General, Organic, and Biological Chemistry Seventh Edition
7th Edition
ISBN: 9781305767867
Author: H. Stephan Stoker
Publisher: Cengage Learning
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Textbook Question
Chapter 9.8, Problem 1QQ
Which of the following is the correct equilibrium constant expression for the reaction
- a. [A] [2B]/[3C]
- b. [3C]/[A] [2B]
- c. [A] [B]/[C]
- d. no correct response
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Relative Intensity
Part VI. consider the multi-step reaction below for compounds
A, B, and C.
These compounds were subjected to mass spectrometric analysis and
the following spectra for A, B, and C was obtained.
Draw the structure of B and C and match all three compounds
to the correct spectra.
Relative Intensity
Relative Intensity
100
HS-NJ-0547
80
60
31
20
S1
84
M+
absent
10
30
40
50
60
70
80
90
100
100-
MS2016-05353CM
80-
60
40
20
135 137
S2
164 166
0-m
25
50
75
100
125
150
m/z
60
100
MS-NJ-09-43
40
20
20
80
45
S3
25
50
75
100
125
150
175
m/z
Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Chapter 9 Solutions
General, Organic, and Biological Chemistry Seventh Edition
Ch. 9.1 - Prob. 1QQCh. 9.1 - Prob. 2QQCh. 9.1 - Prob. 3QQCh. 9.2 - The proper assignment of oxidation numbers to the...Ch. 9.2 - The proper assignment of oxidation numbers to the...Ch. 9.2 - Prob. 3QQCh. 9.3 - Prob. 1QQCh. 9.3 - Prob. 2QQCh. 9.3 - Prob. 3QQCh. 9.3 - Prob. 4QQ
Ch. 9.3 - Prob. 5QQCh. 9.4 - Prob. 1QQCh. 9.4 - Prob. 2QQCh. 9.4 - Prob. 3QQCh. 9.5 - Prob. 1QQCh. 9.5 - Prob. 2QQCh. 9.5 - For endothermic chemical reactions the energy...Ch. 9.6 - Prob. 1QQCh. 9.6 - Prob. 2QQCh. 9.6 - Prob. 3QQCh. 9.7 - Prob. 1QQCh. 9.7 - Prob. 2QQCh. 9.7 - Prob. 3QQCh. 9.8 - Which of the following is the correct equilibrium...Ch. 9.8 - Prob. 2QQCh. 9.8 - Prob. 3QQCh. 9.9 - Prob. 1QQCh. 9.9 - Prob. 2QQCh. 9.9 - Prob. 3QQCh. 9.9 - Prob. 4QQCh. 9 - What is the general chemical equation for each of...Ch. 9 - What is the general chemical equation for each of...Ch. 9 - Classify each of the following reactions as a...Ch. 9 - Classify each of the following reactions as a...Ch. 9 - Write the chemical formulas for the products...Ch. 9 - Write the chemical formulas for the products...Ch. 9 - Indicate whether or not each of the following...Ch. 9 - Indicate whether or not each of the following...Ch. 9 - Indicate to which of the following types of...Ch. 9 - Indicate to which of the following types of...Ch. 9 - What is the oxidation number of S in each of the...Ch. 9 - Prob. 9.12EPCh. 9 - Determine the oxidation number of the indicated...Ch. 9 - Determine the oxidation number of the indicated...Ch. 9 - Prob. 9.15EPCh. 9 - Prob. 9.16EPCh. 9 - What is the oxidation number of each element...Ch. 9 - What is the oxidation number of each element...Ch. 9 - Classify each of the following reactions as a...Ch. 9 - Classify each of the following reactions as a...Ch. 9 - Classify each of the following reactions as (1) a...Ch. 9 - Prob. 9.22EPCh. 9 - Classify each of the following reactions using one...Ch. 9 - Classify each of the following reactions using one...Ch. 9 - Prob. 9.25EPCh. 9 - In each of the following changes is the reactant...Ch. 9 - Identify which substance is oxidized and which...Ch. 9 - Identify which substance is oxidized and which...Ch. 9 - Prob. 9.29EPCh. 9 - Prob. 9.30EPCh. 9 - Indicate whether each of the following substances...Ch. 9 - Indicate whether each of the following substances...Ch. 9 - Prob. 9.33EPCh. 9 - Prob. 9.34EPCh. 9 - What are the three central concepts associated...Ch. 9 - Why are most chemical reactions carried out either...Ch. 9 - What two factors determine whether a collision...Ch. 9 - What happens to the reactants in an ineffective...Ch. 9 - Which of the following reactions are endothermic,...Ch. 9 - Prob. 9.40EPCh. 9 - Should heat be added as a reactant or as a product...Ch. 9 - Should heat be added as a reactant or as a product...Ch. 9 - Prob. 9.43EPCh. 9 - Indicate whether each of the following is a...Ch. 9 - Sketch an energy diagram graph representing an...Ch. 9 - Sketch an energy diagram graph representing an...Ch. 9 - Using collision theory, indicate why each of the...Ch. 9 - Using collision theory, indicate why each of the...Ch. 9 - Substances burn more rapidly in pure oxygen than...Ch. 9 - Milk will sour in a couple of days when left at...Ch. 9 - Will each of the changes listed increase or...Ch. 9 - Will each of the changes listed increase or...Ch. 9 - For each of the changes listed will the rate of...Ch. 9 - For each of the changes listed will the rate of...Ch. 9 - Prob. 9.55EPCh. 9 - Draw an energy diagram graph for an endothermic...Ch. 9 - The characteristics of four reactions, each of...Ch. 9 - The characteristics of four reactions, each of...Ch. 9 - What condition must be met in order for a system...Ch. 9 - What relationship exists between the rates of the...Ch. 9 - What does the term reversible reaction mean?Ch. 9 - What does the notation denote when it is used in...Ch. 9 - Consider the following equilibrium system....Ch. 9 - Consider the following equilibrium system....Ch. 9 - Prob. 9.65EPCh. 9 - Sketch a graph showing how the rates of the...Ch. 9 - The following series of diagrams represent the...Ch. 9 - The following series of diagrams represent the...Ch. 9 - For the reaction A2 + 2B 2AB, diagram I depicts...Ch. 9 - For the reaction A2 + B2 2AB, diagram I depicts...Ch. 9 - Write equilibrium constant expressions for the...Ch. 9 - Write equilibrium constant expressions for the...Ch. 9 - Write equilibrium constant expressions for the...Ch. 9 - Prob. 9.74EPCh. 9 - Calculate the value of the equilibrium constant...Ch. 9 - Calculate the value of the equilibrium constant...Ch. 9 - Prob. 9.77EPCh. 9 - Use the given Keq value and the terminology in...Ch. 9 - Write a balanced chemical equation for a totally...Ch. 9 - Write a balanced chemical equation for a totally...Ch. 9 - The following four diagrams represent gaseous...Ch. 9 - Based on the diagrams, chemical reaction, and...Ch. 9 - The following four diagrams represent gaseous...Ch. 9 - Based on the diagrams, chemical reaction, and...Ch. 9 - Indicate whether or not each of the following...Ch. 9 - Indicate whether or not each of the following...Ch. 9 - For the generalized chemical reaction...Ch. 9 - For the generalized chemical reaction...Ch. 9 - Prob. 9.89EPCh. 9 - For the reaction C6H6(g)+3H2(g)C6H12(g)+heat...Ch. 9 - Consider the following chemical system at...Ch. 9 - Prob. 9.92EPCh. 9 - The following two diagrams represent the...Ch. 9 - The following two diagrams represent the...Ch. 9 - Indicate whether or not product formation...Ch. 9 - Prob. 9.96EPCh. 9 - Prob. 9.97EPCh. 9 - Indicate whether or not product formation...
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