(a) Interpretation: The structure for hex-2-ene is to be drawn. Concept introduction: In the case of molecules containing a C=C or a C ≡ C , the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene, if a double bond is present. The suffix ane is replaced by yne if a triple bond is present. If the root is a chain, numbering begins from that end of the chain which encounters the C=C or C ≡ C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers. If the root is a ring, then the double or triple bonded carbon atoms are designated as C1 and C2. This must be done such that the locator numbers for the substituents, are minimized. The lower of the two locator numbers for the C=C or C ≡ C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

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Question

Chapter B, Problem B.21P

Interpretation Introduction

(a)

Interpretation:

The structure for hex-2-ene is to be drawn.

Concept introduction:

In the case of molecules containing a C=C or a C≡C, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene, if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, numbering begins from that end of the chain which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

If the root is a ring, then the double or triple bonded carbon atoms are designated as C1 and C2. This must be done such that the locator numbers for the substituents, are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Interpretation Introduction

(b)

Interpretation:

The structure for hex-3-ene is to be drawn.

Concept introduction:

In the case of molecules containing a C=C or a C≡C, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene, if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, numbering begins from that end of the chain which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

If the root is a ring, then the double or triple bonded carbon atoms are designated as C1 and C2. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Interpretation Introduction

(c)

Interpretation:

The structure for hept-1-ene is to be drawn.

Concept introduction:

In the case of molecules containing a C=C or a C≡C, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene, if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, numbering begins from that end of the chain which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

If the root is a ring, then the double or triple bonded carbon atoms are designated as C1 and C2. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Interpretation Introduction

(d)

Interpretation:

The structure for oct-2-yne is to be drawn.

Concept introduction:

In the case of molecules containing a C=C or a C≡C, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene, if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, numbering begins from that end of the chain which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

If the root is a ring, then the double or triple bonded carbon atoms are designated as C1 and C2. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Interpretation Introduction

(e)

Interpretation:

The structure for cycloheptene is to be drawn.

Concept introduction:

In the case of molecules containing a C=C or a C≡C, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene, if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, numbering begins from that end of the chain which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

If the root is a ring, then the double or triple bonded carbon atoms are designated as C1 and C2. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

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16) A 2.0 L flask containing 2.0 x 10-3 mol H2(g), 3.0 x 10-3 mol Cl2(g), and 4.0 x 10-3 mol HCl(g) at equilibrium. This system is represented by the following chemical equation: H2 (g) + Cl2 (g) → 2HCl(g) Calculate the equilibrium constant for this reaction.

Answer 2

Question

Chapter B, Problem B.21P

Interpretation Introduction

(a)

Interpretation:

The structure for hex-2-ene is to be drawn.

Concept introduction:

In the case of molecules containing a C=C or a C≡C, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene, if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, numbering begins from that end of the chain which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

If the root is a ring, then the double or triple bonded carbon atoms are designated as C1 and C2. This must be done such that the locator numbers for the substituents, are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Interpretation Introduction

(b)

Interpretation:

The structure for hex-3-ene is to be drawn.

Concept introduction:

In the case of molecules containing a C=C or a C≡C, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene, if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, numbering begins from that end of the chain which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

If the root is a ring, then the double or triple bonded carbon atoms are designated as C1 and C2. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Interpretation Introduction

(c)

Interpretation:

The structure for hept-1-ene is to be drawn.

Concept introduction:

In the case of molecules containing a C=C or a C≡C, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene, if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, numbering begins from that end of the chain which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

If the root is a ring, then the double or triple bonded carbon atoms are designated as C1 and C2. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Interpretation Introduction

(d)

Interpretation:

The structure for oct-2-yne is to be drawn.

Concept introduction:

In the case of molecules containing a C=C or a C≡C, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene, if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, numbering begins from that end of the chain which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

If the root is a ring, then the double or triple bonded carbon atoms are designated as C1 and C2. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Interpretation Introduction

(e)

Interpretation:

The structure for cycloheptene is to be drawn.

Concept introduction:

In the case of molecules containing a C=C or a C≡C, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene, if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, numbering begins from that end of the chain which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

If the root is a ring, then the double or triple bonded carbon atoms are designated as C1 and C2. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

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Answer 3

Question

Chapter B, Problem B.21P

Interpretation Introduction

(a)

Interpretation:

The structure for hex-2-ene is to be drawn.

Concept introduction:

In the case of molecules containing a C=C or a C≡C, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene, if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, numbering begins from that end of the chain which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

If the root is a ring, then the double or triple bonded carbon atoms are designated as C1 and C2. This must be done such that the locator numbers for the substituents, are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Interpretation Introduction

(b)

Interpretation:

The structure for hex-3-ene is to be drawn.

Concept introduction:

In the case of molecules containing a C=C or a C≡C, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene, if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, numbering begins from that end of the chain which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

If the root is a ring, then the double or triple bonded carbon atoms are designated as C1 and C2. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Interpretation Introduction

(c)

Interpretation:

The structure for hept-1-ene is to be drawn.

Concept introduction:

In the case of molecules containing a C=C or a C≡C, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene, if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, numbering begins from that end of the chain which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

If the root is a ring, then the double or triple bonded carbon atoms are designated as C1 and C2. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Interpretation Introduction

(d)

Interpretation:

The structure for oct-2-yne is to be drawn.

Concept introduction:

In the case of molecules containing a C=C or a C≡C, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene, if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, numbering begins from that end of the chain which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

If the root is a ring, then the double or triple bonded carbon atoms are designated as C1 and C2. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Interpretation Introduction

(e)

Interpretation:

The structure for cycloheptene is to be drawn.

Concept introduction:

In the case of molecules containing a C=C or a C≡C, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene, if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, numbering begins from that end of the chain which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

If the root is a ring, then the double or triple bonded carbon atoms are designated as C1 and C2. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

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Answer 4

Question

Chapter B, Problem B.21P

Interpretation Introduction

(a)

Interpretation:

The structure for hex-2-ene is to be drawn.

Concept introduction:

In the case of molecules containing a C=C or a C≡C, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene, if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, numbering begins from that end of the chain which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

If the root is a ring, then the double or triple bonded carbon atoms are designated as C1 and C2. This must be done such that the locator numbers for the substituents, are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Interpretation Introduction

(b)

Interpretation:

The structure for hex-3-ene is to be drawn.

Concept introduction:

In the case of molecules containing a C=C or a C≡C, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene, if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, numbering begins from that end of the chain which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

If the root is a ring, then the double or triple bonded carbon atoms are designated as C1 and C2. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Interpretation Introduction

(c)

Interpretation:

The structure for hept-1-ene is to be drawn.

Concept introduction:

In the case of molecules containing a C=C or a C≡C, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene, if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, numbering begins from that end of the chain which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

If the root is a ring, then the double or triple bonded carbon atoms are designated as C1 and C2. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Interpretation Introduction

(d)

Interpretation:

The structure for oct-2-yne is to be drawn.

Concept introduction:

In the case of molecules containing a C=C or a C≡C, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene, if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, numbering begins from that end of the chain which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

If the root is a ring, then the double or triple bonded carbon atoms are designated as C1 and C2. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Interpretation Introduction

(e)

Interpretation:

The structure for cycloheptene is to be drawn.

Concept introduction:

In the case of molecules containing a C=C or a C≡C, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene, if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, numbering begins from that end of the chain which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

If the root is a ring, then the double or triple bonded carbon atoms are designated as C1 and C2. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

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Answer 5

Chapter B, Problem B.21P

Interpretation Introduction

(a)

Interpretation:

The structure for hex-2-ene is to be drawn.

Concept introduction:

In the case of molecules containing a C=C or a C≡C, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene, if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, numbering begins from that end of the chain which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

If the root is a ring, then the double or triple bonded carbon atoms are designated as C1 and C2. This must be done such that the locator numbers for the substituents, are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Interpretation Introduction

(b)

Interpretation:

The structure for hex-3-ene is to be drawn.

Concept introduction:

In the case of molecules containing a C=C or a C≡C, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene, if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, numbering begins from that end of the chain which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

If the root is a ring, then the double or triple bonded carbon atoms are designated as C1 and C2. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Interpretation Introduction

(c)

Interpretation:

The structure for hept-1-ene is to be drawn.

Concept introduction:

In the case of molecules containing a C=C or a C≡C, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene, if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, numbering begins from that end of the chain which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

If the root is a ring, then the double or triple bonded carbon atoms are designated as C1 and C2. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Interpretation Introduction

(d)

Interpretation:

The structure for oct-2-yne is to be drawn.

Concept introduction:

In the case of molecules containing a C=C or a C≡C, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene, if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, numbering begins from that end of the chain which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

If the root is a ring, then the double or triple bonded carbon atoms are designated as C1 and C2. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Interpretation Introduction

(e)

Interpretation:

The structure for cycloheptene is to be drawn.

Concept introduction:

In the case of molecules containing a C=C or a C≡C, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene, if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, numbering begins from that end of the chain which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

If the root is a ring, then the double or triple bonded carbon atoms are designated as C1 and C2. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Answer 6

Chapter B, Problem B.21P

Interpretation Introduction

(a)

Interpretation:

The structure for hex-2-ene is to be drawn.

Concept introduction:

In the case of molecules containing a C=C or a C≡C, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene, if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, numbering begins from that end of the chain which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

If the root is a ring, then the double or triple bonded carbon atoms are designated as C1 and C2. This must be done such that the locator numbers for the substituents, are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Answer 7

Chapter B, Problem B.21P

Interpretation Introduction

(a)

Interpretation:

The structure for hex-2-ene is to be drawn.

Concept introduction:

In the case of molecules containing a C=C or a C≡C, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene, if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, numbering begins from that end of the chain which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

If the root is a ring, then the double or triple bonded carbon atoms are designated as C1 and C2. This must be done such that the locator numbers for the substituents, are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure for hex-3-ene is to be drawn.

Concept introduction:

In the case of molecules containing a C=C or a C≡C, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene, if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, numbering begins from that end of the chain which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

If the root is a ring, then the double or triple bonded carbon atoms are designated as C1 and C2. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure for hex-3-ene is to be drawn.

Concept introduction:

In the case of molecules containing a C=C or a C≡C, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene, if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, numbering begins from that end of the chain which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

If the root is a ring, then the double or triple bonded carbon atoms are designated as C1 and C2. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structure for hept-1-ene is to be drawn.

Concept introduction:

In the case of molecules containing a C=C or a C≡C, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene, if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, numbering begins from that end of the chain which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

If the root is a ring, then the double or triple bonded carbon atoms are designated as C1 and C2. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structure for hept-1-ene is to be drawn.

Concept introduction:

In the case of molecules containing a C=C or a C≡C, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene, if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, numbering begins from that end of the chain which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

If the root is a ring, then the double or triple bonded carbon atoms are designated as C1 and C2. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The structure for oct-2-yne is to be drawn.

Concept introduction:

In the case of molecules containing a C=C or a C≡C, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene, if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, numbering begins from that end of the chain which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

If the root is a ring, then the double or triple bonded carbon atoms are designated as C1 and C2. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The structure for oct-2-yne is to be drawn.

Concept introduction:

In the case of molecules containing a C=C or a C≡C, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene, if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, numbering begins from that end of the chain which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

If the root is a ring, then the double or triple bonded carbon atoms are designated as C1 and C2. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Answer 14

Interpretation Introduction

(e)

Interpretation:

The structure for cycloheptene is to be drawn.

Concept introduction:

In the case of molecules containing a C=C or a C≡C, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene, if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, numbering begins from that end of the chain which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

If the root is a ring, then the double or triple bonded carbon atoms are designated as C1 and C2. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Answer 15

Interpretation Introduction

(e)

Interpretation:

The structure for cycloheptene is to be drawn.

Concept introduction:

In the case of molecules containing a C=C or a C≡C, the longest continuous carbon chain or largest ring that contains the double or triple bond is considered as the root. The root is named from the name of the analogous alkane or cycloalkane by replacing the suffix ane by ene, if a double bond is present. The suffix ane is replaced by yne if a triple bond is present.

If the root is a chain, numbering begins from that end of the chain which encounters the C=C or C≡C at the earliest. If there is a tie, then the chain is numbered such that the substituents get the lowest locator numbers.

If the root is a ring, then the double or triple bonded carbon atoms are designated as C1 and C2. This must be done such that the locator numbers for the substituents are minimized. The lower of the two locator numbers for the C=C or C≡C is written before the ene or yne suffix. Prefixes and locator numbers are used for the substituents attached.

Answer 16

Expert Solution & Answer

Answer 17

Expert Solution & Answer

Answer 18

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Answer 19

Ch. B - Prob. B.1P Ch. B - Prob. B.2P Ch. B - Prob. B.3P Ch. B - Prob. B.4P Ch. B - Prob. B.5P Ch. B - Prob. B.6P Ch. B - Prob. B.7P Ch. B - Prob. B.8P Ch. B - Prob. B.9P Ch. B - Prob. B.10P

Solution Summary: The author explains the structure of hex-2-ene. The longest continuous carbon chain or largest ring that contains the double or triple bond is considered the root.

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