a) Interpretation: The product of the two step process shown is to be given and complete electron-pushing mechanism for its formation also is to be provided. Concept introduction: The terminal alkynes being acidic form sodium alkynides when treated with bases like sodium amide. The alkynides when treated with alkyl halides yield the higher alkynes as the product. The alkynide ion being nucleophilic attacks the positively polarized carbon of C-X bond in alkyl halides displaces the halogen to yield the higher alkyne as the product. To propose: The product of the two step process shown and to give a complete electron-pushing mechanism for its formation.

Question

b) Certain cyclic compounds are known to be conformationally similar to carbohydrates, although they are not themselves carbohydrates. One example is Compound C shown below, which could be imagined as adopting four possible conformations. In reality, however, only one of these is particularly stable. Circle the conformation you expect to be the most stable, and provide an explanation to justify your choice. For your explanation to be both convincing and correct, it must contain not only words, but also "cartoon" orbital drawings contrasting the four structures. Compound C Possible conformations (circle one): Дет

Answer 1

Question

Chapter 9.SE, Problem 24MP

Interpretation Introduction

a)

Interpretation:

The product of the two step process shown is to be given and complete electron-pushing mechanism for its formation also is to be provided.

Concept introduction:

The terminal alkynes being acidic form sodium alkynides when treated with bases like sodium amide. The alkynides when treated with alkyl halides yield the higher alkynes as the product. The alkynide ion being nucleophilic attacks the positively polarized carbon of C-X bond in alkyl halides displaces the halogen to yield the higher alkyne as the product.

To propose:

The product of the two step process shown and to give a complete electron-pushing mechanism for its formation.

Interpretation Introduction

b)

Interpretation:

The product of the two step process shown is to be given and complete electron-pushing mechanism for its formation also is to be provided.

Concept introduction:

The terminal alkynes being acidic form sodium alkynides when treated with bases like sodium amide. The alkynides when treated with alkyl halides yield the higher alkynes as the product. The alkynide ion being nucleophilic attacks the positively polarized carbon of C-X bond in alkyl halides displaces the halogen to yield the higher alkyne as the product.

To propose:

The product of the two step process shown and to give a complete electron-pushing mechanism for its formation.

Interpretation Introduction

c)

Interpretation:

The product of the two step process shown is to be given and complete electron-pushing mechanism for its formation also is to be provided.

Concept introduction:

The terminal alkynes being acidic form sodium alkynide when treated with bases like sodium amide. The alkynides when treated with alkyl halides yield the higher alkynes as the product. The alkynide ion being nucleophilic attacks the positively polarized carbon of C-X bond in alkyl halides displaces the halogen to yield the higher alkyne as the product.

To propose:

The product of the two step process shown and to give a complete electron-pushing mechanism for its formation.

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b) Certain cyclic compounds are known to be conformationally similar to carbohydrates, although they are not themselves carbohydrates. One example is Compound C shown below, which could be imagined as adopting four possible conformations. In reality, however, only one of these is particularly stable. Circle the conformation you expect to be the most stable, and provide an explanation to justify your choice. For your explanation to be both convincing and correct, it must contain not only words, but also "cartoon" orbital drawings contrasting the four structures. Compound C Possible conformations (circle one): Дет

Lab Data The distance entered is out of the expected range. Check your calculations and conversion factors. Verify your distance. Will the gas cloud be closer to the cotton ball with HCI or NH3? Did you report your data to the correct number of significant figures? - X Experimental Set-up HCI-NH3 NH3-HCI Longer Tube Time elapsed (min) 5 (exact) 5 (exact) Distance between cotton balls (cm) 24.30 24.40 Distance to cloud (cm) 9.70 14.16 Distance traveled by HCI (cm) 9.70 9.80 Distance traveled by NH3 (cm) 14.60 14.50 Diffusion rate of HCI (cm/hr) 116 118 Diffusion rate of NH3 (cm/hr) 175.2 175.2 How to measure distance and calculate rate

For the titration of a divalent metal ion (M2+) with EDTA, the stoichiometry of the reaction is typically: 1:1 (one mole of EDTA per mole of metal ion) 2:1 (two moles of EDTA per mole of metal ion) 1:2 (one mole of EDTA per two moles of metal ion) None of the above

Answer 2

Question

Chapter 9.SE, Problem 24MP

Interpretation Introduction

a)

Interpretation:

The product of the two step process shown is to be given and complete electron-pushing mechanism for its formation also is to be provided.

Concept introduction:

The terminal alkynes being acidic form sodium alkynides when treated with bases like sodium amide. The alkynides when treated with alkyl halides yield the higher alkynes as the product. The alkynide ion being nucleophilic attacks the positively polarized carbon of C-X bond in alkyl halides displaces the halogen to yield the higher alkyne as the product.

To propose:

The product of the two step process shown and to give a complete electron-pushing mechanism for its formation.

Interpretation Introduction

b)

Interpretation:

The product of the two step process shown is to be given and complete electron-pushing mechanism for its formation also is to be provided.

Concept introduction:

The terminal alkynes being acidic form sodium alkynides when treated with bases like sodium amide. The alkynides when treated with alkyl halides yield the higher alkynes as the product. The alkynide ion being nucleophilic attacks the positively polarized carbon of C-X bond in alkyl halides displaces the halogen to yield the higher alkyne as the product.

To propose:

The product of the two step process shown and to give a complete electron-pushing mechanism for its formation.

Interpretation Introduction

c)

Interpretation:

The product of the two step process shown is to be given and complete electron-pushing mechanism for its formation also is to be provided.

Concept introduction:

The terminal alkynes being acidic form sodium alkynide when treated with bases like sodium amide. The alkynides when treated with alkyl halides yield the higher alkynes as the product. The alkynide ion being nucleophilic attacks the positively polarized carbon of C-X bond in alkyl halides displaces the halogen to yield the higher alkyne as the product.

To propose:

The product of the two step process shown and to give a complete electron-pushing mechanism for its formation.

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Answer 3

Question

Chapter 9.SE, Problem 24MP

Interpretation Introduction

a)

Interpretation:

The product of the two step process shown is to be given and complete electron-pushing mechanism for its formation also is to be provided.

Concept introduction:

The terminal alkynes being acidic form sodium alkynides when treated with bases like sodium amide. The alkynides when treated with alkyl halides yield the higher alkynes as the product. The alkynide ion being nucleophilic attacks the positively polarized carbon of C-X bond in alkyl halides displaces the halogen to yield the higher alkyne as the product.

To propose:

The product of the two step process shown and to give a complete electron-pushing mechanism for its formation.

Interpretation Introduction

b)

Interpretation:

The product of the two step process shown is to be given and complete electron-pushing mechanism for its formation also is to be provided.

Concept introduction:

The terminal alkynes being acidic form sodium alkynides when treated with bases like sodium amide. The alkynides when treated with alkyl halides yield the higher alkynes as the product. The alkynide ion being nucleophilic attacks the positively polarized carbon of C-X bond in alkyl halides displaces the halogen to yield the higher alkyne as the product.

To propose:

The product of the two step process shown and to give a complete electron-pushing mechanism for its formation.

Interpretation Introduction

c)

Interpretation:

The product of the two step process shown is to be given and complete electron-pushing mechanism for its formation also is to be provided.

Concept introduction:

The terminal alkynes being acidic form sodium alkynide when treated with bases like sodium amide. The alkynides when treated with alkyl halides yield the higher alkynes as the product. The alkynide ion being nucleophilic attacks the positively polarized carbon of C-X bond in alkyl halides displaces the halogen to yield the higher alkyne as the product.

To propose:

The product of the two step process shown and to give a complete electron-pushing mechanism for its formation.

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Answer 4

Question

Chapter 9.SE, Problem 24MP

Interpretation Introduction

a)

Interpretation:

The product of the two step process shown is to be given and complete electron-pushing mechanism for its formation also is to be provided.

Concept introduction:

The terminal alkynes being acidic form sodium alkynides when treated with bases like sodium amide. The alkynides when treated with alkyl halides yield the higher alkynes as the product. The alkynide ion being nucleophilic attacks the positively polarized carbon of C-X bond in alkyl halides displaces the halogen to yield the higher alkyne as the product.

To propose:

The product of the two step process shown and to give a complete electron-pushing mechanism for its formation.

Interpretation Introduction

b)

Interpretation:

The product of the two step process shown is to be given and complete electron-pushing mechanism for its formation also is to be provided.

Concept introduction:

The terminal alkynes being acidic form sodium alkynides when treated with bases like sodium amide. The alkynides when treated with alkyl halides yield the higher alkynes as the product. The alkynide ion being nucleophilic attacks the positively polarized carbon of C-X bond in alkyl halides displaces the halogen to yield the higher alkyne as the product.

To propose:

The product of the two step process shown and to give a complete electron-pushing mechanism for its formation.

Interpretation Introduction

c)

Interpretation:

The product of the two step process shown is to be given and complete electron-pushing mechanism for its formation also is to be provided.

Concept introduction:

The terminal alkynes being acidic form sodium alkynide when treated with bases like sodium amide. The alkynides when treated with alkyl halides yield the higher alkynes as the product. The alkynide ion being nucleophilic attacks the positively polarized carbon of C-X bond in alkyl halides displaces the halogen to yield the higher alkyne as the product.

To propose:

The product of the two step process shown and to give a complete electron-pushing mechanism for its formation.

Expert Solution & Answer

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Answer 5

Chapter 9.SE, Problem 24MP

Interpretation Introduction

a)

Interpretation:

The product of the two step process shown is to be given and complete electron-pushing mechanism for its formation also is to be provided.

Concept introduction:

The terminal alkynes being acidic form sodium alkynides when treated with bases like sodium amide. The alkynides when treated with alkyl halides yield the higher alkynes as the product. The alkynide ion being nucleophilic attacks the positively polarized carbon of C-X bond in alkyl halides displaces the halogen to yield the higher alkyne as the product.

To propose:

The product of the two step process shown and to give a complete electron-pushing mechanism for its formation.

Interpretation Introduction

b)

Interpretation:

The product of the two step process shown is to be given and complete electron-pushing mechanism for its formation also is to be provided.

Concept introduction:

The terminal alkynes being acidic form sodium alkynides when treated with bases like sodium amide. The alkynides when treated with alkyl halides yield the higher alkynes as the product. The alkynide ion being nucleophilic attacks the positively polarized carbon of C-X bond in alkyl halides displaces the halogen to yield the higher alkyne as the product.

To propose:

The product of the two step process shown and to give a complete electron-pushing mechanism for its formation.

Interpretation Introduction

c)

Interpretation:

The product of the two step process shown is to be given and complete electron-pushing mechanism for its formation also is to be provided.

Concept introduction:

The terminal alkynes being acidic form sodium alkynide when treated with bases like sodium amide. The alkynides when treated with alkyl halides yield the higher alkynes as the product. The alkynide ion being nucleophilic attacks the positively polarized carbon of C-X bond in alkyl halides displaces the halogen to yield the higher alkyne as the product.

To propose:

The product of the two step process shown and to give a complete electron-pushing mechanism for its formation.

Answer 6

Chapter 9.SE, Problem 24MP

Interpretation Introduction

a)

Interpretation:

The product of the two step process shown is to be given and complete electron-pushing mechanism for its formation also is to be provided.

Concept introduction:

The terminal alkynes being acidic form sodium alkynides when treated with bases like sodium amide. The alkynides when treated with alkyl halides yield the higher alkynes as the product. The alkynide ion being nucleophilic attacks the positively polarized carbon of C-X bond in alkyl halides displaces the halogen to yield the higher alkyne as the product.

To propose:

The product of the two step process shown and to give a complete electron-pushing mechanism for its formation.

Answer 7

Chapter 9.SE, Problem 24MP

Interpretation Introduction

a)

Interpretation:

The product of the two step process shown is to be given and complete electron-pushing mechanism for its formation also is to be provided.

Concept introduction:

The terminal alkynes being acidic form sodium alkynides when treated with bases like sodium amide. The alkynides when treated with alkyl halides yield the higher alkynes as the product. The alkynide ion being nucleophilic attacks the positively polarized carbon of C-X bond in alkyl halides displaces the halogen to yield the higher alkyne as the product.

To propose:

The product of the two step process shown and to give a complete electron-pushing mechanism for its formation.

Answer 8

Interpretation Introduction

b)

Interpretation:

The product of the two step process shown is to be given and complete electron-pushing mechanism for its formation also is to be provided.

Concept introduction:

The terminal alkynes being acidic form sodium alkynides when treated with bases like sodium amide. The alkynides when treated with alkyl halides yield the higher alkynes as the product. The alkynide ion being nucleophilic attacks the positively polarized carbon of C-X bond in alkyl halides displaces the halogen to yield the higher alkyne as the product.

To propose:

The product of the two step process shown and to give a complete electron-pushing mechanism for its formation.

Answer 9

Interpretation Introduction

b)

Interpretation:

The product of the two step process shown is to be given and complete electron-pushing mechanism for its formation also is to be provided.

Concept introduction:

The terminal alkynes being acidic form sodium alkynides when treated with bases like sodium amide. The alkynides when treated with alkyl halides yield the higher alkynes as the product. The alkynide ion being nucleophilic attacks the positively polarized carbon of C-X bond in alkyl halides displaces the halogen to yield the higher alkyne as the product.

To propose:

The product of the two step process shown and to give a complete electron-pushing mechanism for its formation.

Answer 10

Interpretation Introduction

c)

Interpretation:

The product of the two step process shown is to be given and complete electron-pushing mechanism for its formation also is to be provided.

Concept introduction:

The terminal alkynes being acidic form sodium alkynide when treated with bases like sodium amide. The alkynides when treated with alkyl halides yield the higher alkynes as the product. The alkynide ion being nucleophilic attacks the positively polarized carbon of C-X bond in alkyl halides displaces the halogen to yield the higher alkyne as the product.

To propose:

The product of the two step process shown and to give a complete electron-pushing mechanism for its formation.

Answer 11

Interpretation Introduction

c)

Interpretation:

The product of the two step process shown is to be given and complete electron-pushing mechanism for its formation also is to be provided.

Concept introduction:

The terminal alkynes being acidic form sodium alkynide when treated with bases like sodium amide. The alkynides when treated with alkyl halides yield the higher alkynes as the product. The alkynide ion being nucleophilic attacks the positively polarized carbon of C-X bond in alkyl halides displaces the halogen to yield the higher alkyne as the product.

To propose:

The product of the two step process shown and to give a complete electron-pushing mechanism for its formation.

Answer 12

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Answer 23

Ch. 9.1 - Prob. 1P Ch. 9.1 - Prob. 2P Ch. 9.3 - What products would you expect from the following...Ch. 9.4 - Prob. 4P Ch. 9.4 - Prob. 5P Ch. 9.4 - Prob. 6P Ch. 9.4 - Prob. 7P Ch. 9.5 - Using any alkyne needed, how would you prepare the...Ch. 9.7 - The pKa of acetone, CH3COCH3, is 19.3. Which of...Ch. 9.8 - Prob. 10P

Solution Summary: The author proposes the product of the two step process shown and to give a complete electron-pushing mechanism for its formation.

Chapter 9 Solutions