Introductory Chemistry: Concepts and Critical Thinking (8th Edition)
Introductory Chemistry: Concepts and Critical Thinking (8th Edition)
8th Edition
ISBN: 9780134421377
Author: Charles H Corwin
Publisher: PEARSON
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Chapter PSS, Problem 8ST
Interpretation Introduction

Interpretation:

Whether it is better to round off after each step, or round off the final answer in the calculator display is to be stated.

Concept introduction:

The significant numbers are taken by counting the digits from left to right and starting by the first non-zero digit. The process of eliminating the non-significant digit is known as the rounding off. This rounding off follows three rules which are stated below as:

Rule 1: If the first non-significant digit is less than 5 then all the non-significant digits are dropped.

Rule 2: If the first non-significant digit is equal to or greater than 5 then last significant digit is increased by 1 and dropped all the non-significant digits.

Rule 3: In a multistep calculation the non-significant digits are taken in all the steps.

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3. SYNTHESIS. Propose a sequence of synthetic steps (FGI) that convert the starting material (SM) into the Target molecule. For each FGI in your proposed synthesis, specify the reagents / conditions, and draw the product(s) of that FGI. DO NOT INCLUDE the FGI mxn in the answer you submit. If an FGI requires two reagent sets, specify the order in which the reagent sets are added, e.g., i) Hg(OAc)2 / H₂O; ii) NaBH4/MeOH. Indicate the stereochemistry (if any) of the products of each FGI. FGI 1. Me Starting Material Source of all carbons in the Target molecule (can use multiple copies) Me Me Target molecule + enantiomer
curved arrows are used to illustate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction mechanism steps

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