(a) Interpretation: The stereochemistry of compound B is to be predicted with information about the stereochemistry of bromine addition. Concept introduction: The addition of one or more than one halogen atom in alkene is known as halogenation reaction. The pathway of the halogenation reaction depends on the structure of the substrate. In this the halogen is added to C=C bond of the alkene to form haloalkane.

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Answer 1

Question

Chapter 9, Problem 9.86AP

Interpretation Introduction

(a)

Interpretation:

The stereochemistry of compound B is to be predicted with information about the stereochemistry of bromine addition.

Concept introduction:

The addition of one or more than one halogen atom in alkene is known as halogenation reaction. The pathway of the halogenation reaction depends on the structure of the substrate. In this the halogen is added to C=C bond of the alkene to form haloalkane.

Interpretation Introduction

(b)

Interpretation:

Whether B→C reaction is a syn- or an anti-elimination is to be stated.

Concept introduction:

Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(c)

Interpretation:

The change in the stereochemistry of products that would occur if E stereoisomer of compound A were carried through the corresponding sequence of reactions is to be stated. The explanation for the corresponding answer is to be stated.

Concept introduction:

The addition of one or more than one halogen atom in alkene is known as halogenation reaction. The pathway of the halogenation reaction depends on the structure of the substrate. In this the halogen is added to C=C bond of the alkene to form haloalkane.

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4. Provide a clear arrow-pushing mechanism for each of the following reactions. Do not skip proton transfers, do not combine steps, and make sure your arrows are clear enough to be interpreted without ambiguity. a. 2. 1. LDA 3. H3O+ HO

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Answer 2

Question

Chapter 9, Problem 9.86AP

Interpretation Introduction

(a)

Interpretation:

The stereochemistry of compound B is to be predicted with information about the stereochemistry of bromine addition.

Concept introduction:

The addition of one or more than one halogen atom in alkene is known as halogenation reaction. The pathway of the halogenation reaction depends on the structure of the substrate. In this the halogen is added to C=C bond of the alkene to form haloalkane.

Interpretation Introduction

(b)

Interpretation:

Whether B→C reaction is a syn- or an anti-elimination is to be stated.

Concept introduction:

Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(c)

Interpretation:

The change in the stereochemistry of products that would occur if E stereoisomer of compound A were carried through the corresponding sequence of reactions is to be stated. The explanation for the corresponding answer is to be stated.

Concept introduction:

The addition of one or more than one halogen atom in alkene is known as halogenation reaction. The pathway of the halogenation reaction depends on the structure of the substrate. In this the halogen is added to C=C bond of the alkene to form haloalkane.

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Answer 3

Question

Chapter 9, Problem 9.86AP

Interpretation Introduction

(a)

Interpretation:

The stereochemistry of compound B is to be predicted with information about the stereochemistry of bromine addition.

Concept introduction:

The addition of one or more than one halogen atom in alkene is known as halogenation reaction. The pathway of the halogenation reaction depends on the structure of the substrate. In this the halogen is added to C=C bond of the alkene to form haloalkane.

Interpretation Introduction

(b)

Interpretation:

Whether B→C reaction is a syn- or an anti-elimination is to be stated.

Concept introduction:

Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(c)

Interpretation:

The change in the stereochemistry of products that would occur if E stereoisomer of compound A were carried through the corresponding sequence of reactions is to be stated. The explanation for the corresponding answer is to be stated.

Concept introduction:

The addition of one or more than one halogen atom in alkene is known as halogenation reaction. The pathway of the halogenation reaction depends on the structure of the substrate. In this the halogen is added to C=C bond of the alkene to form haloalkane.

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Answer 4

Question

Chapter 9, Problem 9.86AP

Interpretation Introduction

(a)

Interpretation:

The stereochemistry of compound B is to be predicted with information about the stereochemistry of bromine addition.

Concept introduction:

The addition of one or more than one halogen atom in alkene is known as halogenation reaction. The pathway of the halogenation reaction depends on the structure of the substrate. In this the halogen is added to C=C bond of the alkene to form haloalkane.

Interpretation Introduction

(b)

Interpretation:

Whether B→C reaction is a syn- or an anti-elimination is to be stated.

Concept introduction:

Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(c)

Interpretation:

The change in the stereochemistry of products that would occur if E stereoisomer of compound A were carried through the corresponding sequence of reactions is to be stated. The explanation for the corresponding answer is to be stated.

Concept introduction:

The addition of one or more than one halogen atom in alkene is known as halogenation reaction. The pathway of the halogenation reaction depends on the structure of the substrate. In this the halogen is added to C=C bond of the alkene to form haloalkane.

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Answer 5

Chapter 9, Problem 9.86AP

Interpretation Introduction

(a)

Interpretation:

The stereochemistry of compound B is to be predicted with information about the stereochemistry of bromine addition.

Concept introduction:

The addition of one or more than one halogen atom in alkene is known as halogenation reaction. The pathway of the halogenation reaction depends on the structure of the substrate. In this the halogen is added to C=C bond of the alkene to form haloalkane.

Interpretation Introduction

(b)

Interpretation:

Whether B→C reaction is a syn- or an anti-elimination is to be stated.

Concept introduction:

Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Interpretation Introduction

(c)

Interpretation:

The change in the stereochemistry of products that would occur if E stereoisomer of compound A were carried through the corresponding sequence of reactions is to be stated. The explanation for the corresponding answer is to be stated.

Concept introduction:

The addition of one or more than one halogen atom in alkene is known as halogenation reaction. The pathway of the halogenation reaction depends on the structure of the substrate. In this the halogen is added to C=C bond of the alkene to form haloalkane.

Answer 6

Chapter 9, Problem 9.86AP

Interpretation Introduction

(a)

Interpretation:

The stereochemistry of compound B is to be predicted with information about the stereochemistry of bromine addition.

Concept introduction:

The addition of one or more than one halogen atom in alkene is known as halogenation reaction. The pathway of the halogenation reaction depends on the structure of the substrate. In this the halogen is added to C=C bond of the alkene to form haloalkane.

Answer 7

Chapter 9, Problem 9.86AP

Interpretation Introduction

(a)

Interpretation:

The stereochemistry of compound B is to be predicted with information about the stereochemistry of bromine addition.

Concept introduction:

The addition of one or more than one halogen atom in alkene is known as halogenation reaction. The pathway of the halogenation reaction depends on the structure of the substrate. In this the halogen is added to C=C bond of the alkene to form haloalkane.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Whether B→C reaction is a syn- or an anti-elimination is to be stated.

Concept introduction:

Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Whether B→C reaction is a syn- or an anti-elimination is to be stated.

Concept introduction:

Alkyl halides undergo elimination reaction in the presence of a base to form alkenes. The mechanism of the reaction followed depends on the base used. The most substituted alkene is formed as the major product according to Zaitsev rule.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The change in the stereochemistry of products that would occur if E stereoisomer of compound A were carried through the corresponding sequence of reactions is to be stated. The explanation for the corresponding answer is to be stated.

Concept introduction:

The addition of one or more than one halogen atom in alkene is known as halogenation reaction. The pathway of the halogenation reaction depends on the structure of the substrate. In this the halogen is added to C=C bond of the alkene to form haloalkane.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The change in the stereochemistry of products that would occur if E stereoisomer of compound A were carried through the corresponding sequence of reactions is to be stated. The explanation for the corresponding answer is to be stated.

Concept introduction:

The addition of one or more than one halogen atom in alkene is known as halogenation reaction. The pathway of the halogenation reaction depends on the structure of the substrate. In this the halogen is added to C=C bond of the alkene to form haloalkane.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 9 - Prob. 9.1P Ch. 9 - Prob. 9.2P Ch. 9 - Prob. 9.3P Ch. 9 - Prob. 9.4P Ch. 9 - Prob. 9.5P Ch. 9 - Prob. 9.6P Ch. 9 - Prob. 9.7P Ch. 9 - Prob. 9.8P Ch. 9 - Prob. 9.9P Ch. 9 - Prob. 9.10P

Solution Summary: The author explains that the stereochemistry of compound B is to be predicted with information about bromine addition.

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