Elements Of Physical Chemistry
Elements Of Physical Chemistry
7th Edition
ISBN: 9780198796701
Author: ATKINS, P. W. (peter William), De Paula, Julio
Publisher: Oxford University Press
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Chapter 9, Problem 9C.1ST
Interpretation Introduction

Interpretation:

The Pauling electronegativity of HBr molecule has to be calculated.

Concept introduction;

Pauling electronegativity is essentially based on the idea that an atom's electronegativity can be defined by the degree to which it polarizes bonds.

  Δ=|χAχB|α|BDEABDAA.DBB

Pauling's theorem states that the difference between the experimental bond dissociation enthalpy (BDE) of two atoms and the geometric mean of the BDE of each of those atoms' covalent homonuclear bonds is proportional to the two atoms' difference in electronegativity:

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