Values of measured bond energies may vary greatly depending on the molecule studied. Consider the following reactions: N C l 3 ( g ) → N C l 2 ( g ) + C l ( g ) Δ E = 375 k J / m o l O N C l ( g ) → N O ( g ) + C l ( g ) Δ E = 158 k J / m o l Rationalize the difference in the values of ∆ E for these reactions, even though each reaction appears to involve only the breaking of one N—Cl bond. (Hint: Consider the bond order of the NO bond in ONCl and in NO.)
Values of measured bond energies may vary greatly depending on the molecule studied. Consider the following reactions: N C l 3 ( g ) → N C l 2 ( g ) + C l ( g ) Δ E = 375 k J / m o l O N C l ( g ) → N O ( g ) + C l ( g ) Δ E = 158 k J / m o l Rationalize the difference in the values of ∆ E for these reactions, even though each reaction appears to involve only the breaking of one N—Cl bond. (Hint: Consider the bond order of the NO bond in ONCl and in NO.)
Solution Summary: The author explains the difference in the values of Delta E for the given reactions.
Values of measured bond energies may vary greatly depending on the molecule studied. Consider the following reactions:
N
C
l
3
(
g
)
→
N
C
l
2
(
g
)
+
C
l
(
g
)
Δ
E
=
375
k
J
/
m
o
l
O
N
C
l
(
g
)
→
N
O
(
g
)
+
C
l
(
g
)
Δ
E
=
158
k
J
/
m
o
l
Rationalize the difference in the values of ∆E for these reactions, even though each reaction appears to involve only the breaking of one N—Cl bond. (Hint: Consider the bond order of the NO bond in ONCl and in NO.)
1. Calculate the accurate monoisotopic mass (using all 1H, 12C, 14N, 160 and 35CI) for your product using the table in
your lab manual. Don't include the Cl, since you should only have [M+H]*. Compare this to the value you see on
the LC-MS printout. How much different are they?
2. There are four isotopic peaks for the [M+H]* ion at m/z 240, 241, 242 and 243. For one point of extra credit,
explain what each of these is and why they are present.
3. There is a fragment ion at m/z 184. For one point of extra credit, identify this fragment and confirm by
calculating the accurate monoisotopic mass.
4. The UV spectrum is also at the bottom of your printout. For one point of extra credit, look up the UV spectrum
of bupropion on Google Images and compare to your spectrum. Do they match? Cite your source.
5. For most of you, there will be a second chromatographic peak whose m/z is 74 (to a round number). For one
point of extra credit, see if you can identify this molecule as well and confirm by…
Please draw, not just describe!
can you draw each step on a piece of a paper please this is very confusing to me
Chapter 9 Solutions
Student Solutions Manual for Zumdahl/Zumdahl/DeCoste?s Chemistry, 10th Edition
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Calorimetry Concept, Examples and Thermochemistry | How to Pass Chemistry; Author: Melissa Maribel;https://www.youtube.com/watch?v=nSh29lUGj00;License: Standard YouTube License, CC-BY
General Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStax
Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
Introductory Chemistry: A FoundationChemistryISBN:9781337399425Author:Steven S. Zumdahl, Donald J. DeCostePublisher:Cengage Learning