CHEMICAL PRINCIPLES PKG W/SAPLING
7th Edition
ISBN: 9781319086411
Author: ATKINS
Publisher: MAC HIGHER
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Chapter 9, Problem 9C.17E
Interpretation Introduction
Interpretation:
The chirality of the complex (a) and (b) has to be given and if they are chiral, the formation of enantiomers has to be identified.
Concept Introduction:
Chirality:
A molecule or ion is called chiral only when there is non-superimpossable mirror image and there is no plane of symmetry in the molecule. This property is known as chirality.
Enantiomers:
The compounds, which are mirror images but are not identical; to each other are called as enantiomers.
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H3C
H
C=C
CH3
H
m-chloroperoxybenzoic acid
CH2Cl2, rt
C-C--.
H3CH2CC
H
H3C CH3
Cl₂
H₂O
NaOH
H₂O
D.
S-
E.
CH3
H₂O₂, H₂O
It
CH₂O Na
+
CHI
F.
HI, H₂O
heat
G.
4
OH
CH3CHCH3 + ICH2CH3
1. NaH
(CH3)3COH
(CH3)3 COCHCH2CH3
2.
CH3
5. Show how the ether below could be prepared from toluene and any other necessary reagents. Show all
reagents and all intermediate structures.
H3C-
H3C-
CI
OCH2CH3
Given the major organic product(s) of each of the following reactions. If none is predicted, write "N.R."
[answer 61
a.
b.
H3C
C.
NO₂
CH3CH2CH2Cl
AICI 3
1) NaOH
CI
2) H3O+
NO₂
1. SnCl2, H3O+
2. NaOH
3
Chapter 9 Solutions
CHEMICAL PRINCIPLES PKG W/SAPLING
Ch. 9 - Prob. 9A.1ASTCh. 9 - Prob. 9A.1BSTCh. 9 - Prob. 9A.1ECh. 9 - Prob. 9A.2ECh. 9 - Prob. 9A.3ECh. 9 - Prob. 9A.4ECh. 9 - Prob. 9A.5ECh. 9 - Prob. 9A.6ECh. 9 - Prob. 9A.7ECh. 9 - Prob. 9A.8E
Ch. 9 - Prob. 9A.9ECh. 9 - Prob. 9A.10ECh. 9 - Prob. 9A.11ECh. 9 - Prob. 9A.12ECh. 9 - Prob. 9A.13ECh. 9 - Prob. 9A.14ECh. 9 - Prob. 9B.1ASTCh. 9 - Prob. 9B.1BSTCh. 9 - Prob. 9B.2ASTCh. 9 - Prob. 9B.2BSTCh. 9 - Prob. 9B.1ECh. 9 - Prob. 9B.2ECh. 9 - Prob. 9B.3ECh. 9 - Prob. 9B.4ECh. 9 - Prob. 9B.5ECh. 9 - Prob. 9B.6ECh. 9 - Prob. 9B.7ECh. 9 - Prob. 9B.8ECh. 9 - Prob. 9B.9ECh. 9 - Prob. 9B.10ECh. 9 - Prob. 9B.11ECh. 9 - Prob. 9B.12ECh. 9 - Prob. 9B.13ECh. 9 - Prob. 9B.14ECh. 9 - Prob. 9B.15ECh. 9 - Prob. 9B.16ECh. 9 - Prob. 9C.1ASTCh. 9 - Prob. 9C.1BSTCh. 9 - Prob. 9C.2ASTCh. 9 - Prob. 9C.2BSTCh. 9 - Prob. 9C.3ASTCh. 9 - Prob. 9C.3BSTCh. 9 - Prob. 9C.4ASTCh. 9 - Prob. 9C.4BSTCh. 9 - Prob. 9C.1ECh. 9 - Prob. 9C.2ECh. 9 - Prob. 9C.3ECh. 9 - Prob. 9C.4ECh. 9 - Prob. 9C.5ECh. 9 - Prob. 9C.6ECh. 9 - Prob. 9C.7ECh. 9 - Prob. 9C.8ECh. 9 - Prob. 9C.9ECh. 9 - Prob. 9C.10ECh. 9 - Prob. 9C.11ECh. 9 - Prob. 9C.12ECh. 9 - Prob. 9C.13ECh. 9 - Prob. 9C.14ECh. 9 - Prob. 9C.15ECh. 9 - Prob. 9C.16ECh. 9 - Prob. 9C.17ECh. 9 - Prob. 9C.18ECh. 9 - Prob. 9C.19ECh. 9 - Prob. 9C.20ECh. 9 - Prob. 9D.1ASTCh. 9 - Prob. 9D.1BSTCh. 9 - Prob. 9D.2ASTCh. 9 - Prob. 9D.2BSTCh. 9 - Prob. 9D.3ASTCh. 9 - Prob. 9D.3BSTCh. 9 - Prob. 9D.4ASTCh. 9 - Prob. 9D.4BSTCh. 9 - Prob. 9D.1ECh. 9 - Prob. 9D.2ECh. 9 - Prob. 9D.3ECh. 9 - Prob. 9D.4ECh. 9 - Prob. 9D.5ECh. 9 - Prob. 9D.6ECh. 9 - Prob. 9D.7ECh. 9 - Prob. 9D.8ECh. 9 - Prob. 9D.9ECh. 9 - Prob. 9D.10ECh. 9 - Prob. 9D.11ECh. 9 - Prob. 9D.12ECh. 9 - Prob. 9D.13ECh. 9 - Prob. 9D.14ECh. 9 - Prob. 9D.15ECh. 9 - Prob. 9D.16ECh. 9 - Prob. 9D.17ECh. 9 - Prob. 9D.18ECh. 9 - Prob. 9D.19ECh. 9 - Prob. 9D.20ECh. 9 - Prob. 9D.21ECh. 9 - Prob. 9D.22ECh. 9 - Prob. 9D.23ECh. 9 - Prob. 9D.24ECh. 9 - Prob. 9D.25ECh. 9 - Prob. 9D.26ECh. 9 - Prob. 9D.27ECh. 9 - Prob. 9D.28ECh. 9 - Prob. 9D.29ECh. 9 - Prob. 9D.30ECh. 9 - Prob. 9D.31ECh. 9 - Prob. 9D.32ECh. 9 - Prob. 9D.33ECh. 9 - Prob. 9D.34ECh. 9 - Prob. 9.1ECh. 9 - Prob. 9.2ECh. 9 - Prob. 9.3ECh. 9 - Prob. 9.4ECh. 9 - Prob. 9.5ECh. 9 - Prob. 9.6ECh. 9 - Prob. 9.7ECh. 9 - Prob. 9.8ECh. 9 - Prob. 9.9ECh. 9 - Prob. 9.10ECh. 9 - Prob. 9.11ECh. 9 - Prob. 9.12ECh. 9 - Prob. 9.13ECh. 9 - Prob. 9.14ECh. 9 - Prob. 9.15ECh. 9 - Prob. 9.16ECh. 9 - Prob. 9.17ECh. 9 - Prob. 9.18ECh. 9 - Prob. 9.19ECh. 9 - Prob. 9.20ECh. 9 - Prob. 9.21ECh. 9 - Prob. 9.23ECh. 9 - Prob. 9.25E
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