(a) Interpretation: The structure is to be drawn, and the correct IUPAC name for the given trivial name is to be provided. Concept introduction: Most of the trivial names of aldehydes are derived from the analogous carboxylic acids. For a straight chain aldehyde, the carbonyl carbon gets number one. For cyclic aldehydes, the carbonyl carbon cannot be the part of the ring, and thus, it must be present outside the ring. To write the IUPAC name of a compound, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. The suffix al is used for aldehydes. Then the main chain or ring is to be determined that contains the highest-priority functional group. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless redundant. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order.

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Answer 1

Question

Chapter E, Problem E.22P

Interpretation Introduction

(a)

Interpretation:

The structure is to be drawn, and the correct IUPAC name for the given trivial name is to be provided.

Concept introduction:

Most of the trivial names of aldehydes are derived from the analogous carboxylic acids.

For a straight chain aldehyde, the carbonyl carbon gets number one. For cyclic aldehydes, the carbonyl carbon cannot be the part of the ring, and thus, it must be present outside the ring.

To write the IUPAC name of a compound, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. The suffix al is used for aldehydes. Then the main chain or ring is to be determined that contains the highest-priority functional group. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless redundant. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order.

Interpretation Introduction

(b)

Interpretation:

The structure is to be drawn, and the correct IUPAC name for the given trivial name is to be provided.

Concept introduction:

Most of the trivial names of aldehydes are derived from the analogous carboxylic acids.

For a straight chain aldehyde, the carbonyl carbon gets number one. For cyclic aldehydes, the carbonyl carbon cannot be the part of the ring, and thus, it must be present outside the ring.

To write the IUPAC name of a compound, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. The suffix al is used for aldehydes. Then the main chain or ring is to be determined that contains the highest-priority functional group. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless redundant. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order.

Interpretation Introduction

(c)

Interpretation:

The structure is to be drawn, and the correct IUPAC name for the given trivial name is to be provided.

Concept introduction:

Most of the trivial names of aldehydes are derived from the analogous carboxylic acids.

For a straight chain aldehyde, the carbonyl carbon gets number one. For cyclic aldehydes, the carbonyl carbon cannot be the part of the ring, and thus, it must be present outside the ring.

To write the IUPAC name of a compound, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. The suffix al is used for aldehydes. Then the main chain or ring is to be determined that contains the highest-priority functional group. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless redundant. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order.

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scratch paper, and the integrated rate table provided in class. our scratch work for this test. Content attribution 3/40 FEEDBACK QUESTION 3 - 4 POINTS Complete the equation that relates the rate of consumption of H+ and the rate of formation of Br2 for the given reaction. 5Br (aq) + BrO3 (aq) + 6H (aq) →3Br2(aq) + 3H2O(l) • Your answers should be whole numbers or fractions without any decimal places. Provide your answer below: Search 尚 5 fn 40 * 00 99+ 2 9 144 a [

(a) Write down the structure of EDTA molecule and show the complex structure with Pb2+ . (b) When do you need to perform back titration? (c) Ni2+ can be analyzed by a back titration using standard Zn2+ at pH 5.5 with xylenol orange indicator. A solution containing 25.00 mL of Ni2+ in dilute HCl is treated with 25.00 mL of 0.05283 M Na2EDTA. The solution is neutralized with NaOH, and the pH is adjusted to 5.5 with acetate buffer. The solution turns yellow when a few drops of indicator are added. Titration with 0.02299 M Zn2+ requires 17.61 mL to reach the red end point. What is the molarity of Ni2+ in the unknown?

A compound has the molecular formula CH40, and shows a strong IR absorption at 2850-3150 cm. The following signals appear in the 'H NMR spectrum: 1.4 ppm (triplet, 6H), 4.0 ppm (quartet, 4H), 6.8 ppm (broad singlet, 4H). Which of the following structures is consistent with these data? Select the single best answer. OCH CH₂ x OCH2CH3 CH₂OCH3 OH CH₂OCH OH CH, OCH₁ CH₂OCH, CH₂OCH HO OH ° CH₂OCH3

Answer 2

Question

Chapter E, Problem E.22P

Interpretation Introduction

(a)

Interpretation:

The structure is to be drawn, and the correct IUPAC name for the given trivial name is to be provided.

Concept introduction:

Most of the trivial names of aldehydes are derived from the analogous carboxylic acids.

For a straight chain aldehyde, the carbonyl carbon gets number one. For cyclic aldehydes, the carbonyl carbon cannot be the part of the ring, and thus, it must be present outside the ring.

To write the IUPAC name of a compound, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. The suffix al is used for aldehydes. Then the main chain or ring is to be determined that contains the highest-priority functional group. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless redundant. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order.

Interpretation Introduction

(b)

Interpretation:

The structure is to be drawn, and the correct IUPAC name for the given trivial name is to be provided.

Concept introduction:

Most of the trivial names of aldehydes are derived from the analogous carboxylic acids.

For a straight chain aldehyde, the carbonyl carbon gets number one. For cyclic aldehydes, the carbonyl carbon cannot be the part of the ring, and thus, it must be present outside the ring.

To write the IUPAC name of a compound, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. The suffix al is used for aldehydes. Then the main chain or ring is to be determined that contains the highest-priority functional group. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless redundant. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order.

Interpretation Introduction

(c)

Interpretation:

The structure is to be drawn, and the correct IUPAC name for the given trivial name is to be provided.

Concept introduction:

Most of the trivial names of aldehydes are derived from the analogous carboxylic acids.

For a straight chain aldehyde, the carbonyl carbon gets number one. For cyclic aldehydes, the carbonyl carbon cannot be the part of the ring, and thus, it must be present outside the ring.

To write the IUPAC name of a compound, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. The suffix al is used for aldehydes. Then the main chain or ring is to be determined that contains the highest-priority functional group. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless redundant. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order.

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Answer 3

Question

Chapter E, Problem E.22P

Interpretation Introduction

(a)

Interpretation:

The structure is to be drawn, and the correct IUPAC name for the given trivial name is to be provided.

Concept introduction:

Most of the trivial names of aldehydes are derived from the analogous carboxylic acids.

For a straight chain aldehyde, the carbonyl carbon gets number one. For cyclic aldehydes, the carbonyl carbon cannot be the part of the ring, and thus, it must be present outside the ring.

To write the IUPAC name of a compound, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. The suffix al is used for aldehydes. Then the main chain or ring is to be determined that contains the highest-priority functional group. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless redundant. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order.

Interpretation Introduction

(b)

Interpretation:

The structure is to be drawn, and the correct IUPAC name for the given trivial name is to be provided.

Concept introduction:

Most of the trivial names of aldehydes are derived from the analogous carboxylic acids.

For a straight chain aldehyde, the carbonyl carbon gets number one. For cyclic aldehydes, the carbonyl carbon cannot be the part of the ring, and thus, it must be present outside the ring.

To write the IUPAC name of a compound, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. The suffix al is used for aldehydes. Then the main chain or ring is to be determined that contains the highest-priority functional group. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless redundant. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order.

Interpretation Introduction

(c)

Interpretation:

The structure is to be drawn, and the correct IUPAC name for the given trivial name is to be provided.

Concept introduction:

Most of the trivial names of aldehydes are derived from the analogous carboxylic acids.

For a straight chain aldehyde, the carbonyl carbon gets number one. For cyclic aldehydes, the carbonyl carbon cannot be the part of the ring, and thus, it must be present outside the ring.

To write the IUPAC name of a compound, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. The suffix al is used for aldehydes. Then the main chain or ring is to be determined that contains the highest-priority functional group. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless redundant. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order.

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Answer 4

Question

Chapter E, Problem E.22P

Interpretation Introduction

(a)

Interpretation:

The structure is to be drawn, and the correct IUPAC name for the given trivial name is to be provided.

Concept introduction:

Most of the trivial names of aldehydes are derived from the analogous carboxylic acids.

For a straight chain aldehyde, the carbonyl carbon gets number one. For cyclic aldehydes, the carbonyl carbon cannot be the part of the ring, and thus, it must be present outside the ring.

To write the IUPAC name of a compound, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. The suffix al is used for aldehydes. Then the main chain or ring is to be determined that contains the highest-priority functional group. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless redundant. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order.

Interpretation Introduction

(b)

Interpretation:

The structure is to be drawn, and the correct IUPAC name for the given trivial name is to be provided.

Concept introduction:

Most of the trivial names of aldehydes are derived from the analogous carboxylic acids.

For a straight chain aldehyde, the carbonyl carbon gets number one. For cyclic aldehydes, the carbonyl carbon cannot be the part of the ring, and thus, it must be present outside the ring.

To write the IUPAC name of a compound, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. The suffix al is used for aldehydes. Then the main chain or ring is to be determined that contains the highest-priority functional group. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless redundant. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order.

Interpretation Introduction

(c)

Interpretation:

The structure is to be drawn, and the correct IUPAC name for the given trivial name is to be provided.

Concept introduction:

Most of the trivial names of aldehydes are derived from the analogous carboxylic acids.

For a straight chain aldehyde, the carbonyl carbon gets number one. For cyclic aldehydes, the carbonyl carbon cannot be the part of the ring, and thus, it must be present outside the ring.

To write the IUPAC name of a compound, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. The suffix al is used for aldehydes. Then the main chain or ring is to be determined that contains the highest-priority functional group. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless redundant. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order.

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Answer 5

Chapter E, Problem E.22P

Interpretation Introduction

(a)

Interpretation:

The structure is to be drawn, and the correct IUPAC name for the given trivial name is to be provided.

Concept introduction:

Most of the trivial names of aldehydes are derived from the analogous carboxylic acids.

For a straight chain aldehyde, the carbonyl carbon gets number one. For cyclic aldehydes, the carbonyl carbon cannot be the part of the ring, and thus, it must be present outside the ring.

To write the IUPAC name of a compound, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. The suffix al is used for aldehydes. Then the main chain or ring is to be determined that contains the highest-priority functional group. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless redundant. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order.

Interpretation Introduction

(b)

Interpretation:

The structure is to be drawn, and the correct IUPAC name for the given trivial name is to be provided.

Concept introduction:

Most of the trivial names of aldehydes are derived from the analogous carboxylic acids.

For a straight chain aldehyde, the carbonyl carbon gets number one. For cyclic aldehydes, the carbonyl carbon cannot be the part of the ring, and thus, it must be present outside the ring.

To write the IUPAC name of a compound, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. The suffix al is used for aldehydes. Then the main chain or ring is to be determined that contains the highest-priority functional group. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless redundant. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order.

Interpretation Introduction

(c)

Interpretation:

The structure is to be drawn, and the correct IUPAC name for the given trivial name is to be provided.

Concept introduction:

Most of the trivial names of aldehydes are derived from the analogous carboxylic acids.

For a straight chain aldehyde, the carbonyl carbon gets number one. For cyclic aldehydes, the carbonyl carbon cannot be the part of the ring, and thus, it must be present outside the ring.

To write the IUPAC name of a compound, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. The suffix al is used for aldehydes. Then the main chain or ring is to be determined that contains the highest-priority functional group. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless redundant. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order.

Answer 6

Chapter E, Problem E.22P

Interpretation Introduction

(a)

Interpretation:

The structure is to be drawn, and the correct IUPAC name for the given trivial name is to be provided.

Concept introduction:

Most of the trivial names of aldehydes are derived from the analogous carboxylic acids.

For a straight chain aldehyde, the carbonyl carbon gets number one. For cyclic aldehydes, the carbonyl carbon cannot be the part of the ring, and thus, it must be present outside the ring.

To write the IUPAC name of a compound, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. The suffix al is used for aldehydes. Then the main chain or ring is to be determined that contains the highest-priority functional group. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless redundant. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order.

Answer 7

Chapter E, Problem E.22P

Interpretation Introduction

(a)

Interpretation:

The structure is to be drawn, and the correct IUPAC name for the given trivial name is to be provided.

Concept introduction:

Most of the trivial names of aldehydes are derived from the analogous carboxylic acids.

For a straight chain aldehyde, the carbonyl carbon gets number one. For cyclic aldehydes, the carbonyl carbon cannot be the part of the ring, and thus, it must be present outside the ring.

To write the IUPAC name of a compound, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. The suffix al is used for aldehydes. Then the main chain or ring is to be determined that contains the highest-priority functional group. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless redundant. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure is to be drawn, and the correct IUPAC name for the given trivial name is to be provided.

Concept introduction:

Most of the trivial names of aldehydes are derived from the analogous carboxylic acids.

For a straight chain aldehyde, the carbonyl carbon gets number one. For cyclic aldehydes, the carbonyl carbon cannot be the part of the ring, and thus, it must be present outside the ring.

To write the IUPAC name of a compound, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. The suffix al is used for aldehydes. Then the main chain or ring is to be determined that contains the highest-priority functional group. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless redundant. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure is to be drawn, and the correct IUPAC name for the given trivial name is to be provided.

Concept introduction:

Most of the trivial names of aldehydes are derived from the analogous carboxylic acids.

For a straight chain aldehyde, the carbonyl carbon gets number one. For cyclic aldehydes, the carbonyl carbon cannot be the part of the ring, and thus, it must be present outside the ring.

To write the IUPAC name of a compound, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. The suffix al is used for aldehydes. Then the main chain or ring is to be determined that contains the highest-priority functional group. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless redundant. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structure is to be drawn, and the correct IUPAC name for the given trivial name is to be provided.

Concept introduction:

Most of the trivial names of aldehydes are derived from the analogous carboxylic acids.

For a straight chain aldehyde, the carbonyl carbon gets number one. For cyclic aldehydes, the carbonyl carbon cannot be the part of the ring, and thus, it must be present outside the ring.

To write the IUPAC name of a compound, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. The suffix al is used for aldehydes. Then the main chain or ring is to be determined that contains the highest-priority functional group. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless redundant. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structure is to be drawn, and the correct IUPAC name for the given trivial name is to be provided.

Concept introduction:

Most of the trivial names of aldehydes are derived from the analogous carboxylic acids.

For a straight chain aldehyde, the carbonyl carbon gets number one. For cyclic aldehydes, the carbonyl carbon cannot be the part of the ring, and thus, it must be present outside the ring.

To write the IUPAC name of a compound, first it is important to determine the highest-priority functional group present that requires a suffix referring to Table E-1. The suffix al is used for aldehydes. Then the main chain or ring is to be determined that contains the highest-priority functional group. The next step is to number the main chain or ring such that carbon atoms involving the highest-priority functional group receive the lowest possible numbers. The locator number for the highest-priority functional group is written immediately before the suffix, unless redundant. All other functional groups in the molecule are treated as substituents and appear in the name as a prefix. Prefixes such as di, tri, tetra, etc., are used to indicate the number of identical substituents attached. The substituents are named in the alphabetical order.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. E - Prob. E.1P Ch. E - Prob. E.2P Ch. E - Prob. E.3P Ch. E - Prob. E.4P Ch. E - Prob. E.5P Ch. E - Prob. E.6P Ch. E - Prob. E.7P Ch. E - Prob. E.8P Ch. E - Prob. E.9P Ch. E - Prob. E.10P

Solution Summary: The author explains that the correct IUPAC name for the given trivial name is to be provided.

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