(a) Interpretation: The structure for 1, 4-divinylcyclohexane is to be drawn. Concept introduction: Commonly used trivial names for substituents having C=C or C ≡ C are used when writing the name of a molecule. The root is named considering the longest continuous chain of carbon atom or the largest ring. The substituents are written with appropriate locator numbers and trivial names.

Question

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Answer 1

Question

Chapter B, Problem B.17P

Interpretation Introduction

(a)

Interpretation:

The structure for 1, 4-divinylcyclohexane is to be drawn.

Concept introduction:

Commonly used trivial names for substituents having C=C or C≡C are used when writing the name of a molecule. The root is named considering the longest continuous chain of carbon atom or the largest ring. The substituents are written with appropriate locator numbers and trivial names.

Interpretation Introduction

(b)

Interpretation:

The structure for allyl vinyl ether is to be drawn.

Concept introduction:

Ethers are compounds containing an oxygen atom attached to alkyl groups. Their trivial names are written by writing the names of the two alkyl groups in alphabetical order followed by the word ether.

Interpretation Introduction

(c)

Interpretation:

The structure for 1-chloro-3-propargylcyclopentane is to be drawn.

Concept introduction:

Commonly used trivial names for substituents having C=C or C≡C are used when writing the name of a molecule. The root is named considering the longest continuous chain of carbon atom or the largest ring. The substituents are written with appropriate locator numbers and trivial names.

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H- H H H H H H Identify and select all structures below that represent a constitutional isomer(s) of the compound shown above. H- H H H A. H H H H-C CI H H D. H H H H H H C C -H H C C H H H H B. H CI H H- C C H H H H E. H CI H C.

Why doesn't this carry on to form a ring by deprotonating the alpha carbon and the negatively-charged carbon attacking the C=O?

6. A solution (0.0004 M) of Fe(S2CNEt2)3 (see the structural drawing below) in chloroform has absorption bands at: 350 nm (absorbance A = 2.34); 514 nm(absorbance A = 0.0532); Calculate the molar absorptivity values for these bands. Comment on their possible nature (charge transfer transitions or d-d S N- transitions?). (4 points)

Answer 2

Question

Chapter B, Problem B.17P

Interpretation Introduction

(a)

Interpretation:

The structure for 1, 4-divinylcyclohexane is to be drawn.

Concept introduction:

Commonly used trivial names for substituents having C=C or C≡C are used when writing the name of a molecule. The root is named considering the longest continuous chain of carbon atom or the largest ring. The substituents are written with appropriate locator numbers and trivial names.

Interpretation Introduction

(b)

Interpretation:

The structure for allyl vinyl ether is to be drawn.

Concept introduction:

Ethers are compounds containing an oxygen atom attached to alkyl groups. Their trivial names are written by writing the names of the two alkyl groups in alphabetical order followed by the word ether.

Interpretation Introduction

(c)

Interpretation:

The structure for 1-chloro-3-propargylcyclopentane is to be drawn.

Concept introduction:

Commonly used trivial names for substituents having C=C or C≡C are used when writing the name of a molecule. The root is named considering the longest continuous chain of carbon atom or the largest ring. The substituents are written with appropriate locator numbers and trivial names.

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Answer 3

Question

Chapter B, Problem B.17P

Interpretation Introduction

(a)

Interpretation:

The structure for 1, 4-divinylcyclohexane is to be drawn.

Concept introduction:

Commonly used trivial names for substituents having C=C or C≡C are used when writing the name of a molecule. The root is named considering the longest continuous chain of carbon atom or the largest ring. The substituents are written with appropriate locator numbers and trivial names.

Interpretation Introduction

(b)

Interpretation:

The structure for allyl vinyl ether is to be drawn.

Concept introduction:

Ethers are compounds containing an oxygen atom attached to alkyl groups. Their trivial names are written by writing the names of the two alkyl groups in alphabetical order followed by the word ether.

Interpretation Introduction

(c)

Interpretation:

The structure for 1-chloro-3-propargylcyclopentane is to be drawn.

Concept introduction:

Commonly used trivial names for substituents having C=C or C≡C are used when writing the name of a molecule. The root is named considering the longest continuous chain of carbon atom or the largest ring. The substituents are written with appropriate locator numbers and trivial names.

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Answer 4

Question

Chapter B, Problem B.17P

Interpretation Introduction

(a)

Interpretation:

The structure for 1, 4-divinylcyclohexane is to be drawn.

Concept introduction:

Commonly used trivial names for substituents having C=C or C≡C are used when writing the name of a molecule. The root is named considering the longest continuous chain of carbon atom or the largest ring. The substituents are written with appropriate locator numbers and trivial names.

Interpretation Introduction

(b)

Interpretation:

The structure for allyl vinyl ether is to be drawn.

Concept introduction:

Ethers are compounds containing an oxygen atom attached to alkyl groups. Their trivial names are written by writing the names of the two alkyl groups in alphabetical order followed by the word ether.

Interpretation Introduction

(c)

Interpretation:

The structure for 1-chloro-3-propargylcyclopentane is to be drawn.

Concept introduction:

Commonly used trivial names for substituents having C=C or C≡C are used when writing the name of a molecule. The root is named considering the longest continuous chain of carbon atom or the largest ring. The substituents are written with appropriate locator numbers and trivial names.

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Answer 5

Chapter B, Problem B.17P

Interpretation Introduction

(a)

Interpretation:

The structure for 1, 4-divinylcyclohexane is to be drawn.

Concept introduction:

Commonly used trivial names for substituents having C=C or C≡C are used when writing the name of a molecule. The root is named considering the longest continuous chain of carbon atom or the largest ring. The substituents are written with appropriate locator numbers and trivial names.

Interpretation Introduction

(b)

Interpretation:

The structure for allyl vinyl ether is to be drawn.

Concept introduction:

Ethers are compounds containing an oxygen atom attached to alkyl groups. Their trivial names are written by writing the names of the two alkyl groups in alphabetical order followed by the word ether.

Interpretation Introduction

(c)

Interpretation:

The structure for 1-chloro-3-propargylcyclopentane is to be drawn.

Concept introduction:

Commonly used trivial names for substituents having C=C or C≡C are used when writing the name of a molecule. The root is named considering the longest continuous chain of carbon atom or the largest ring. The substituents are written with appropriate locator numbers and trivial names.

Answer 6

Chapter B, Problem B.17P

Interpretation Introduction

(a)

Interpretation:

The structure for 1, 4-divinylcyclohexane is to be drawn.

Concept introduction:

Commonly used trivial names for substituents having C=C or C≡C are used when writing the name of a molecule. The root is named considering the longest continuous chain of carbon atom or the largest ring. The substituents are written with appropriate locator numbers and trivial names.

Answer 7

Chapter B, Problem B.17P

Interpretation Introduction

(a)

Interpretation:

The structure for 1, 4-divinylcyclohexane is to be drawn.

Concept introduction:

Commonly used trivial names for substituents having C=C or C≡C are used when writing the name of a molecule. The root is named considering the longest continuous chain of carbon atom or the largest ring. The substituents are written with appropriate locator numbers and trivial names.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure for allyl vinyl ether is to be drawn.

Concept introduction:

Ethers are compounds containing an oxygen atom attached to alkyl groups. Their trivial names are written by writing the names of the two alkyl groups in alphabetical order followed by the word ether.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure for allyl vinyl ether is to be drawn.

Concept introduction:

Ethers are compounds containing an oxygen atom attached to alkyl groups. Their trivial names are written by writing the names of the two alkyl groups in alphabetical order followed by the word ether.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structure for 1-chloro-3-propargylcyclopentane is to be drawn.

Concept introduction:

Commonly used trivial names for substituents having C=C or C≡C are used when writing the name of a molecule. The root is named considering the longest continuous chain of carbon atom or the largest ring. The substituents are written with appropriate locator numbers and trivial names.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structure for 1-chloro-3-propargylcyclopentane is to be drawn.

Concept introduction:

Commonly used trivial names for substituents having C=C or C≡C are used when writing the name of a molecule. The root is named considering the longest continuous chain of carbon atom or the largest ring. The substituents are written with appropriate locator numbers and trivial names.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. B - Prob. B.1P Ch. B - Prob. B.2P Ch. B - Prob. B.3P Ch. B - Prob. B.4P Ch. B - Prob. B.5P Ch. B - Prob. B.6P Ch. B - Prob. B.7P Ch. B - Prob. B.8P Ch. B - Prob. B.9P Ch. B - Prob. B.10P

Solution Summary: The author explains the structure of 1, 4-divinylcyclohexane and allyl vinyl ether.

Concept explainers

(b)

Interpretation:

The structure for allyl vinyl ether is to be drawn.

Concept introduction:

Ethers are compounds containing an oxygen atom attached to alkyl groups. Their trivial names are written by writing the names of the two alkyl groups in alphabetical order followed by the word ether.

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Chapter B Solutions

Solution Summary: The author explains the structure of 1, 4-divinylcyclohexane and allyl vinyl ether.

Concept explainers

(b) Interpretation: The structure for allyl vinyl ether is to be drawn. Concept introduction: Ethers are compounds containing an oxygen atom attached to alkyl groups. Their trivial names are written by writing the names of the two alkyl groups in alphabetical order followed by the word ether.

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Chapter B Solutions

(b)

Interpretation:

The structure for allyl vinyl ether is to be drawn.

Concept introduction:

Ethers are compounds containing an oxygen atom attached to alkyl groups. Their trivial names are written by writing the names of the two alkyl groups in alphabetical order followed by the word ether.