(a) Interpretation: The structure for m-bromotoluene is to be drawn and the alternate IUPAC name is to be written. Concept introduction: Trivial names like toluene and anisole have been adopted by the IUPAC system. If these compounds are present in a structure, the root is used as toluene or anisole respectively. The root in such compounds specifies the position of the methyl group as C1 in toluene, and the methoxy group in anisole. Other substituents attached to the benzene ring are indicated by using locator numbers or the prefixes like ortho, meta, and para.

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Answer 1

Question

Chapter B, Problem B.18P

Interpretation Introduction

(a)

Interpretation:

The structure for m-bromotoluene is to be drawn and the alternate IUPAC name is to be written.

Concept introduction:

Trivial names like toluene and anisole have been adopted by the IUPAC system. If these compounds are present in a structure, the root is used as toluene or anisole respectively. The root in such compounds specifies the position of the methyl group as C1 in toluene, and the methoxy group in anisole. Other substituents attached to the benzene ring are indicated by using locator numbers or the prefixes like ortho, meta, and para.

Interpretation Introduction

(b)

Interpretation:

The structure for 2, 5-dinitrotoluene is to be drawn and the alternate IUPAC name is to be written.

Concept introduction:

Trivial names like toluene and anisole have been adopted by the IUPAC system. If these compounds are present in a structure, the root is used as toluene or anisole respectively. The root in such compounds specifies the position of the methyl group as C1 in toluene, and the methoxy group in anisole. Other substituents attached to the benzene ring are indicated by using locator numbers or the prefixes like ortho, meta, and para.

Interpretation Introduction

(c)

Interpretation:

The structure for p-chloroanisole is to be drawn and the alternate IUPAC name is to be written.

Concept introduction:

Trivial names like toluene and anisole have been adopted by the IUPAC system. If these compounds are present in a structure, the root is used as toluene or anisole respectively. The root in such compounds specifies the position of the methyl group as C1 in toluene, and the methoxy group in anisole. Other substituents attached to the benzene ring are indicated by using locator numbers or the prefixes like ortho, meta, and para.

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2. 200 LOD For an unknown compound with a molecular ion of 101 m/z: a. Use the molecular ion to propose at least two molecular formulas. (show your work) b. What is the DU for each of your possible formulas? (show your work) C. Solve the structure and assign each of the following spectra. 8 6 4 2 (ppm) 150 100 50 ō (ppm) 4000 3000 2000 1500 1000 500 HAVENUMBERI-11

Complete the spectroscopy with structure

Answer 2

Question

Chapter B, Problem B.18P

Interpretation Introduction

(a)

Interpretation:

The structure for m-bromotoluene is to be drawn and the alternate IUPAC name is to be written.

Concept introduction:

Trivial names like toluene and anisole have been adopted by the IUPAC system. If these compounds are present in a structure, the root is used as toluene or anisole respectively. The root in such compounds specifies the position of the methyl group as C1 in toluene, and the methoxy group in anisole. Other substituents attached to the benzene ring are indicated by using locator numbers or the prefixes like ortho, meta, and para.

Interpretation Introduction

(b)

Interpretation:

The structure for 2, 5-dinitrotoluene is to be drawn and the alternate IUPAC name is to be written.

Concept introduction:

Trivial names like toluene and anisole have been adopted by the IUPAC system. If these compounds are present in a structure, the root is used as toluene or anisole respectively. The root in such compounds specifies the position of the methyl group as C1 in toluene, and the methoxy group in anisole. Other substituents attached to the benzene ring are indicated by using locator numbers or the prefixes like ortho, meta, and para.

Interpretation Introduction

(c)

Interpretation:

The structure for p-chloroanisole is to be drawn and the alternate IUPAC name is to be written.

Concept introduction:

Trivial names like toluene and anisole have been adopted by the IUPAC system. If these compounds are present in a structure, the root is used as toluene or anisole respectively. The root in such compounds specifies the position of the methyl group as C1 in toluene, and the methoxy group in anisole. Other substituents attached to the benzene ring are indicated by using locator numbers or the prefixes like ortho, meta, and para.

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Answer 3

Question

Chapter B, Problem B.18P

Interpretation Introduction

(a)

Interpretation:

The structure for m-bromotoluene is to be drawn and the alternate IUPAC name is to be written.

Concept introduction:

Trivial names like toluene and anisole have been adopted by the IUPAC system. If these compounds are present in a structure, the root is used as toluene or anisole respectively. The root in such compounds specifies the position of the methyl group as C1 in toluene, and the methoxy group in anisole. Other substituents attached to the benzene ring are indicated by using locator numbers or the prefixes like ortho, meta, and para.

Interpretation Introduction

(b)

Interpretation:

The structure for 2, 5-dinitrotoluene is to be drawn and the alternate IUPAC name is to be written.

Concept introduction:

Trivial names like toluene and anisole have been adopted by the IUPAC system. If these compounds are present in a structure, the root is used as toluene or anisole respectively. The root in such compounds specifies the position of the methyl group as C1 in toluene, and the methoxy group in anisole. Other substituents attached to the benzene ring are indicated by using locator numbers or the prefixes like ortho, meta, and para.

Interpretation Introduction

(c)

Interpretation:

The structure for p-chloroanisole is to be drawn and the alternate IUPAC name is to be written.

Concept introduction:

Trivial names like toluene and anisole have been adopted by the IUPAC system. If these compounds are present in a structure, the root is used as toluene or anisole respectively. The root in such compounds specifies the position of the methyl group as C1 in toluene, and the methoxy group in anisole. Other substituents attached to the benzene ring are indicated by using locator numbers or the prefixes like ortho, meta, and para.

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Answer 4

Question

Chapter B, Problem B.18P

Interpretation Introduction

(a)

Interpretation:

The structure for m-bromotoluene is to be drawn and the alternate IUPAC name is to be written.

Concept introduction:

Trivial names like toluene and anisole have been adopted by the IUPAC system. If these compounds are present in a structure, the root is used as toluene or anisole respectively. The root in such compounds specifies the position of the methyl group as C1 in toluene, and the methoxy group in anisole. Other substituents attached to the benzene ring are indicated by using locator numbers or the prefixes like ortho, meta, and para.

Interpretation Introduction

(b)

Interpretation:

The structure for 2, 5-dinitrotoluene is to be drawn and the alternate IUPAC name is to be written.

Concept introduction:

Trivial names like toluene and anisole have been adopted by the IUPAC system. If these compounds are present in a structure, the root is used as toluene or anisole respectively. The root in such compounds specifies the position of the methyl group as C1 in toluene, and the methoxy group in anisole. Other substituents attached to the benzene ring are indicated by using locator numbers or the prefixes like ortho, meta, and para.

Interpretation Introduction

(c)

Interpretation:

The structure for p-chloroanisole is to be drawn and the alternate IUPAC name is to be written.

Concept introduction:

Trivial names like toluene and anisole have been adopted by the IUPAC system. If these compounds are present in a structure, the root is used as toluene or anisole respectively. The root in such compounds specifies the position of the methyl group as C1 in toluene, and the methoxy group in anisole. Other substituents attached to the benzene ring are indicated by using locator numbers or the prefixes like ortho, meta, and para.

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Answer 5

Chapter B, Problem B.18P

Interpretation Introduction

(a)

Interpretation:

The structure for m-bromotoluene is to be drawn and the alternate IUPAC name is to be written.

Concept introduction:

Trivial names like toluene and anisole have been adopted by the IUPAC system. If these compounds are present in a structure, the root is used as toluene or anisole respectively. The root in such compounds specifies the position of the methyl group as C1 in toluene, and the methoxy group in anisole. Other substituents attached to the benzene ring are indicated by using locator numbers or the prefixes like ortho, meta, and para.

Interpretation Introduction

(b)

Interpretation:

The structure for 2, 5-dinitrotoluene is to be drawn and the alternate IUPAC name is to be written.

Concept introduction:

Trivial names like toluene and anisole have been adopted by the IUPAC system. If these compounds are present in a structure, the root is used as toluene or anisole respectively. The root in such compounds specifies the position of the methyl group as C1 in toluene, and the methoxy group in anisole. Other substituents attached to the benzene ring are indicated by using locator numbers or the prefixes like ortho, meta, and para.

Interpretation Introduction

(c)

Interpretation:

The structure for p-chloroanisole is to be drawn and the alternate IUPAC name is to be written.

Concept introduction:

Trivial names like toluene and anisole have been adopted by the IUPAC system. If these compounds are present in a structure, the root is used as toluene or anisole respectively. The root in such compounds specifies the position of the methyl group as C1 in toluene, and the methoxy group in anisole. Other substituents attached to the benzene ring are indicated by using locator numbers or the prefixes like ortho, meta, and para.

Answer 6

Chapter B, Problem B.18P

Interpretation Introduction

(a)

Interpretation:

The structure for m-bromotoluene is to be drawn and the alternate IUPAC name is to be written.

Concept introduction:

Trivial names like toluene and anisole have been adopted by the IUPAC system. If these compounds are present in a structure, the root is used as toluene or anisole respectively. The root in such compounds specifies the position of the methyl group as C1 in toluene, and the methoxy group in anisole. Other substituents attached to the benzene ring are indicated by using locator numbers or the prefixes like ortho, meta, and para.

Answer 7

Chapter B, Problem B.18P

Interpretation Introduction

(a)

Interpretation:

The structure for m-bromotoluene is to be drawn and the alternate IUPAC name is to be written.

Concept introduction:

Trivial names like toluene and anisole have been adopted by the IUPAC system. If these compounds are present in a structure, the root is used as toluene or anisole respectively. The root in such compounds specifies the position of the methyl group as C1 in toluene, and the methoxy group in anisole. Other substituents attached to the benzene ring are indicated by using locator numbers or the prefixes like ortho, meta, and para.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure for 2, 5-dinitrotoluene is to be drawn and the alternate IUPAC name is to be written.

Concept introduction:

Trivial names like toluene and anisole have been adopted by the IUPAC system. If these compounds are present in a structure, the root is used as toluene or anisole respectively. The root in such compounds specifies the position of the methyl group as C1 in toluene, and the methoxy group in anisole. Other substituents attached to the benzene ring are indicated by using locator numbers or the prefixes like ortho, meta, and para.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure for 2, 5-dinitrotoluene is to be drawn and the alternate IUPAC name is to be written.

Concept introduction:

Trivial names like toluene and anisole have been adopted by the IUPAC system. If these compounds are present in a structure, the root is used as toluene or anisole respectively. The root in such compounds specifies the position of the methyl group as C1 in toluene, and the methoxy group in anisole. Other substituents attached to the benzene ring are indicated by using locator numbers or the prefixes like ortho, meta, and para.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structure for p-chloroanisole is to be drawn and the alternate IUPAC name is to be written.

Concept introduction:

Trivial names like toluene and anisole have been adopted by the IUPAC system. If these compounds are present in a structure, the root is used as toluene or anisole respectively. The root in such compounds specifies the position of the methyl group as C1 in toluene, and the methoxy group in anisole. Other substituents attached to the benzene ring are indicated by using locator numbers or the prefixes like ortho, meta, and para.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structure for p-chloroanisole is to be drawn and the alternate IUPAC name is to be written.

Concept introduction:

Trivial names like toluene and anisole have been adopted by the IUPAC system. If these compounds are present in a structure, the root is used as toluene or anisole respectively. The root in such compounds specifies the position of the methyl group as C1 in toluene, and the methoxy group in anisole. Other substituents attached to the benzene ring are indicated by using locator numbers or the prefixes like ortho, meta, and para.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. B - Prob. B.1P Ch. B - Prob. B.2P Ch. B - Prob. B.3P Ch. B - Prob. B.4P Ch. B - Prob. B.5P Ch. B - Prob. B.6P Ch. B - Prob. B.7P Ch. B - Prob. B.8P Ch. B - Prob. B.9P Ch. B - Prob. B.10P

Solution Summary: The author explains the structure of m-bromotoluene and the alternate IUPAC name.

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