EBK ORGANIC CHEMISTRY
EBK ORGANIC CHEMISTRY
12th Edition
ISBN: 9781119233664
Author: Snyder
Publisher: VST
Question
Book Icon
Chapter FRP, Problem 17P
Interpretation Introduction

Interpretation:

A resonance explanation for the ability of halides of the type ROCH2X to undergo SN1 reactions is to be proposed.

Concept introduction:

The rules for drawing resonance structures are as follows:

Only nonbonding electron pairs and pi electrons can participate in conjugation in the formation of various resonating structures.

The single bonds present in the molecule do not break or form in the resonance structures.

The placement of atoms present in the molecule remains fixed.

The octet of all atoms is completely filled.

The resonance effect is the withdrawal or release of electrons through delocalization of π electrons. Compounds that contain double bonds in their structures are made up by the overlap of p-orbitals on two adjacent carbon atoms.

Inductive effect is the electronic effect that arises due to electronegativity difference between the atoms at either end of the bonds.

Primary alkyl halide undergoes SN2 mechanism because primary carbocations are not stable and the substrates have less steric hindrance to nucleophilic attack.

Electron withdrawing groups attract electron density toward itself and draw electrons away from the reaction centre.

Electron donating group donate electron density or releases electrons into the reaction centre.

Alkyl group is an electron donating group.

Blurred answer
Students have asked these similar questions
Name the molecules & Identify any chiral center CH3CH2CH2CHCH₂CH₂CH₂CH₂ OH CH₂CHCH2CH3 Br CH3 CH3CHCH2CHCH2CH3 CH3
Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electrons-pushing arrows for the following reaction or mechanistic step(s).
Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electrons-pushing arrows for the following reaction or mechanistic step(s).

Chapter FRP Solutions

EBK ORGANIC CHEMISTRY

Knowledge Booster
Background pattern image
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
  • Text book image
    Organic Chemistry
    Chemistry
    ISBN:9781305080485
    Author:John E. McMurry
    Publisher:Cengage Learning
    Text book image
    Pushing Electrons
    Chemistry
    ISBN:9781133951889
    Author:Weeks, Daniel P.
    Publisher:Cengage Learning
Text book image
Organic Chemistry
Chemistry
ISBN:9781305080485
Author:John E. McMurry
Publisher:Cengage Learning
Text book image
Pushing Electrons
Chemistry
ISBN:9781133951889
Author:Weeks, Daniel P.
Publisher:Cengage Learning