
Study Guide for Chemistry: Structure and Properties
2nd Edition
ISBN: 9780134460680
Author: Nivaldo Tro
Publisher: PEARSON
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Chapter E, Problem 66E
Interpretation Introduction
To determine:
The time in hours when a cyclist wants to bike 212 km and her average speed for cycling is 18 miles per hour.
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Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
Chapter E Solutions
Study Guide for Chemistry: Structure and Properties
Ch. E - What are the standard SI base units of length,...Ch. E - What are the three common temperature scales? Does...Ch. E - What are prefix multipliers? List some examples.Ch. E - What is a derived unit? List an example.Ch. E - Explain the relationship between the reliability...Ch. E - What is the significance of the number of digits...Ch. E - Explain the difference between precision and...Ch. E - Prob. 8ECh. E - When multiplying or dividing measured quantities,...Ch. E - When adding or subtracting measured quantities,...
Ch. E - Explain the difference between density and mass.Ch. E - Explain the difference between intensive and...Ch. E - Prob. 13ECh. E - Prob. 14ECh. E - Prob. 15ECh. E - Prob. 16ECh. E - What is dimensional analysis?Ch. E - How should units be treated in calculations?Ch. E - Convert each temperature. a. 32 °F to °C...Ch. E - Convert each temperature. a. 212 °F to °C...Ch. E - The coldest temperature ever measured in the...Ch. E - Prob. 22ECh. E - Use the prefix multipliers to express each...Ch. E - Use prefix multipliers to express each measurement...Ch. E - Use scientific notation to express each quantity...Ch. E - Use scientific notation to express each quantity...Ch. E - Complete the table.Ch. E - Complete the table.Ch. E - Express the quantity 254,998 m in each unit. a. km...Ch. E - Express the quantity 556.2 × 10-12 s in each unit....Ch. E - How many 1-cm squares does it take to construct a...Ch. E - How many 1-cm cubes does it take to construct a...Ch. E - Convert 15.0 L to each unit. a.mL b. cm3 c. gal d....Ch. E - Convert 4.58 x 103 cm3 to each unit. a. L b. mL c....Ch. E - A ruler used to measure a penny has markings every...Ch. E - A scale used to weigh produce at a market has...Ch. E - Read each measurement to the correct number of...Ch. E - Read each measurement to the correct number of...Ch. E - For each number, underline the zeroes that are...Ch. E - For each number, underline the zeroes that are...Ch. E - How many significant figures are in each number?...Ch. E - How many significant figures are in each number?...Ch. E - Which numbers are exact (and therefore have an...Ch. E - Indicate the number of significant figures in each...Ch. E - Round each number to four significant figures. a....Ch. E - Round each number to three significant figures. a....Ch. E - Calculate to the correct number of significant...Ch. E - Calculate to the correct number of significant...Ch. E - Calculate to the correct number of significant...Ch. E - Calculate to the correct number of significant...Ch. E - Calculate to the correct number of significant...Ch. E - Calculate to the correct number of significant...Ch. E - A new penny has a mass of 2.49 g and a volume of...Ch. E - A titanium bicycle frame displaces 0.314 L of...Ch. E - Glycerol is a syrupy liquid used in cosmetics and...Ch. E - An allegedly gold nugget is tested to determine...Ch. E - Ethylene glycol (antifreeze) has a density of 1.11...Ch. E - Prob. 58ECh. E - A small airplane takes on 245 L of fuel, If the...Ch. E - Human fat has a density of 0.918 g/cm3. How much...Ch. E - Perform each unit conversion. a. 27.8 L to cm3 b....Ch. E - Prob. 62ECh. E - Prob. 63ECh. E - Prob. 64ECh. E - A runner wants to run 10.0 km. She knows that her...Ch. E - Prob. 66ECh. E - A European automobile has a gas mileage of 17...Ch. E - A gas can holds 5.0 gallons of gasoline. Express...Ch. E - A house has an area of 195 m2. What is its area...Ch. E - Prob. 70ECh. E - The average U.S. farm occupies 435 acres. (1 acre...Ch. E - Total U.S. farmland occupies 954 million acres....Ch. E - An acetaminophen suspension for infants contains...Ch. E - An ibuprofen suspension for infants contains 100...Ch. E - Convert between energy units. a. 534 kWh to J b....Ch. E - Prob. 76ECh. E - Suppose that a person eats 2387 Calories per day....Ch. E - A particular frost-free refrigerator uses about...Ch. E - Prob. 79ECh. E - Prob. 80ECh. E - A solid gold cylinder sits on a weight-sensitive...Ch. E - The proton has a radius of approximately 1.0 ×...Ch. E - The density of titanium is 4.51 g/cm3. What is the...Ch. E - The density of iron is 7.86 g/cm3. What is its...Ch. E - A steel cylinder has a length of 2.16 in, a radius...Ch. E - A solid aluminum sphere has a mass of 85 g. Use...Ch. E - Prob. 87ECh. E - Prob. 88ECh. E - The Toyota Prius, a hybrid electric vehicle, has a...Ch. E - The Honda Insight, a hybrid electric vehicle, has...Ch. E - The single proton that forms the nucleus of the...Ch. E - A sample of gaseous neon atoms at atmospheric...Ch. E - Prob. 93ECh. E - The world’s record in the 100-m dash is 9.58 s,...Ch. E - Table salt contains 39.33 g of sodium per 100 g of...Ch. E - Prob. 96ECh. E - A length of #8 copper wire (radius = 1.63 mm) has...Ch. E - Rolls of aluminum foil are 304 mm wide and 0.016...Ch. E - Liquid nitrogen has a density of 0.808 g/L and...Ch. E - Mercury is often used in thermometers. The mercury...Ch. E - Prob. 101ECh. E - In 1999, scientists discovered a new class of...Ch. E - Prob. 103ECh. E - Nanotechnology, the field of building ultrasmall...Ch. E - Prob. 105ECh. E - A box contains a mixture of small copper spheres...Ch. E - A cube has an edge length of 7 cm. If it is...Ch. E - Prob. 108ECh. E - For each box, examine the blocks attached to the...Ch. E - Look up the measurement of the approximate...Ch. E - Prob. 111ECh. E - One inch is equal to 2.54 cm. Draw a line that is...Ch. E - Convert the height of each member in your group...Ch. E - Prob. 114ECh. E - Convert 85.0 °F to k. 358 k 181.1 k 302.6 k 29.4 kCh. E - Express the quantity 33.2 × 10-4 m in mm. 0.332 mm...Ch. E - How many significant figures are there in the...Ch. E - Perform the calculation to the correct number of...Ch. E - Perform the calculation to the correct number of...Ch. E - What is the mass of a 1 .75-L sample of a liquid...Ch. E - Convert 1,285 cm2to m2. 12.85 m2 0.1285 m2 1.285 ×...Ch. E - Prob. 8SAQCh. E - A solid metal sphere has a radius of 3.53 cm and a...Ch. E - A German automobile’s gas mileage is 22km/L....Ch. E - A wooden block has a volume of 18.5 in3. Express...
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