Concept explainers
(a)
Interpretation:
Using trivial names where appropriate, the name for the given molecule is to be written.
Concept introduction:
Benzene derivatives have one or more substituents attached to the benzene ring. In such compounds, the root name is benzene. The ring is numbered so that the substituents attached to it get the lowest locator numbers. Prefixes and locator numbers are used for writing the number and type of substituents. If the substituents attached to a benzene ring are complicated, it is easy to treat the benzene ring as a substituent instead of a root.
(b)
Interpretation:
Using trivial names where appropriate, the name for the given molecule is to be written.
Concept introduction:
For a molecule that has more than one double bond or triple bond, the name must indicate the number of double bonds or triple bonds present as well as their locations. To name the molecule with multiple double/triple bonds, establish the root as the longest carbon chain or the largest carbon ring that contains the greatest number of entire
Trivial names are also commonly used for substituents containing
(c)
Interpretation:
Using trivial names where appropriate, the name for the given molecule is to be written.
Concept introduction:
Benzene derivatives have one or more substituents attached to the benzene ring. In such compounds, the root name is benzene. The ring is numbered so that the substituents attached to it get the lowest locator numbers. Prefixes and locator numbers are used for writing the number and type of substituents. If the substituents attached to a benzene ring are complicated, it is easy to treat the benzene ring as a substituent instead of a root. Alkenes, alkynes, and benzene derivatives have trivial names. Trivial names are also commonly used for substituents containing
(d)
Interpretation:
Using trivial names where appropriate, the name for the given molecule is to be written.
Concept introduction:
For a molecule that has more than one double bond or triple bond, the name must indicate the number of double bonds or triple bonds present as well as their locations. To name the molecule with multiple double/triple bonds, establish the root as the longest carbon chain or the largest carbon ring that contains the greatest number of entire
Trivial names are also commonly used for substituents containing

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Chapter B Solutions
EBK ORGANIC CHEMISTRY: PRINCIPLES AND M
- . Provide structure(s) for the starting material(s), reagent(s) or the major organic product(s) of each of the ollowing reactions or sequences of reactions. Show all relevant stereochemistry [five only] A. O B. OET CH3 1. LIAIH, ether 2 H₂O O (CH3)2CH-C-CI + 0 0 ether (CH3)2CH-C-O-C-CH3 CH3 C. 0 OH HO CH3 ° Clarrow_forwardHow would you prepare each of the following compounds using either an acetoacetic ester synthesis or a alonic ester synthesis? Show all intermediate structures and all reagents.[Three only] A. B. COOH OH C. D. 0 H2C CHCH2CH2CCH3arrow_forwardFats and greases have mostly aliphatic regions which are hydrophobic. Provide a schematic of howsoaps/detergents remove fats and grease from the soiled material. * see imagearrow_forward
- What chemical has the common name "lye"? Pick one of the 3 esters and show the hydrolysis mechanism to make a carboxylic acid. The organic “R” should be used to limit the redrawing time of the entire molecule. * see imagearrow_forwardProvide the products for each reaction. There are two and they are not related. *see imagearrow_forwardd. a phenylal Give the major organic product(s) of each of the following reactions or sequences of reactions. Show all levant stereochemistry. [three only] 0 A. B. CH3 Bra CH3COOH OH 1. Br₂, PBrz 2 H₂O 12arrow_forward
- 2arrow_forwardShow how the following conversions might be accomplished. Show all reagents and all intermediate ructures. More than one step may be required [2 ONLY]: A. B. ° C. OH 0 OH 0arrow_forwardA 20.3 mL sample of 0.263 M triethylamine, (C2H5)3N, is titrated with 0.252 M hydrochloric acid. (1) At the titration midpoint, the pH is . (2) At the equivalence point, the pH is .arrow_forward
- d. 3,4,5-trimethoxybenzoyl chloride . What is the order of decreasing reactivity towards nucleophilic acyl substitution for the arboxylic acid derivatives? (most reactive first) A. B. 0 0 O 0 0 H3C-C-O-C-CH3 H3C-C-N(CH3)2 H3C-C-OCH 3 (CH3)2CH-C-OCH3 I || ။ IV a. I, II, III, IV b. I, III, IV, II C. II, IV, III, I d. II, I, III, IV 0 0 0 0 0 R-C-O C-R R-C-NH2 R-C OR R-C-CI a. I, III, II, IV | 11 III IV b. II, III, I, IV c. III, II, I, IV d. IV, I, III, IIarrow_forwardB. d. a hydrate 4. Give the major organic product(s) for each of the following reactions or sequences of reactions. Show all relevant stereochemistry [4 ONLY]. A. CH₂OH PCC CH2Cl2 0 H KCN HCN 2arrow_forwardPropose a synthesis of the anti-inflammatory drug Ibuprofen from benzene. Show all reagents and all intermediate structures. Assume that ortho and para isomers can be separated. (CH3)2CHCH2 CH3 CHCOOH 1buprofen be requiredarrow_forward
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