![ALEKS 360 for Silberberg Chemistry: The Molecular Nature of Matter and Change](https://www.bartleby.com/isbn_cover_images/9781260477313/9781260477313_largeCoverImage.gif)
Interpretation:
The relative hardnesses and melting points of rubidium, vanadium, and cadmium with the use of condensed electron configurations are to be predicted.
Concept introduction:
The electronic configuration tells about the distribution of electrons in various atomic orbitals. The condensed electronic configuration is a way to write the electronic configuration where the inner shell configurations are compressed to the nearest noble gas configuration and only the valence shell configuration is written in the expanded form.
Metallic bonds are formed between metals. A metallic bond is formed between positively charged ions in a sea of delocalized electrons. The electrons in metals are delocalized over the entire metal.
The metallic character is characterized by the tendency of metals to lose their outermost valence shell electrons. Greater the ease of electron removal, higher will be the electropositivity of the corresponding elements and vice versa.
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Chapter 9 Solutions
ALEKS 360 for Silberberg Chemistry: The Molecular Nature of Matter and Change
- Nonearrow_forwardIn the solid state, oxalic acid occurs as a dihydrate with the formula H2C2O4 C+2H2O. Use this formula to calculate the formula weight of oxalic acid. Use the calculated formula weight and the number of moles (0.00504mol) of oxalic acid in each titrated unknown sample recorded in Table 6.4 to calculate the number of grams of pure oxalic acid dihydrate contained in each titrated unknown sample.arrow_forward1. Consider a pair of elements with 2p and 4p valence orbitals (e.g., N and Se). Draw their (2p and 4p AO's) radial probability plots, and sketch their angular profiles. Then, consider these orbitals from the two atoms forming a homonuclear л-bond. Which element would have a stronger bond, and why? (4 points)arrow_forward
- Write the reaction and show the mechanism of the reaction. Include the mechanism for formation of the NO2+ 2. Explain, using resonance structures, why the meta isomer is formed. Draw possible resonance structures for ortho, meta and para.arrow_forwardNonearrow_forward3. A molecular form of "dicarbon", C2, can be generated in gas phase. Its bond dissociation energy has been determined at 599 kJ/mol. Use molecular orbital theory to explain why energy of dissociation for C₂+ is 513 kJ/mol, and that for C2² is 818 kJ/mol. (10 points)arrow_forward
- 9.73 g of lead(IV) chloride contains enough Cl- ions to make ____ g of magnesium chloride.arrow_forward6. a) C2's. Phosphorus pentafluoride PF5 belongs to D3h symmetry group. Draw the structure of the molecule, identify principal axis of rotation and perpendicular (4 points) b) assume that the principal axis of rotation is aligned with z axis, assign symmetry labels (such as a1, b2, etc.) to the following atomic orbitals of the P atom. (character table for this group is included in the Supplemental material). 3s 3pz (6 points) 3dz²arrow_forward2. Construct Lewis-dot structures, and draw VESPR models for the ions listed below. a) SiF5 (4 points) b) IOF4 (4 points)arrow_forward
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