
Principles of General Organic & Biological Chemistry
2nd Edition
ISBN: 9780077633721
Author: Janice Smith
Publisher: Mcgraw-hill Higher Education (us)
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Question
Chapter 9.2, Problem 9.7P
(a)
Interpretation Introduction
Interpretation:
The balanced nuclear reaction for an alpha decay of Polonium-218 has to be given.
Concept Introduction:
Alpha decay reaction:
Alpha decay is one process that unstable atoms can use to become more stable. During alpha decay, an atomsnucleus sheds two protons and two neutrons in a packet that is known as an alpha particle.
(b)
Interpretation Introduction
Interpretation:
The balanced nuclear reaction for an alpha decay of Thorium-230 has to be given.
Concept Introduction:
Refer to part (a).
(c)
Interpretation Introduction
Interpretation:
The balanced nuclear reaction for an alpha decay of Einstenium-252 has to be given.
Concept Introduction:
Refer to part (a).
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For the decomposition reaction of N2O5(g): 2 N2O5(g) → 4 NO2(g) + O2(g), the following mechanism has been proposed:
N2O5 NO2 + NO3 (K1) | NO2 + NO3 → N2O5 (k-1) | NO2 + NO3 NO2 + O2 + NO (k2) | NO + N2O51 NO2 + NO2 + NO2 (K3)
→
Give the expression for the acceptable rate.
→
→
(A).
d[N205]
dt
==
2k,k₂[N₂O₂]
k₁+k₁₂
(B).
d[N2O5]
=-k₁[N₂O] + k₁[NO₂] [NO3] - k₂[NO₂]³
dt
(C).
d[N2O5]
=-k₁[N₂O] + k [NO] - k₂[NO] [NO]
d[N2O5]
(D).
=
dt
= -k₁[N2O5] - k¸[NO][N₂05]
dt
Do not apply the calculations, based on the approximation of the stationary state, to make them perform correctly. Basta discard
the 3 responses that you encounter that are obviously erroneous if you apply the formula to determine the speed of a reaction.
R lactam or lactone considering as weak acid or weak base and why
81. a. Propose a mechanism for the following reaction:
OH
CH2=CHCHC=N
b. What is the product of the following reaction?
HO
H₂O
N=CCH2CH2CH
OH
HO
CH3CCH=CH2
H₂O
C=N
82. Unlike a phosphonium ylide that reacts with an aldehyde or a ketone to form an alkene a sulfonium ulia
Chapter 9 Solutions
Principles of General Organic & Biological Chemistry
Ch. 9.1 - Prob. 9.1PCh. 9.1 - What is the difference between an particle and a...Ch. 9.1 - Prob. 9.3PCh. 9.1 - Identify Q in each of the following symbols. a....Ch. 9.2 - Prob. 9.5PCh. 9.2 - Prob. 9.6PCh. 9.2 - Prob. 9.7PCh. 9.2 - Prob. 9.8PCh. 9.2 - Prob. 9.9PCh. 9.2 - Prob. 9.10P
Ch. 9.2 - Prob. 9.11PCh. 9.3 - Prob. 9.13PCh. 9.3 - Prob. 9.14PCh. 9.3 - Prob. 9.15PCh. 9.3 - Prob. 9.16PCh. 9.4 - Prob. 9.17PCh. 9.4 - Prob. 9.18PCh. 9.5 - Prob. 9.19PCh. 9.5 - Prob. 9.20PCh. 9.6 - Prob. 9.21PCh. 9.6 - Prob. 9.22PCh. 9 - Compare fluorine-18 and fluorine-19 with regard to...Ch. 9 - Prob. 9.24UKCCh. 9 - Prob. 9.29UKCCh. 9 - Prob. 9.30UKCCh. 9 - Prob. 9.31APCh. 9 - Prob. 9.32APCh. 9 - Prob. 9.33APCh. 9 - Prob. 9.35APCh. 9 - Prob. 9.36APCh. 9 - Prob. 9.37APCh. 9 - Prob. 9.38APCh. 9 - Prob. 9.39APCh. 9 - Prob. 9.40APCh. 9 - Prob. 9.41APCh. 9 - Prob. 9.42APCh. 9 - Prob. 9.43APCh. 9 - Prob. 9.44APCh. 9 - Prob. 9.45APCh. 9 - Prob. 9.46APCh. 9 - Prob. 9.47APCh. 9 - Prob. 9.48APCh. 9 - Prob. 9.49APCh. 9 - Prob. 9.50APCh. 9 - Prob. 9.51APCh. 9 - Prob. 9.52APCh. 9 - Prob. 9.53APCh. 9 - Prob. 9.54APCh. 9 - Prob. 9.55APCh. 9 - Prob. 9.56APCh. 9 - Prob. 9.57APCh. 9 - Prob. 9.58APCh. 9 - Prob. 9.59APCh. 9 - Prob. 9.60APCh. 9 - Prob. 9.61APCh. 9 - Prob. 9.62APCh. 9 - Prob. 9.63APCh. 9 - Prob. 9.64APCh. 9 - Prob. 9.67APCh. 9 - Prob. 9.68APCh. 9 - Prob. 9.69APCh. 9 - Prob. 9.70APCh. 9 - Prob. 9.71APCh. 9 - Prob. 9.72APCh. 9 - Prob. 9.73APCh. 9 - Prob. 9.74APCh. 9 - Prob. 9.75APCh. 9 - Prob. 9.76APCh. 9 - Prob. 9.77APCh. 9 - Prob. 9.78APCh. 9 - Prob. 9.79APCh. 9 - Prob. 9.80APCh. 9 - Prob. 9.81APCh. 9 - Prob. 9.82APCh. 9 - Prob. 9.83APCh. 9 - Prob. 9.84APCh. 9 - Prob. 9.85APCh. 9 - Prob. 9.86APCh. 9 - Prob. 9.87CPCh. 9 - Prob. 9.88CP
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