EBK ORGANIC CHEMISTRY: PRINCIPLES AND M
EBK ORGANIC CHEMISTRY: PRINCIPLES AND M
2nd Edition
ISBN: 9780393630817
Author: KARTY
Publisher: W.W.NORTON+CO. (CC)
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Chapter B, Problem B.30P
Interpretation Introduction

Interpretation:

IUPAC name for the molecule is to be written.

Concept introduction:

For a molecule that has more than one double bond or triple bond, the IUPAC name must indicate the number of double bonds or triple bonds present as well as their locations. To name the molecule with multiple double/triple bonds, establish the root as the longest carbon chain or the largest carbon ring that contains the greatest number of entire C=C or CC groups. Number the chain or ring so that each successive C=C or CC group is encountered the earliest. For each pair of C=C or CC atoms, identify the lower of the two locator numbers. Immediately before the ‘ene’ or ‘yne’ suffix, add a letter ‘a’ followed by the above set of locator numbers, and then add a prefix ‘di, tri’ etc.. to specify the number of double or triple bonds. The substituents attached to the root are named in the alphabetical order.

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fcrip = ↓ bandwidth Il temp 32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual components of the van Deemter equation and consequently, band broadening? Increase temperature Longer column Using a gas mobile phase instead of liquid Smaller particle stationary phase Multiple Paths Diffusion Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.). A) Predict whether decreasing the column inner diameters increase or decrease bandwidth. B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or decreasing bandwidth as a function of i.d. and justify your answer. Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles. 35 20 H(um) 큰 20 15 90 0+ 1500 100 75 550 01 02 594 05 μ(cm/sec) 30 15 10
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