(a) Interpretation: The product of given reaction is to be drawn and the stereochemistry at any stereogenic center is to be indicated. Concept introduction: The strong nucleophiles that open epoxide ring are − OH, − OR , − CN, − SR, HC ≡ C − , and NH 3 . The reaction takes place through an S N 2 mechanism. The mechanism of overall reaction involves two steps.

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Answer 1

Question

Chapter 9.16, Problem 33P

Interpretation Introduction

(a)

Interpretation: The product of given reaction is to be drawn and the stereochemistry at any stereogenic center is to be indicated.

Concept introduction: The strong nucleophiles that open epoxide ring are −OH, −OR, −CN, −SR, HC≡C−, and NH3. The reaction takes place through an SN2 mechanism. The mechanism of overall reaction involves two steps.

Interpretation Introduction

(b)

Interpretation: The product of given reaction is to be drawn and the stereochemistry at any stereogenic center is to be indicated.

Concept introduction: The strong nucleophiles that open epoxide ring are −OH, −OR, −CN, −SR, HC≡C−, and NH3. The reaction takes place through an SN2 mechanism. The mechanism of overall reaction involves two steps.

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Using the general properties of equilibrium constants At a certain temperature, the equilibrium constant K for the following reaction is 1.3 × 10 4: Cl2(g) + CHCl3(g) HCl(g) + CC₁(g) Use this information to complete the following table. Suppose a 16. L reaction vessel is filled with 1.6 mol of HCI and 1.6 mol of CCl4. What can you say about the composition of the mixture in the vessel at equilibrium? There will be very little Cl2 and CHCl3. ☐ x10 There will be very little HCI and CCl4. Neither of the above is true. What is the equilibrium constant for the following reaction? Be sure your answer has the correct number of significant digits. HCl(g)+CC14(g) 12 Cl2(9)+CHCl3(9) K = 0 ☐ What is the equilibrium constant for the following reaction? Be sure your answer has the correct number of significant digits. 2 Cl₂(9)+2CHCl3(9) 2 HCl(9)+2CC₁₁(9) K = ✓ 00. 18 Ar

Answer 2

Question

Chapter 9.16, Problem 33P

Interpretation Introduction

(a)

Interpretation: The product of given reaction is to be drawn and the stereochemistry at any stereogenic center is to be indicated.

Concept introduction: The strong nucleophiles that open epoxide ring are −OH, −OR, −CN, −SR, HC≡C−, and NH3. The reaction takes place through an SN2 mechanism. The mechanism of overall reaction involves two steps.

Interpretation Introduction

(b)

Interpretation: The product of given reaction is to be drawn and the stereochemistry at any stereogenic center is to be indicated.

Concept introduction: The strong nucleophiles that open epoxide ring are −OH, −OR, −CN, −SR, HC≡C−, and NH3. The reaction takes place through an SN2 mechanism. The mechanism of overall reaction involves two steps.

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Answer 3

Question

Chapter 9.16, Problem 33P

Interpretation Introduction

(a)

Interpretation: The product of given reaction is to be drawn and the stereochemistry at any stereogenic center is to be indicated.

Concept introduction: The strong nucleophiles that open epoxide ring are −OH, −OR, −CN, −SR, HC≡C−, and NH3. The reaction takes place through an SN2 mechanism. The mechanism of overall reaction involves two steps.

Interpretation Introduction

(b)

Interpretation: The product of given reaction is to be drawn and the stereochemistry at any stereogenic center is to be indicated.

Concept introduction: The strong nucleophiles that open epoxide ring are −OH, −OR, −CN, −SR, HC≡C−, and NH3. The reaction takes place through an SN2 mechanism. The mechanism of overall reaction involves two steps.

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Answer 4

Question

Chapter 9.16, Problem 33P

Interpretation Introduction

(a)

Interpretation: The product of given reaction is to be drawn and the stereochemistry at any stereogenic center is to be indicated.

Concept introduction: The strong nucleophiles that open epoxide ring are −OH, −OR, −CN, −SR, HC≡C−, and NH3. The reaction takes place through an SN2 mechanism. The mechanism of overall reaction involves two steps.

Interpretation Introduction

(b)

Interpretation: The product of given reaction is to be drawn and the stereochemistry at any stereogenic center is to be indicated.

Concept introduction: The strong nucleophiles that open epoxide ring are −OH, −OR, −CN, −SR, HC≡C−, and NH3. The reaction takes place through an SN2 mechanism. The mechanism of overall reaction involves two steps.

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Answer 5

Chapter 9.16, Problem 33P

Interpretation Introduction

(a)

Interpretation: The product of given reaction is to be drawn and the stereochemistry at any stereogenic center is to be indicated.

Concept introduction: The strong nucleophiles that open epoxide ring are −OH, −OR, −CN, −SR, HC≡C−, and NH3. The reaction takes place through an SN2 mechanism. The mechanism of overall reaction involves two steps.

Interpretation Introduction

(b)

Interpretation: The product of given reaction is to be drawn and the stereochemistry at any stereogenic center is to be indicated.

Concept introduction: The strong nucleophiles that open epoxide ring are −OH, −OR, −CN, −SR, HC≡C−, and NH3. The reaction takes place through an SN2 mechanism. The mechanism of overall reaction involves two steps.

Answer 6

Chapter 9.16, Problem 33P

Interpretation Introduction

(a)

Interpretation: The product of given reaction is to be drawn and the stereochemistry at any stereogenic center is to be indicated.

Concept introduction: The strong nucleophiles that open epoxide ring are −OH, −OR, −CN, −SR, HC≡C−, and NH3. The reaction takes place through an SN2 mechanism. The mechanism of overall reaction involves two steps.

Answer 7

Chapter 9.16, Problem 33P

Interpretation Introduction

(a)

Interpretation: The product of given reaction is to be drawn and the stereochemistry at any stereogenic center is to be indicated.

Concept introduction: The strong nucleophiles that open epoxide ring are −OH, −OR, −CN, −SR, HC≡C−, and NH3. The reaction takes place through an SN2 mechanism. The mechanism of overall reaction involves two steps.

Answer 8

Interpretation Introduction

(b)

Interpretation: The product of given reaction is to be drawn and the stereochemistry at any stereogenic center is to be indicated.

Concept introduction: The strong nucleophiles that open epoxide ring are −OH, −OR, −CN, −SR, HC≡C−, and NH3. The reaction takes place through an SN2 mechanism. The mechanism of overall reaction involves two steps.

Answer 9

Interpretation Introduction

(b)

Interpretation: The product of given reaction is to be drawn and the stereochemistry at any stereogenic center is to be indicated.

Concept introduction: The strong nucleophiles that open epoxide ring are −OH, −OR, −CN, −SR, HC≡C−, and NH3. The reaction takes place through an SN2 mechanism. The mechanism of overall reaction involves two steps.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 9.1 - Problem 9.1 Label each ether and alcohol in...Ch. 9.3 - Give the IUPAC name for each compound.Ch. 9.3 - Problem 9.3 Give the structure corresponding to...Ch. 9.3 - Name each of the following ethers.Ch. 9.3 - Name each epoxide. a. (two ways) b. c. (two...Ch. 9.6 - Problem 9.8 Draw the organic product of each...Ch. 9.6 - Prob. 9P Ch. 9.6 - Problem 9.10 Draw the products of each reaction. ...Ch. 9.8 - Problem 9.11 Draw the products formed when each...Ch. 9.8 - Prob. 12P

Solution Summary: The author explains that the product of given reaction is drawn and the stereochemistry at any stereogenic center is indicated.

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