
EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
3rd Edition
ISBN: 9781259298424
Author: SMITH
Publisher: VST
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Chapter 9, Problem 9.95P
Interpretation Introduction
Interpretation:
The balanced chemical equation of reaction between
Concept Introduction:
An acid is a substance that gives
Here BA stands for salt and the reaction named as neutralization reaction. Thus, the reaction of an acid with a base result in the formation of salt and water. The salt is an ionic compound that is formed by the combination of the cation (
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Draw the stepwise mechanism for the reactions
Part I.
a)
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone
b) Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
(3,3-dimethyl-2-butanone) and 2, 3-dimethyl - 1,3-butadiene. Give reasonable mechanism
the formation of
the products
For
3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below:
Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life).
2
CH3
H
NO2
NO2
3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s)
H
a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.
Chapter 9 Solutions
EBK GENERAL, ORGANIC, & BIOLOGICAL CHEM
Ch. 9.1 - Name each acid: (a)HF;(b)HNO3;(c)HCN.Ch. 9.1 - If the polyatomic anion C1O2- is called chlorite,...Ch. 9.1 - Which of the following species can be...Ch. 9.1 - Which of the following species can be...Ch. 9.1 - Classify each reactant as a Brønsted-Lowry acid or...Ch. 9.2 - Determine the conjugate acid of each species:...Ch. 9.2 - Determine the conjugate base of each species:...Ch. 9.2 - Draw the structure of the conjugate base of each...Ch. 9.2 - Label the acid and the base and the conjugate acid...Ch. 9.2 - Ammonia, NH3, is amphoteric. Draw the conjugate...
Ch. 9.2 - Prob. 9.11PCh. 9.3 - Diagrams represent three acids (HA) dissolved in...Ch. 9.3 - Label the stronger acid in each pair. Which acid...Ch. 9.3 - Are the reactants or products favored at...Ch. 9.3 - If lactic acid is similar in strength to acetic...Ch. 9.4 - Rank the acids in each group in order of...Ch. 9.4 - Use the acid dissociation constants in Table 9.3...Ch. 9.4 - Consider the weak acids, HCN and H2CO3. Which acid...Ch. 9.5 - Calculate the value of [OH-] from the given [H3O+]...Ch. 9.5 - Calculate the value of [H3O+] from the given [OH-]...Ch. 9.5 - Calculate the value of [H3O+] and [H3O-] in each...Ch. 9.6 - Convert each H3O+ concentration to a pH value. a....Ch. 9.6 - What H3O+ concentration corresponds to each pH...Ch. 9.6 - Prob. 9.24PCh. 9.6 - Convert each H3O+ concentration to a pH value....Ch. 9.6 - Prob. 9.26PCh. 9.7 - Write a balanced equation for each acid-base...Ch. 9.7 - Prob. 9.28PCh. 9.7 - The acid in acid rain is generally sulfuric acid...Ch. 9.7 - Write a balanced equation for the reaction of...Ch. 9.8 - Determine whether each salt forms an acidic,...Ch. 9.8 - Which of the following salts forms an aqueous...Ch. 9.9 - What is the molarity of an HCI solution if 25.5 mL...Ch. 9.9 - How many milliliters of 2.0MNaOH are needed to...Ch. 9.10 - Determine whether a solution containing each of...Ch. 9.10 - Consider a buffer prepared from the weak acid HCO3...Ch. 9.10 - Calculate the pH of a dihydrogen...Ch. 9.10 - What is the pH of a buffer that contains...Ch. 9 - Which of the following species can be...Ch. 9 - Which of the following species can be...Ch. 9 - Prob. 9.41PCh. 9 - Which of the following species can be...Ch. 9 - Prob. 9.43PCh. 9 - Draw the conjugate acid of each base. a. Br- b....Ch. 9 - Draw the conjugate base of each acid. HNO2 NH4+...Ch. 9 - Draw the conjugate base of each acid. H3O+ H2Se...Ch. 9 - Prob. 9.47PCh. 9 - Prob. 9.48PCh. 9 - Prob. 9.49PCh. 9 - Prob. 9.50PCh. 9 - Label the conjugate acid-base pairs in each...Ch. 9 - Label the conjugate acid-base pairs in each...Ch. 9 - Prob. 9.53PCh. 9 - Prob. 9.54PCh. 9 - Fill in the missing product in each acid-base...Ch. 9 - Fill in the missing product in each acid-base...Ch. 9 - Prob. 9.57PCh. 9 - Write the equation for the acid-base reaction that...Ch. 9 - Prob. 9.59PCh. 9 - Which diagram represents what happens when HCN...Ch. 9 - Prob. 9.61PCh. 9 - Prob. 9.62PCh. 9 - Prob. 9.63PCh. 9 - Use the data in and 9.2 and 9.3 to label the...Ch. 9 - Prob. 9.65PCh. 9 - Which acid, A or B, is stronger in each part? a. B...Ch. 9 - Fill in the missing terms (strong or weak) and...Ch. 9 - Fill in the missing terms (strong or weak) and...Ch. 9 - For each pair of acids: [1] Label the stronger...Ch. 9 - For each pair of acids: [1] Label the stronger...Ch. 9 - Prob. 9.71PCh. 9 - Prob. 9.72PCh. 9 - Prob. 9.73PCh. 9 - Label the acid in the reactants and the conjugate...Ch. 9 - Calculate the value of [OH-] from the given and...Ch. 9 - Calculate the value of [OH-] from the given [H3O+]...Ch. 9 - Calculate the value of [OH-] from the given [HO-]...Ch. 9 - Calculate the value of [H3O+] from the given [OH-]...Ch. 9 - Prob. 9.79PCh. 9 - Prob. 9.80PCh. 9 - Prob. 9.81PCh. 9 - Complete the following table with the needed...Ch. 9 - Prob. 9.83PCh. 9 - Prob. 9.84PCh. 9 - Prob. 9.85PCh. 9 - If pancreaticfluids have a pH of 8.2, calculate...Ch. 9 - Calculate the concentrations of H3O+ and OH in the...Ch. 9 - Prob. 9.88PCh. 9 - Prob. 9.89PCh. 9 - Prob. 9.90PCh. 9 - Prob. 9.91PCh. 9 - Prob. 9.92PCh. 9 - Write a balanced equation for each reaction. a....Ch. 9 - Prob. 9.94PCh. 9 - Prob. 9.95PCh. 9 - Prob. 9.96PCh. 9 - Prob. 9.97PCh. 9 - Prob. 9.98PCh. 9 - Prob. 9.99PCh. 9 - Prob. 9.100PCh. 9 - Whatisthe molarityofanaceticacid (CH3COOH)...Ch. 9 - What is the molarity of an H2SO4 solution if 18.5...Ch. 9 - How many milliliters of 1.0MNaOH solution are...Ch. 9 - How many milliliters of 2.0MNaOH solution are...Ch. 9 - Prob. 9.105PCh. 9 - Prob. 9.106PCh. 9 - Prob. 9.107PCh. 9 - Prob. 9.108PCh. 9 - Prob. 9.109PCh. 9 - Prob. 9.110PCh. 9 - Using the Ka values in Table9.6, calculate the pH...Ch. 9 - Using the Ka values in Table9.6, calculate the pH...Ch. 9 - Calculate the pH of an acetic acid/acetate buffer...Ch. 9 - Calculate the pH of a bicarbonate/carbonate buffer...Ch. 9 - Why is the pH of unpolluted rainwater lower than...Ch. 9 - Prob. 9.116PCh. 9 - Prob. 9.117PCh. 9 - A sample of rainwater has a pH of 4.18. Calculate...Ch. 9 - Prob. 9.119PCh. 9 - Prob. 9.120PCh. 9 - Prob. 9.121PCh. 9 - Prob. 9.122PCh. 9 - Prob. 9.123CPCh. 9 - Prob. 9.124CP
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- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone and (3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism the formation of the products Forarrow_forwardShow the mechanism for these reactionsarrow_forwardDraw the stepwise mechanismarrow_forward
- Draw a structural formula of the principal product formed when benzonitrile is treated with each reagent. (a) H₂O (one equivalent), H₂SO₄, heat (b) H₂O (excess), H₂SO₄, heat (c) NaOH, H₂O, heat (d) LiAlH4, then H₂Oarrow_forwardDraw the stepwise mechanism for the reactionsarrow_forwardDraw stepwise mechanismarrow_forward
- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: a) Give the major reason for the exposure of benzophenone al isopropyl alcohol (w/acid) to direct sunlight of pina colone Mechanism For b) Pinacol (2,3-dimethy 1, 1-3-butanediol) on treatment w/ acid gives a mixture (3,3-dimethyl-2-butanone) and 2, 3-dimethyl-1,3-butadiene. Give reasonable the formation of the productsarrow_forwardwhat are the Iupac names for each structurearrow_forwardWhat are the IUPAC Names of all the compounds in the picture?arrow_forward
- 1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)arrow_forward19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+arrow_forwardLi+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiClarrow_forward
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