Chemistry: The Science in Context (Fifth Edition)
5th Edition
ISBN: 9780393614046
Author: Thomas R. Gilbert, Rein V. Kirss, Natalie Foster, Stacey Lowery Bretz, Geoffrey Davies
Publisher: W. W. Norton & Company
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Chapter 9, Problem 9.40QP
Interpretation Introduction
Interpretation: The complete Lewis structures of the given compound are to be determined.
Concept introduction: The Lewis structure represents all bonding and non-bonding electrons surrounding the atoms involved in a molecule. A molecule exhibits a particular geometry in space considering the steric hindrances of the bond pairs and the lone pairs of electron.
To determine: The complete Lewis structures of the given compound.
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Assign all integrated peaks
- Consider the data in the Table below to answer the following questions:
Acidities of Substituted Benzoic and Acetic Acids
pk,s at 25C
Y-CH COOH
Y
Y - CH₂COOH
meta
para
H
4.75
4.19
4.19
2.47
3.64
3.55
3.57
4.09
4.46
CN
OCH 3
A. Draw the structure of the strongest acid in the table above.
B. Explain why cyanoacetic acid and methoxyacetic acid are more acidic than their correspondingly
substituted benzoic acid counterparts.
Draw the curved arrow mechanism for this reaction starting with 2-propanol in sulfuric acid. Show all nonzero formal charges and all
nonbonded electrons in each step. Species not involved in a particular step do not need to be included in that step, and resonance forms
do not need to be shown. Note that the alcohol is in much higher concentration than H₂O in this reaction.
H
Chapter 9 Solutions
Chemistry: The Science in Context (Fifth Edition)
Ch. 9.2 - Prob. 1PECh. 9.2 - Prob. 2PECh. 9.2 - Prob. 3PECh. 9.3 - Prob. 4PECh. 9.4 - Prob. 5PECh. 9.4 - Prob. 6PECh. 9.4 - Prob. 7PECh. 9.5 - Prob. 8PECh. 9.5 - Prob. 9PECh. 9.7 - Prob. 10PE
Ch. 9.7 - Prob. 11PECh. 9.7 - Prob. 12PECh. 9.7 - Prob. 13PECh. 9 - Prob. 9.1VPCh. 9 - Prob. 9.2VPCh. 9 - Prob. 9.3VPCh. 9 - Prob. 9.4VPCh. 9 - Prob. 9.5VPCh. 9 - Prob. 9.6VPCh. 9 - Prob. 9.7VPCh. 9 - Prob. 9.8VPCh. 9 - Prob. 9.9QPCh. 9 - Prob. 9.10QPCh. 9 - Prob. 9.11QPCh. 9 - Prob. 9.12QPCh. 9 - Prob. 9.13QPCh. 9 - Prob. 9.14QPCh. 9 - Prob. 9.15QPCh. 9 - Prob. 9.16QPCh. 9 - Prob. 9.17QPCh. 9 - Prob. 9.18QPCh. 9 - Prob. 9.19QPCh. 9 - Prob. 9.20QPCh. 9 - Prob. 9.21QPCh. 9 - Prob. 9.22QPCh. 9 - Prob. 9.23QPCh. 9 - Prob. 9.24QPCh. 9 - Prob. 9.25QPCh. 9 - Prob. 9.26QPCh. 9 - Prob. 9.27QPCh. 9 - Prob. 9.28QPCh. 9 - Prob. 9.29QPCh. 9 - Prob. 9.30QPCh. 9 - Prob. 9.31QPCh. 9 - Prob. 9.32QPCh. 9 - Prob. 9.33QPCh. 9 - Prob. 9.34QPCh. 9 - Prob. 9.35QPCh. 9 - Prob. 9.36QPCh. 9 - Prob. 9.37QPCh. 9 - Prob. 9.38QPCh. 9 - Prob. 9.39QPCh. 9 - Prob. 9.40QPCh. 9 - Prob. 9.41QPCh. 9 - Prob. 9.42QPCh. 9 - Prob. 9.43QPCh. 9 - Prob. 9.44QPCh. 9 - Prob. 9.45QPCh. 9 - Prob. 9.46QPCh. 9 - Prob. 9.47QPCh. 9 - Prob. 9.48QPCh. 9 - Prob. 9.49QPCh. 9 - Prob. 9.50QPCh. 9 - Prob. 9.51QPCh. 9 - Prob. 9.52QPCh. 9 - Prob. 9.53QPCh. 9 - Prob. 9.54QPCh. 9 - Prob. 9.55QPCh. 9 - Prob. 9.56QPCh. 9 - Prob. 9.57QPCh. 9 - Prob. 9.58QPCh. 9 - Prob. 9.59QPCh. 9 - Prob. 9.60QPCh. 9 - Prob. 9.61QPCh. 9 - Prob. 9.62QPCh. 9 - Prob. 9.63QPCh. 9 - Prob. 9.64QPCh. 9 - Prob. 9.65QPCh. 9 - Prob. 9.66QPCh. 9 - Prob. 9.67QPCh. 9 - Prob. 9.68QPCh. 9 - Prob. 9.69QPCh. 9 - Prob. 9.70QPCh. 9 - Prob. 9.71QPCh. 9 - Prob. 9.72QPCh. 9 - Prob. 9.73QPCh. 9 - Prob. 9.74QPCh. 9 - Prob. 9.75QPCh. 9 - Prob. 9.76QPCh. 9 - Prob. 9.77QPCh. 9 - Prob. 9.78QPCh. 9 - Prob. 9.79QPCh. 9 - Prob. 9.80QPCh. 9 - Prob. 9.81QPCh. 9 - Prob. 9.82QPCh. 9 - Prob. 9.83QPCh. 9 - Prob. 9.84QPCh. 9 - Prob. 9.85QPCh. 9 - Prob. 9.86QPCh. 9 - Prob. 9.87QPCh. 9 - Prob. 9.88QPCh. 9 - Prob. 9.89QPCh. 9 - Prob. 9.90QPCh. 9 - Prob. 9.91QPCh. 9 - Prob. 9.92QPCh. 9 - Prob. 9.93QPCh. 9 - Prob. 9.94QPCh. 9 - Prob. 9.95QPCh. 9 - Prob. 9.96QPCh. 9 - Prob. 9.97QPCh. 9 - Prob. 9.98QPCh. 9 - Prob. 9.99QPCh. 9 - Prob. 9.100QPCh. 9 - Prob. 9.101QPCh. 9 - Prob. 9.102QPCh. 9 - Prob. 9.103QPCh. 9 - Prob. 9.104QPCh. 9 - Prob. 9.105QPCh. 9 - Prob. 9.106QPCh. 9 - Prob. 9.107QPCh. 9 - Prob. 9.108QPCh. 9 - Prob. 9.109QPCh. 9 - Prob. 9.110QPCh. 9 - Prob. 9.111QPCh. 9 - Prob. 9.112QPCh. 9 - Prob. 9.113QPCh. 9 - Prob. 9.114QPCh. 9 - Prob. 9.115APCh. 9 - Prob. 9.116APCh. 9 - Prob. 9.117APCh. 9 - Prob. 9.118APCh. 9 - Prob. 9.119APCh. 9 - Prob. 9.120APCh. 9 - Prob. 9.121APCh. 9 - Prob. 9.122APCh. 9 - Prob. 9.123APCh. 9 - Prob. 9.124APCh. 9 - Prob. 9.125APCh. 9 - Prob. 9.126APCh. 9 - Prob. 9.127APCh. 9 - Prob. 9.128APCh. 9 - Prob. 9.129APCh. 9 - Prob. 9.130APCh. 9 - Prob. 9.131APCh. 9 - Prob. 9.132APCh. 9 - Prob. 9.133APCh. 9 - Prob. 9.134APCh. 9 - Prob. 9.135APCh. 9 - Prob. 9.136APCh. 9 - Prob. 9.137APCh. 9 - Prob. 9.138APCh. 9 - Prob. 9.139APCh. 9 - Prob. 9.140APCh. 9 - Prob. 9.141APCh. 9 - Prob. 9.142APCh. 9 - Prob. 9.143AP
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