(a) Interpretation: For each given reaction, the structure of each product is to be drawn. Concept introduction: If the reactant molecule has two different functional groups attached to different places on the same molecule, then intramolecular reaction is possible. Whenever an intramolecular reaction can take place, an intermolecular reaction is also possible. When a five or six-membered ring can be formed, the intramolecular cyclization reactions are favored over their corresponding intermolecular reactions.

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Answer 1

Question

Chapter 9, Problem 9.70P

Interpretation Introduction

(a)

Interpretation:

For each given reaction, the structure of each product is to be drawn.

Concept introduction:

If the reactant molecule has two different functional groups attached to different places on the same molecule, then intramolecular reaction is possible. Whenever an intramolecular reaction can take place, an intermolecular reaction is also possible. When a five or six-membered ring can be formed, the intramolecular cyclization reactions are favored over their corresponding intermolecular reactions.

Interpretation Introduction

(b)

Interpretation:

For the given reaction, the mechanism that accounts for the formation of each of those products is to be drawn.

Concept introduction:

If the reactant molecule has two different functional groups attached to different places on the same molecule, then the intramolecular reaction is possible. Whenever an intramolecular reaction can take place, an intermolecular reaction is also possible. When a five or six-membered ring can be formed, the intramolecular cyclization reactions are favored over their corresponding intermolecular reactions.

Interpretation Introduction

(c)

Interpretation:

How the isomeric reactants lead to different products is to be explained.

Concept introduction:

If the reactant molecule has two different functional groups attached to different places on the same molecule, then the intramolecular reaction is possible. Whenever an intramolecular reaction can take place, an intermolecular reaction is also possible. When a five or six-membered ring can be formed, the intramolecular cyclization reactions are favored over their corresponding intermolecular reactions.

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8. (16 pts) Provide the stepwise mechanism for the synthesis of the following compound via an enamine

Draw the titration curve of (i) weak acid vs. strong base; (ii) weak acid vs. weakbase; (iii) diprotic acid with strong base (iii) triprotic acid with strong base.

Complete the reaction in the drawing area below by adding the major products to the right-hand side. If there won't be any products, because nothing will happen under these reaction conditions, check the box under the drawing area instead. Note: if the products contain one or more pairs of enantiomers, don't worry about drawing each enantiomer with dash and wedge bonds. Just draw one molecule to represent each pair of enantiomers, using line bonds at the chiral center. More... No reaction. my ㄖˋ + 1. Na O Me Click and drag to start drawing a structure. 2. H +

Answer 2

Question

Chapter 9, Problem 9.70P

Interpretation Introduction

(a)

Interpretation:

For each given reaction, the structure of each product is to be drawn.

Concept introduction:

If the reactant molecule has two different functional groups attached to different places on the same molecule, then intramolecular reaction is possible. Whenever an intramolecular reaction can take place, an intermolecular reaction is also possible. When a five or six-membered ring can be formed, the intramolecular cyclization reactions are favored over their corresponding intermolecular reactions.

Interpretation Introduction

(b)

Interpretation:

For the given reaction, the mechanism that accounts for the formation of each of those products is to be drawn.

Concept introduction:

If the reactant molecule has two different functional groups attached to different places on the same molecule, then the intramolecular reaction is possible. Whenever an intramolecular reaction can take place, an intermolecular reaction is also possible. When a five or six-membered ring can be formed, the intramolecular cyclization reactions are favored over their corresponding intermolecular reactions.

Interpretation Introduction

(c)

Interpretation:

How the isomeric reactants lead to different products is to be explained.

Concept introduction:

If the reactant molecule has two different functional groups attached to different places on the same molecule, then the intramolecular reaction is possible. Whenever an intramolecular reaction can take place, an intermolecular reaction is also possible. When a five or six-membered ring can be formed, the intramolecular cyclization reactions are favored over their corresponding intermolecular reactions.

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Answer 3

Question

Chapter 9, Problem 9.70P

Interpretation Introduction

(a)

Interpretation:

For each given reaction, the structure of each product is to be drawn.

Concept introduction:

If the reactant molecule has two different functional groups attached to different places on the same molecule, then intramolecular reaction is possible. Whenever an intramolecular reaction can take place, an intermolecular reaction is also possible. When a five or six-membered ring can be formed, the intramolecular cyclization reactions are favored over their corresponding intermolecular reactions.

Interpretation Introduction

(b)

Interpretation:

For the given reaction, the mechanism that accounts for the formation of each of those products is to be drawn.

Concept introduction:

If the reactant molecule has two different functional groups attached to different places on the same molecule, then the intramolecular reaction is possible. Whenever an intramolecular reaction can take place, an intermolecular reaction is also possible. When a five or six-membered ring can be formed, the intramolecular cyclization reactions are favored over their corresponding intermolecular reactions.

Interpretation Introduction

(c)

Interpretation:

How the isomeric reactants lead to different products is to be explained.

Concept introduction:

If the reactant molecule has two different functional groups attached to different places on the same molecule, then the intramolecular reaction is possible. Whenever an intramolecular reaction can take place, an intermolecular reaction is also possible. When a five or six-membered ring can be formed, the intramolecular cyclization reactions are favored over their corresponding intermolecular reactions.

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Answer 4

Question

Chapter 9, Problem 9.70P

Interpretation Introduction

(a)

Interpretation:

For each given reaction, the structure of each product is to be drawn.

Concept introduction:

If the reactant molecule has two different functional groups attached to different places on the same molecule, then intramolecular reaction is possible. Whenever an intramolecular reaction can take place, an intermolecular reaction is also possible. When a five or six-membered ring can be formed, the intramolecular cyclization reactions are favored over their corresponding intermolecular reactions.

Interpretation Introduction

(b)

Interpretation:

For the given reaction, the mechanism that accounts for the formation of each of those products is to be drawn.

Concept introduction:

If the reactant molecule has two different functional groups attached to different places on the same molecule, then the intramolecular reaction is possible. Whenever an intramolecular reaction can take place, an intermolecular reaction is also possible. When a five or six-membered ring can be formed, the intramolecular cyclization reactions are favored over their corresponding intermolecular reactions.

Interpretation Introduction

(c)

Interpretation:

How the isomeric reactants lead to different products is to be explained.

Concept introduction:

If the reactant molecule has two different functional groups attached to different places on the same molecule, then the intramolecular reaction is possible. Whenever an intramolecular reaction can take place, an intermolecular reaction is also possible. When a five or six-membered ring can be formed, the intramolecular cyclization reactions are favored over their corresponding intermolecular reactions.

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Answer 5

Chapter 9, Problem 9.70P

Interpretation Introduction

(a)

Interpretation:

For each given reaction, the structure of each product is to be drawn.

Concept introduction:

If the reactant molecule has two different functional groups attached to different places on the same molecule, then intramolecular reaction is possible. Whenever an intramolecular reaction can take place, an intermolecular reaction is also possible. When a five or six-membered ring can be formed, the intramolecular cyclization reactions are favored over their corresponding intermolecular reactions.

Interpretation Introduction

(b)

Interpretation:

For the given reaction, the mechanism that accounts for the formation of each of those products is to be drawn.

Concept introduction:

If the reactant molecule has two different functional groups attached to different places on the same molecule, then the intramolecular reaction is possible. Whenever an intramolecular reaction can take place, an intermolecular reaction is also possible. When a five or six-membered ring can be formed, the intramolecular cyclization reactions are favored over their corresponding intermolecular reactions.

Interpretation Introduction

(c)

Interpretation:

How the isomeric reactants lead to different products is to be explained.

Concept introduction:

If the reactant molecule has two different functional groups attached to different places on the same molecule, then the intramolecular reaction is possible. Whenever an intramolecular reaction can take place, an intermolecular reaction is also possible. When a five or six-membered ring can be formed, the intramolecular cyclization reactions are favored over their corresponding intermolecular reactions.

Answer 6

Chapter 9, Problem 9.70P

Interpretation Introduction

(a)

Interpretation:

For each given reaction, the structure of each product is to be drawn.

Concept introduction:

If the reactant molecule has two different functional groups attached to different places on the same molecule, then intramolecular reaction is possible. Whenever an intramolecular reaction can take place, an intermolecular reaction is also possible. When a five or six-membered ring can be formed, the intramolecular cyclization reactions are favored over their corresponding intermolecular reactions.

Answer 7

Chapter 9, Problem 9.70P

Interpretation Introduction

(a)

Interpretation:

For each given reaction, the structure of each product is to be drawn.

Concept introduction:

If the reactant molecule has two different functional groups attached to different places on the same molecule, then intramolecular reaction is possible. Whenever an intramolecular reaction can take place, an intermolecular reaction is also possible. When a five or six-membered ring can be formed, the intramolecular cyclization reactions are favored over their corresponding intermolecular reactions.

Answer 8

Interpretation Introduction

(b)

Interpretation:

For the given reaction, the mechanism that accounts for the formation of each of those products is to be drawn.

Concept introduction:

If the reactant molecule has two different functional groups attached to different places on the same molecule, then the intramolecular reaction is possible. Whenever an intramolecular reaction can take place, an intermolecular reaction is also possible. When a five or six-membered ring can be formed, the intramolecular cyclization reactions are favored over their corresponding intermolecular reactions.

Answer 9

Interpretation Introduction

(b)

Interpretation:

For the given reaction, the mechanism that accounts for the formation of each of those products is to be drawn.

Concept introduction:

If the reactant molecule has two different functional groups attached to different places on the same molecule, then the intramolecular reaction is possible. Whenever an intramolecular reaction can take place, an intermolecular reaction is also possible. When a five or six-membered ring can be formed, the intramolecular cyclization reactions are favored over their corresponding intermolecular reactions.

Answer 10

Interpretation Introduction

(c)

Interpretation:

How the isomeric reactants lead to different products is to be explained.

Concept introduction:

If the reactant molecule has two different functional groups attached to different places on the same molecule, then the intramolecular reaction is possible. Whenever an intramolecular reaction can take place, an intermolecular reaction is also possible. When a five or six-membered ring can be formed, the intramolecular cyclization reactions are favored over their corresponding intermolecular reactions.

Answer 11

Interpretation Introduction

(c)

Interpretation:

How the isomeric reactants lead to different products is to be explained.

Concept introduction:

If the reactant molecule has two different functional groups attached to different places on the same molecule, then the intramolecular reaction is possible. Whenever an intramolecular reaction can take place, an intermolecular reaction is also possible. When a five or six-membered ring can be formed, the intramolecular cyclization reactions are favored over their corresponding intermolecular reactions.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 9 - Prob. 9.1P Ch. 9 - Prob. 9.2P Ch. 9 - Prob. 9.3P Ch. 9 - Prob. 9.4P Ch. 9 - Prob. 9.5P Ch. 9 - Prob. 9.6P Ch. 9 - Prob. 9.7P Ch. 9 - Prob. 9.8P Ch. 9 - Prob. 9.9P Ch. 9 - Prob. 9.10P

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Chapter 9 Solutions