12th Edition

ISBN: 9781118875766

Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder

Publisher: WILEY

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Textbook Question

Chapter H, Problem 5PP

Practice Problem H.5

Many alkaloids appear to be synthesized in plants by reactions that resemble the Mannich reaction (Section 19.8). Recognition of this (by R. Robinson in 1917) led to a synthesis of tropinone that takes place under “physiological conditions,” that is, at room temperature and at pH values near neutrality. This synthesis is shown here (and discussed in “Why These Topics Matter” at the end of Chapter 19). Propose reasonable mechanisms that account for the overall course of the reaction.

Chapter H, Problem 5PP, Practice Problem H.5
Many alkaloids appear to be synthesized in plants by reactions that resemble

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Chapter H, Problem 4PP

Chapter H, Problem 6PP

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Chapter H Solutions

Organic Chemistry

Ch. H - Prob. 1PP Ch. H - Prob. 2PP Ch. H - Prob. 3PP Ch. H - Practice Problem H.4 In 1891 G. Merling...Ch. H - Practice Problem H.5 Many alkaloids appear to be...Ch. H - Practice Problem H.6 Papaverine has been...Ch. H - Practice Problem H.7 One of the important steps in...Ch. H - Prob. 8PP Ch. H - Practice Problem H.9 Gramine has been synthesized...

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