Principles of General Organic & Biological Chemistry
Principles of General Organic & Biological Chemistry
2nd Edition
ISBN: 9780077633721
Author: Janice Smith
Publisher: Mcgraw-hill Higher Education (us)
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Chapter 9, Problem 9.42AP
Interpretation Introduction

Interpretation:

The balanced nuclear reaction for the decay of lead-210 to form Thallium-210 and Polonium-214 has to be given.

Concept Introduction:

Positron emission reaction:

Positron particles are electrons with positive electric charge. Positron decay occurs when in a nucleus with too many protons or too many neutrons, one of the protons or neutrons is transformed into the other.

  ZAXZ-1AX++10e

Alpha absorption reaction:

An alpha particle is a high energy particle that contains two protons and two neutrons.  An alpha particle is symbolized by the Greek letter alpha or the element symbol for helium has +2 charge and mass number of four.  If an alpha particle is emitted the mass of the nucleus decreased by four and the charge of the nucleus is decreased by two.

  ZAX+24αZ+2A+4X

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a. What is the eluent used in the column chromatography here (a “silica plug filtration” is essentially a very short column)? b. The spectroscopy of compound 5b is described in the second half of this excerpt, including 1H-NMR and 13C-NMR (which you will learn about in CHEM 2412L), MS (which you will learn about later in CHEM 2411L) and IR. One of the IR signals is at 3530 cm-1. What functional group does this indicate might be present in compound 5b?
Steps and explanations. Also provide, if possible, ways to adress this kind of problems in general.
a. The first three lines of this procedure describe the reaction used to make compound 5b. In the fourth line, hexane and sodium bicarbonate are added. What organic lab technique is being used here?  b. What is the purpose of the Na2SO4?  c. What equipment would you use to “concentrate [a solution] under reduced pressure”?

Chapter 9 Solutions

Principles of General Organic & Biological Chemistry

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