
HINT: To start, draw the chair conformations of trans-1,4-
dimethylcyclohexane...
The two chair conformations are of equal energy.
ou Answered
ou Answered
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The higher energy chair conformation contains two axial methyl groups.
orrect Answer
orrect Answer
0 / 3.49 pts
Question 29
Which of the statements below correctly describes the chair
conformations of trans
-1,3-diethylcyclohexane?
HINT: To start, draw the chair conformations of trans-1,3-
diethylcyclohexane...
The lower energy chair conformation contains two equatorial ethyl
groups.
ou Answered
ou Answered
The two chair conformations are equal in energy.
orrect Answer
orrect Answer
3.49 / 3.49 pts
Question 30
In the lowest energy conformation of the compound below, how many
alkyl substituents are equatorial?
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HINT: To start, draw the chair conformations of this compound...
2
Correct!
Correct!
3.49 / 3.49 pts
Question 31
In the lowest energy conformation of the compound below, how many
alkyl substituents are axial?
HINT: To start, draw the chair conformations of this compound...
0
Correct!
Correct!
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3.49 / 3.49 pts
Question 32
Arrange the following Newman projections of butane in order of energy
(lowest to highest).
I < III < II < IV
Correct!
Correct!
3.49 / 3.49 pts
Question 33
Which line-angle formula corresponds to the chair conformation shown
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below?
III
Correct!
Correct!
Quiz Score: 69.8
out of 115.17
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Quèstion 6
Select the statement that is not supported by the following equation:
q=0=(mwater)(Cwater)(ATwater)+ (mmetal)(Cmetal)( ATmetal)
The total change in heat is the sum of the changes in heat of water and a metal.
Energy is conserved.
Energy is transferred between water and a metal.
Energy is lost during a calorimetry experiment.
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5.
Use the MS data to answer the questions on the next page.
14.0
1.4
15.0
8.1
100-
MS-IW-5644
26.0
2.8
27.0
6.7
28.0
1.8
29.0
80
4.4
38.0
1.0
39.0
1.5
41.0
1.2
42.0
11.2
43.0
100.0
44.0
4.3
79.0
1.9
80.0
2.6
Relative Intensity
40
81.0
1.9
82.0
2.5
93.0
8.7
20-
95.0
8.2
121.0
2.0
123.0
2.0
136.0
11.8
0
138.0
11.5
20
40
8.
60
a.
Br
- 0
80
100
120
140
160
180
200
220
m/z
Identify the m/z of the base peak and molecular ion.
2
b.
Draw structures for each of the following fragments (include electrons and charges): 43.0, 93.0,
95.0, 136.0, and 138.0 m/z.
C.
Draw a reasonable a-fragmentation mechanism for the fragmentation of the molecular ion to
fragment 43.0 m/z. Be sure to include all electrons and formal charges.
6. Using the values provided in Appendix E of your lab manual, calculate the monoisotopic mass for the pyridinium
ion (CsH6N) and show your work.
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Instructions You are required to produce a short lab report using the information given in the accompanying document, ‘Lab report assessment_student data’. This document introduces an experiment, and also provides a set of experimental data for this experiment. You are required to use this data to perform steps 8 and 9 of the procedure. This includes calculations of a particular value, and then comparison to the true value. Consider any experimental errors when comparing calculated values and true values. Your report should be between 300 and 500 words (including all table contents and titles of tables and graphs). Your lab report should consist of three sections only: • Experimental • Results and Discussion • Conclusion You do NOT need to include an introduction section. Your experimental section should be written in appropriate lab report format, (passive voice, 3 rd person, in paragraphs). Your results and discussion section should contain the data presented in table format, and…
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Question 5 (1 point)
Ben starts walking along a path at 3 mi hr¹. Amanda starts jogging along the same path 1 hour later at 5 mi hr. After how much
time jogging does Amanda catch up to Ben?
3.5 hr
2.5 hr
2 hr
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It takes 155 s for an unknown gas to effuse through a porous wall and 97 s for the same volume of N2
gas to effuse at the same temperature and pressure. What is the molar mass of the unknown gas?
g/mol
...
115
MAR
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Question 10 (Mandatory)
1) Listen>
What is the absolute error of the answer for the following operation? (8.12 +- 0.03)-(3.12+-0.02) =
0.04
0.05
0.02
O 0.007
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Group-12 )436 9 10 11 12 13 14 15 16 17 10
Irerlod
The Perlodic Table of the Elements
Elements in the same group tend to have similar characteristics, but some things like tendency to gain or lose electrons can still vary
even within a group Which of the following is true regarding the elements in group 2?
O A Be, Beryllium is the largest and has the greatest tendency to gain electrons.
OB Be Beryllium and Ba, Barium will have the same tendancy to lose electrons
OC Ra, Radium is the smallest and will have the greatest tendency to lose electrons.
O D. Ba, Barium will have a greater tendency to lose electrons than Mg, Magnesium.
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Calculate the difference between AH and AU when 1.0 mol Sn (gray) of density 5.75 g cm3
changes to Sn (white) of density 7.31 g•cm3 at 10.0 bar. Molar mass of Sn = 118.71 g•mol-!.
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237 g
Use the References to access important values if needed for this question.
A copy of your chemistry textbook is found to have a mass of 2310 grams.
Using unit analysis, show what the mass of this copy of your chemistry textbook is in
ounces.
12 oz
7. Unit Conversion: Metric/Standard: This is group attempt 1 of 5
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Oz
Drag and drop your selection from the following list to complete the answer:
28.3 g
2.20 lb
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()
16 oz
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