CNCT ORG CHEM 6 2020
6th Edition
ISBN: 9781266807244
Author: SMITH
Publisher: MCG
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Question
Chapter 9, Problem 51P
Interpretation Introduction
Interpretation: A stepwise detailed mechanism that illustrates formation of B and C products from A is to be drawn.
Concept introduction: The reaction of alcohols with halogen acids
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Please choose the best reagents to complete the following reaction
Problem 6-17
Look at the following energy diagram:
Energy
Reaction progress
(a) Is AG for the reaction positive or negative? Label it on the diagram.
(b) How many steps are involved in the reaction?
(c) How many transition states are there? Label them on the diagram.
Problem 6-19
What is the difference between a transition state and an intermediate?
Problem 6-21
Draw an energy diagram for a two-step reaction with Keq > 1. Label the overall AG°, transition states, and
intermediate. Is AG° positive or negative?
Problem 6-23
Draw an energy diagram for a reaction with Keq = 1. What is the value of AG° in this reaction?
Problem 6-37
Draw the different monochlorinated constitutional isomers you would obtain by the radical chlorination of the
following compounds.
(b)
(c)
Problem 6-39
Show the structure of the carbocation that would result when each of the following alkenes reacts with an
acid, H+.
(a)
(b)
(c)
Chapter 9 Solutions
CNCT ORG CHEM 6 2020
Ch. 9.1 - Problem 9.1 Label each ether and alcohol in...Ch. 9.3 - Give the IUPAC name for each compound.Ch. 9.3 - Problem 9.3 Give the structure corresponding to...Ch. 9.3 - Name each of the following ethers.Ch. 9.3 - Name each epoxide.
a. (two ways) b. c. (two...Ch. 9.6 - Problem 9.8 Draw the organic product of each...Ch. 9.6 - Prob. 9PCh. 9.6 - Problem 9.10 Draw the products of each reaction.
...Ch. 9.8 - Problem 9.11 Draw the products formed when each...Ch. 9.8 - Prob. 12P
Ch. 9.11 - Problem 9.18 Draw the products of each reaction,...Ch. 9.11 - Problem 9.19 What is the major product formed...Ch. 9.12 - Prob. 19PCh. 9.12 - Prob. 20PCh. 9.12 - Problem 9.22 Draw the organic products formed in...Ch. 9.12 - Problem 9.23 Draw two steps to convert into each...Ch. 9.13 - Prob. 23PCh. 9.13 - Problem 9.25 Draw the products of each reaction,...Ch. 9.13 - Draw the products formed when (S)-butan-2-ol is...Ch. 9.13 - Draw the product formed when (CH3)2CHOH is treated...Ch. 9.14 - What alkyl halides are formed when each ether is...Ch. 9.14 - Explain why the treatment of anisole with HBr...Ch. 9.15 - Name each thiol.
a. b.
Ch. 9.15 - Draw the product of each reaction. ac b.d.Ch. 9.15 - Give the IUPAC name for each sulfide.
a. b.
Ch. 9.15 - Draw the product of each reaction.
a. b.
Ch. 9.16 - Prob. 33PCh. 9.16 - The cis and trans isomers of 2, 3-dimethyloxirane...Ch. 9.16 - Problem 9.36 Draw the product of each...Ch. 9 - 9.37 Name each compound depicted in the...Ch. 9 - Answer each question using the ball-and-stick...Ch. 9 - Prob. 38PCh. 9 - 9.40 Give IUPAC name for each...Ch. 9 - Prob. 40PCh. 9 - Prob. 41PCh. 9 - 9.46 What alkenes are formed when each alcohol is...Ch. 9 - Prob. 46PCh. 9 - Prob. 51PCh. 9 - 9.57 Draw a stepwise, detailed mechanism for the...Ch. 9 - Prob. 53PCh. 9 - 9.59 Draw two different routes to each of the...Ch. 9 - Prob. 55PCh. 9 -
9.61 Draw the products formed when each ether is...Ch. 9 - 9.62 Draw a stepwise mechanism for each...Ch. 9 - Draw a stepwise, detailed mechanism for the...Ch. 9 - Prob. 59PCh. 9 - Draw the products of each reaction. a.c. b.d.Ch. 9 - Prob. 64PCh. 9 - Prob. 75P
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