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Chemistry

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Nov 24, 2024

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Quarter 3: 7) SC.912.P.8.9 - Mole conversions ( 9/50 questions = 20% of your EOC!!!! ) Vocabulary: chem4kids - http://tinyurl.com/5gykqx PP - http://tinyurl.com/ntj4xx3 Law of Conservation of mass- in a chemical reaction mass is neither created nor destroyed. Moles- 6.02 x 10 ^23 Molarity - a unit of concentration expressed as the number of moles of dissolved solute per liter of solution. Molar Mass - the sum of all element in a compound Molar ratio - the ratio of the amount in moles of one substance to the amount in moles of another substance Avogadro's # - 6.02 x 10 ^23 Stoichiometry - a section of chemistry that involves using relationships between reactants and/or products in a chemical reaction to determine desired quantitative data. Limiting reactant - the reactant that gets consumed first in a chemical reaction and therefore limits how much product can be formed. Excess reactant - a substance that is not wholly consumed or entirely reacted in a chemical reaction. % yield - a measure of the quantity of moles of a product formed in relation to the reactant consumed, obtained in a chemical reaction, usually expressed as a percentage
Balancing Equations - http://tinyurl.com/q8ev6d4 1. __6__ H 2 + _3___ O 2 _6___H 2 O 2. _2___ Al 2 O 3 _2___ Al + __3__ O 2 3. _2___ KClO 3 _2___ KCl + _3___ O 2 4. __2__ Al + __3__ Br 2 _2___ AlBr 3 5. _3___ AgNO 3 + __1__ K 3 PO 4 __1__ Ag 3 PO 4 + __3__ KNO 3 6. _1___ Al 2 (SO 4 ) 3 + __3__ Ca(OH) 2 → _2___ Al(OH) 3 + _3___ CaSO 4 Mole ↔ Grams Conversions: Example: 1. How many moles of carbon dioxide, CO 2 , are in a 22 gram sample of the compound? 22 grams CO 2 X __q__6.02x 10_____moles CO 2 = __3.00x10^23____ moles of CO 2 44.01 grams CO 2 2. What is the mass of 0.5 moles of carbon tetrafluoride, CF 4 ? 0.5 moles of CF 4 X_88.01________grams CF 4 = __7.30 x 10 ^-23____ grams of CF 4 6.02 x10^23 moles CF 4 3. How many moles of water are in 360 grams of water? 360 grams H 2 O X __6.02…__________ = __2.16 x 10 ^26____ moles H 2 O
4. What is the mass of 2.5 moles of hydrogen fluoride gas, HF? 2.5 moles of HF X ___20.1_________ = __50.025____ grams HF 5. What is the mass of 5 moles of nitrogen gas, N 2 ? 5 moles N 2 X ___28_________ = __140____ grams of N 2 6. How many moles of ammonia, NH 3 , are in 51 grams of NH 3 ? 51 grams of NH 3 ___6.02…_________ = ___3.07 x 10 ^25___ moles NH 3 Grams ↔ Liters Conversions: Example: 1. What volume is occupied by 4 grams of hydrogen molecules (H 2 ) at standard conditions? 4 grams H 2 X ___2.02_________ X ____22.4________ = ___87.7___ Liters H 2 2. What is the volume occupied by 40 grams of argon gas (Ar) at standard conditions? 40 grams Ar X ____40________ X ___22.4_________ = _22.4_____ Liters Ar 3. What is the mass occupied by 44.8 L of Nitrogen (N 2 ) at standard conditions? 44.8 L N 2 X ____28________ X ____22.4________ = ___35.84___ grams N 2 4. What is the mass occupied by 11.2 L of Chlorine Cl 2 at standard conditions? 11.2 L Cl 2 X _____70.9_______ X ____22.4________ = __3.5____ grams Cl 2 Grams ↔ Atoms Conversions: Example:
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1. How many atoms are occupied by 10 grams of Br 2 at STP? 10 grams Br 2 X ______160______ X ____6.02…________ = __3.76 x 10 ^22____ atoms Br 2 2. How many atoms are occupied by 44.8 L of He at STP? 44.8 L He X ____8________ X ____6.02…________ = __3.37 x 10 ^24____ atoms He 3. What volume, in liters, is occupied by 1.5 x 10 23 atoms of argon gas (Ar) at STP? 1.5 x 10 23 atoms X ___6.02…_________ X ____22.4________ = __5.58____ Liters Ar 4. What mass, in grams does 12.04 x 10 23 atoms of Carbon weigh at STP? 12.04 x 10 23 atoms C X __6.02…__________ X ___12_________ = ___24.7___ g C Molarity Conversions: Example : Concentration Simulation - http://tinyurl.com/k346tyn Molarity Simulation- http://tinyurl.com/pm6nwjn 1. What is the molarity of a solution in which 51 grams of aluminum oxide, Al 2 O 3 , is dissolved in 500 mL of solution?
51 grams Al 2 O 3 X ___6.02 x 10^23_________ = __3.0 x 10 ^25____ moles Al 2 O 3 500 mL X ___22.4_________ = __11200____ Liters Al 2 O 3 MOLARITY = _2.6_____ moles Al 2 O 3 Liters Al 2 O 3 2. A solution with a volume of 250 mL contains 10 grams of hydrogen fluoride, HF. What is the molarity of the solution? 10 grams HF X _____20_______ = ___200___ moles HF 250 mL X ___22.4_________ = __5600____ Liters HF MOLARITY = __.03____ moles HF Liters HF 3. What mass of Na 2 SO 4 is needed to make 2.5 L of 2.0M solution? Stoichiometry : 1. How many grams of oxygen are required to burn 48.8 liters of ethane gas, C 2 H 6 at STP? 2 C 2 H 6 ( g ) + 7 O 2 ( g ) → 4 CO 2 ( g ) + 6 H 2 O ( g ) Given Find 48.8 L C 2 H 6 X 1 mole C 2 H 6 X _ _7 __mole O 2 X _32___grams O 2 = __244____ grams O 2 22.4 L C 2 H 6 2 mole C 2 H 6 1 mole O 2 2. . How many grams of water can be prepared from 8 grams of hydrogen at STP? 2 H 2 ( g ) + O 2 ( g ) → 2 H 2 O Given Find
8 grams H 2 X 1 mole H 2 X __2__mole H 2 O X 18.02___grams H 2 O = __71.3____ grams H 2 O 2.02 g H 2 2 mole H 2 1 mole H 2 O 3. How many liters of oxygen are required to react completely with 22.4 liters of carbon monoxide , CO, at STP? 2 CO ( g ) + O 2 ( g ) → 2 CO 2 ( g ) Given Find 22.4 L CO X 1 mole CO X __1__mole O 2 X _22.4___ Liters O 2 = __11.2____ Liters O 2 22.4L CO 2 mole CO 1 mole O 2 Stoichiometry : Limiting Reagents Example: 1. 6Na + Fe 2 O 3 --> 3Na 2 O + 2Fe If you are provided 200g of sodium and 250 grams of iron(III) oxide, which substance is the limiting & excess reactant? 200 g Na X __1___ mole Na X __1___ mole Fe = _1.4____ mole Fe 23 gram Na 6 mole Na 250 g Fe 2 O 3 X __1___ mole Fe 2 O 3 X __2___ mole Fe = __3.1___ mole Fe 159.6 gram Fe 2 O 3 1 mole Fe 2 O 3 Which reactant was used up first? __Na____ = Limiting Reactant Which reactant was left over? __Fe2O3____ = Excess Reactant
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Stoichiometry : % yield 8) SC.912.P.12.10 - Gases & KMT ( 3/50 questions) KMT PP - http://tinyurl.com/lxsn2r9 Vocabulary: @ STP 1 mole = ____6.02 x 10^23____________ atoms = ___22.4______ Liters Kinetic Molecular Theory Postulates : http://tinyurl.com/dg2a9w 1. the particles in a gas are in constant, random motion 2. the combined volume of the particles is negligible 3. the particles exert no forces on one another 4. any collisions between the particles are completely elastic 5. the average kinetic energy of the particles is proportional to the temperature in kelvins What causes pressure ? Compression of molecule in a limited space
Temperature is a measure of ? the average kinetic energy of the particles in a substance. What is Absolute Temperature? Kelvin Scale = K Celsius = C Freezing Water ? +273ºK 0 Evaporating Water ? 373 kelvin. 100° C Explain the Gas Law Relationships PP - Gas Laws http://tinyurl.com/nxxn7m3 Pressure vs Volume ( http://tinyurl.com/phurqe3 ) Boye’s law P1V1=P2V2 Pressure and volume have an indirect relationship Volume vs Temperature ( http://tinyurl.com/owde33l ) Charles's law V1/T1=V2/T2 Volume and temperature have a direct relationship Pressure vs Temperature ( http://tinyurl.com/n2xehnv ) Gay-Lussac law P1/T1=P2/T2 Pressure and temperature have a direct relationship Combined Gas Law: Temperature has to be in KELVINS !!!
1. At constant pressure, a sample of gas occupies 420 mL at 210 K. What volume does the gas occupy at 250 K? 500ml 2. A chemist produces 460 mL of oxygen gas at - 43 °C and constant pressure. To what Celsius temperature must the oxygen be warmed in order for it to have a volume of 600 mL? 1200 K 3. A 900 liter supply of xenon gas is held at 27 °C and 100 kPa. When the temperature is lowered to -73 °C, what pressure must be applied to compress the gas to 200 liters? 300 kpa Ideal Gas Law: Temperature has to be in KELVINS !!! 1. How many moles of oxygen must be placed in a 3.00 liter container in order to exert a pressure of 2.00 atmospheres at 25 °C? (R = 0.0821) .245 moles 2. At 17 °C, a 0.80 mole sample of a gas exerts a pressure of 1.2 atmospheres. What is the volume of the container? (R = 0.0821) 15.87 3. A 7.50 liter sealed jar at 18 °C contains 0.125 moles of oxygen and 0.125 moles of nitrogen gas. What is the pressure in the container? (R = 0.0821)
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.39 9) SC.912.P.10.7 - Heat ( 2/50 questions) Exothermic vs Endothermic ? PP - http://tinyurl.com/qyfr2of Exo or Endo ? Exo or Endo ? Vocabulary: Δ H (Heat or Enthalpy) - change in heat or enthalpy Exothermic (- Δ H) : means energy exits the system into the surrounding Endothermic (+ Δ H) : means energy enter the system from the surrounding Activation Energy - the minimum amount of energy that is required to activate atoms or molecules to a condition in which they can undergo chemical transformation or physical transport. Interactives: 1. Heating Curve 2. Heating Curve Label the Chart: Solid Liquid Gas Melting Condensation Freezing Boiling Exothermic or Endothermic ? Boiling - Condensation - Melting - Freezing -
Scenario Exothermic vs Endothermic ? Ice melting endo Gas vapor condensing into liquid endo Liquid vaporizing (boiling) into a gas exo Liquid freezing endo Hot pack exo Cold pack endo ( - H) or Negative change in Enthalpy ? exo ( + H) or Positive change in Enthalpy ? endo 10) SC.912.P.10.1 - Heat Transfer ( 3/50 questions) Specific Heat - http://tinyurl.com/a3q6qtn Heat Curve for water - Heating Curve & Heating Curve Vocabulary: Conservation of Energy (system vs surroundings)- matter cannot be created or destroyed. Specific Heat Capacity - the amount of heat needed to raise the temperature of 1 gram of a substance 1 degree Celsius (°C). Specific Heat Capacity (C) of water? 4,184 Joules of heat (1 kilocalorie) for the temperature of one kilogram of water to increase 1°C. Temperature - the average kinetic energy of all the atoms or molecules of that
substance. Heat of Chemical Reaction - the energy that is released or absorbed when chemicals are transformed in a chemical reaction. Q=mC Δ T 1. What energy change has occurred when 500 grams of water cools from 35°C to 25°C? a. 20 900 joules b. 11.96 joules c. -1196 joules d. -20 900 joules 2. Is the answer to question #1 Exothermic or Endothermic? Explain. a. Will the reaction feel like it's getting “hotter” or “colder”? Getting hotter will means that the energy form the surrounding will go into your system and getting colder means that the energy will exits your system 3. How many joules of heat energy are required to raise the temperature of 20 grams of water by 50°C? a. 4180 joules b. 19.7 joules c. 239.2 joules d. 0.00418 joules 4. Is the answer to question #3 Exothermic or Endothermic? Explain. a. Will the reaction feel like it’s getting “hotter” or “colder”? Getting hotter will means that the energy form the surrounding will go into your system and getting colder means that the energy will exits your system https://chemquiz.net/gas?a=3974 https://chemquiz.net/cal?a=3973 https://chemquiz.net/per?a=3976 https://chemquiz.net/sto?a=3975 https://chemquiz.net/sto?a=3977
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