EBK EXPERIMENTAL ORGANIC CHEMISTRY: A M
6th Edition
ISBN: 9781305687875
Author: Gilbert
Publisher: CENGAGE LEARNING - CONSIGNMENT
expand_more
expand_more
format_list_bulleted
Question
Chapter 9.2, Problem 20E
(a)
Interpretation Introduction
Interpretation: Considering the mono-chlorination of heptane using ABCN (1) and sulfuryl chloride, the structures and names of the possible mono-chlorination products that could be produced, needs to be written.
Concept Introduction: Heptane, being a main component of gasoline, has a chemical formula of
(b)
Interpretation Introduction
Interpretation: Considering the mono-chlorination of heptane using ABCN (1) and sulfuryl chloride, the center(s) of chirality, if any, that are present in the isomers derived in Part a, needs to be circled.
Concept Introduction: When an atom is bonded to four other groups, such that the group is held in space with this atom becoming the stereocenter, and the mirror image of the bond is non-superimposable, then this atom is called chiral center or chirality center.
(c)
Interpretation Introduction
Interpretation: The structure of each sample needs to be determined using the 1H and 13C NMR spectroscopic data.
Concept Introduction: Stereoscopic imaging is used to view and understand three dimensional images and record the same, such that the viewer will also be able to see and understand the depth of the image.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Draw the structure(s) of the major organic product(s) of the following reaction.
CrO3/H30*
• You do not have to consider stereochemistry.
• If no reaction occurs, draw the organic starting material.
• Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bott
Separate multiple products using the sign from the drop-down menu.
●
90-85
[...
?
ChemDoodle"
h
SIF
>
remove
Draw the structure(s) of the major organic product(s) of the following reaction.
H
1. NaBH / methanol
2. aqueous HCI
• You do not have to consider stereochemistry.
.
You do not have to explicitly draw H atoms.
• Do not include lone pairs in your answer. They will not be considered in the grading.
●
If no reaction occurs, draw the organic starting material.
Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner.
• Separate multiple products using the + sign from the drop-down menu.
sall
ChemDoodleⓇ
On [F
за
Draw the structure(s) of the major organic product(s) of the following reaction.
H
SILL
KMnO, / aqueous H₂SO,
• You do not have to consider stereochemistry.
• You do not have to explicitly draw H atoms.
.
Do not include lone pairs in your answer. They will not be considered in the grading.
●
If no reaction occurs, draw the organic starting material.
• Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner.
• Separate multiple products using the + sign from the drop-down menu.
ChemDoodleⓇ
n[F
66
Chapter 9 Solutions
EBK EXPERIMENTAL ORGANIC CHEMISTRY: A M
Ch. 9.2 - Prob. 1ECh. 9.2 - Prob. 2ECh. 9.2 - Prob. 3ECh. 9.2 - Prob. 4ECh. 9.2 - Prob. 5ECh. 9.2 - Prob. 6ECh. 9.2 - Prob. 7ECh. 9.2 - Prob. 8ECh. 9.2 - Prob. 9ECh. 9.2 - Prob. 10E
Ch. 9.2 - Prob. 11ECh. 9.2 - Prob. 12ECh. 9.2 - Prob. 13ECh. 9.2 - Prob. 14ECh. 9.2 - Prob. 15ECh. 9.2 - Prob. 16ECh. 9.2 - Prob. 17ECh. 9.2 - Prob. 18ECh. 9.2 - Prob. 19ECh. 9.2 - Prob. 20ECh. 9.2 - Prob. 21ECh. 9.2 - Prob. 22ECh. 9.2 - Prob. 23ECh. 9.2 - Prob. 24ECh. 9.3 - Prob. 1ECh. 9.3 - Prob. 2ECh. 9.3 - Prob. 3ECh. 9.3 - Prob. 4ECh. 9.3 - Prob. 5ECh. 9.3 - Prob. 6ECh. 9.3 - Prob. 7ECh. 9.3 - Prob. 8ECh. 9.3 - Prob. 9ECh. 9.3 - Prob. 10ECh. 9.3 - Prob. 11ECh. 9.3 - Prob. 12ECh. 9.3 - Prob. 13ECh. 9.3 - Prob. 14E
Knowledge Booster
Similar questions
- Draw the structure of the major organic product(s) of the reaction. H3C 1. DIBAH, toluene 2. H,0+ DIBAH = diisobutylaluminum hydride, [(CH3),CHCH2],ÁIH • You do not have to consider stereochemistry. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate multiple products using the + sign from the drop-down menu.arrow_forwarda. Name the following structure. Use the correct stereochemistry notation where needed. ** Name b. Draw the structure of (3R,5S)-4-isopropyl-3,5-dimethylheptane. ( Structurearrow_forwardDraw the structure of the organic product(s) of the reaction between (S)-3-methylhexan-2-one and ethylmagnesium bromide, followed by acidification. • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate multiple products using the sign from the drop-down menu. My 3 32 00-05 OO° [] +▾ ChemDoodleⓇarrow_forward
- Answer number 19, 20, and 21.arrow_forwardDraw the organic product(s) of the following reactions including stereochemistry when it is appropriate. H₂ Lindlar catalyst H3C-CEC-CH3 • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • Consider E/Z stereochemistry of alkenes. • If no reaction occurs, draw the organic starting material. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Separate multiple products using the + sign from the drop-down menu. + ▾ 53 ChemDoodleⓇ On [F 6barrow_forwardDraw the structure of the organic product of the reaction between cyclohexene and H₂, Pd/C. • Use the wedge/hash bond tools to indicate stereochemistry where it exists. Separate multiple products using the + sign from the drop-down menu. . In cases where there is more than one answer, just draw one.arrow_forward
- Draw the organic product(s) of the following reaction. You do not have to consider stereochemistry. • Include cationic counter-ions, e.g., Nat in your answer, but draw them in their own sketcher. CH₂CH₂-CEC-H • If no reaction occurs, draw the organic starting material. . Separate multiple products using the + sign from the drop-down menu. . Show Transcribed Text . -81 . *** NaOH/H₂O Review Topics] Draw the organic product(s) of the following reaction. NANH, NHS() -CEC- S References You do not have to consider stereochemistry. Include cationic counter-ions, e.g., Na* in your answer, but draw them in their c sketcher. If no reaction occurs, draw the organic starting material. Separate multiple products using the + sign from the drop-down menu.arrow_forward4. Write in the product, including stereochemistry where relevant, for these reactions. See end of ch. 8, p. 301-303. 1. 03 2. Zn, H* a) 3-methylcyclohexene b) 1-ethylcyclopentene Br₂ →arrow_forward[References] The synthesis of carbohydrates can be particularly difficult because of the large number of chiral centers and OH functional groups present. Epoxides can be useful synthetic intermediates in carbohydrate synthesis. Draw the product of the reaction of a phenyl Gilman reagent with this epoxide. Å . • • Use the wedge/hash bond tools to indicate stereochemistry where it exists. Explicitly define the cis/trans stereochemistry of fused rings using wedge or hash bonds. If enantiomers are formed, draw both. Separate multiple products using the + sign from the drop-down menu. 0 Θ F ? ChemDoodle remove Previous Nexarrow_forward
- Draw the structure(s) of the major organic product(s) of the following reaction. bul H₂C • Use the wedge/hash bond tools to indicate stereochemistry where it exists. • If the reaction produces a racemic mixture, draw both stereoisomers. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. • Include anionic counter-ions, e.g., I, in your answer, but draw them in their own sketcher. B CH₂ PPh ChemDoodle THFarrow_forwardDraw the structure of the major organic product(s) of the reaction. 99-85 / CI You do not have to consider stereochemistry. • All carboxyl and amino groups should be drawn in the neutral form. • If no reaction occurs, draw the organic starting material. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corn- Separate multiple products using the sign from the drop-down menu. . *** OH HCI 000- /IF [References] Provinuarrow_forwardDraw a structural formula for ethyl benzoate. O • You do not have to consider stereochemistry. You do not have to explicitly draw H atoms. Do not include lone pairs in your answer. They will not be considered in the grading. ● ● [Review Topics] [References] Use the References to access important values if needed for this question. m... CH4 ? ChemDoodlearrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Macroscale and Microscale Organic ExperimentsChemistryISBN:9781305577190Author:Kenneth L. Williamson, Katherine M. MastersPublisher:Brooks Cole
Macroscale and Microscale Organic Experiments
Chemistry
ISBN:9781305577190
Author:Kenneth L. Williamson, Katherine M. Masters
Publisher:Brooks Cole