(a) Interpretation: The products that are expected in the ethoxide-promoted β -elimination reaction of 2-bromo-2, 3-dimethylbutane are to be stated. Concept introduction: The β -elimination reaction occurs when tertiary alkyl halide reacts with a Bronsted base and forms a double bond. The carbon bearing the halogen in alkyl halide is known as α -carbon and the adjacent carbons of α -carbon is β -carbon. The elimination occurs through the β -carbon therefore elimination is called β -elimination reaction.

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Answer 1

Question

Chapter 9, Problem 9.3P

Interpretation Introduction

(a)

Interpretation:

The products that are expected in the ethoxide-promoted β-elimination reaction of 2-bromo-2, 3-dimethylbutane are to be stated.

Concept introduction:

The β-elimination reaction occurs when tertiary alkyl halide reacts with a Bronsted base and forms a double bond. The carbon bearing the halogen in alkyl halide is known as α-carbon and the adjacent carbons of α-carbon is β-carbon. The elimination occurs through the β-carbon therefore elimination is called β-elimination reaction.

Interpretation Introduction

(b)

Interpretation:

The products that are expected in the ethoxide-promoted β-elimination reaction of 1-chloro-1-methylcyclohexane are to be stated.

Concept introduction:

The β-elimination reaction occurs when tertiary alkyl halide reacts with a Bronsted base and forms a double bond. The carbon bearing the halogen in alkyl halide is known as α-carbon and the adjacent carbons of α-carbon is β-carbon. The elimination occurs through the β-carbon therefore elimination is called β-elimination reaction.

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?

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Answer 2

Question

Chapter 9, Problem 9.3P

Interpretation Introduction

(a)

Interpretation:

The products that are expected in the ethoxide-promoted β-elimination reaction of 2-bromo-2, 3-dimethylbutane are to be stated.

Concept introduction:

The β-elimination reaction occurs when tertiary alkyl halide reacts with a Bronsted base and forms a double bond. The carbon bearing the halogen in alkyl halide is known as α-carbon and the adjacent carbons of α-carbon is β-carbon. The elimination occurs through the β-carbon therefore elimination is called β-elimination reaction.

Interpretation Introduction

(b)

Interpretation:

The products that are expected in the ethoxide-promoted β-elimination reaction of 1-chloro-1-methylcyclohexane are to be stated.

Concept introduction:

The β-elimination reaction occurs when tertiary alkyl halide reacts with a Bronsted base and forms a double bond. The carbon bearing the halogen in alkyl halide is known as α-carbon and the adjacent carbons of α-carbon is β-carbon. The elimination occurs through the β-carbon therefore elimination is called β-elimination reaction.

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Answer 3

Question

Chapter 9, Problem 9.3P

Interpretation Introduction

(a)

Interpretation:

The products that are expected in the ethoxide-promoted β-elimination reaction of 2-bromo-2, 3-dimethylbutane are to be stated.

Concept introduction:

The β-elimination reaction occurs when tertiary alkyl halide reacts with a Bronsted base and forms a double bond. The carbon bearing the halogen in alkyl halide is known as α-carbon and the adjacent carbons of α-carbon is β-carbon. The elimination occurs through the β-carbon therefore elimination is called β-elimination reaction.

Interpretation Introduction

(b)

Interpretation:

The products that are expected in the ethoxide-promoted β-elimination reaction of 1-chloro-1-methylcyclohexane are to be stated.

Concept introduction:

The β-elimination reaction occurs when tertiary alkyl halide reacts with a Bronsted base and forms a double bond. The carbon bearing the halogen in alkyl halide is known as α-carbon and the adjacent carbons of α-carbon is β-carbon. The elimination occurs through the β-carbon therefore elimination is called β-elimination reaction.

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Answer 4

Question

Chapter 9, Problem 9.3P

Interpretation Introduction

(a)

Interpretation:

The products that are expected in the ethoxide-promoted β-elimination reaction of 2-bromo-2, 3-dimethylbutane are to be stated.

Concept introduction:

The β-elimination reaction occurs when tertiary alkyl halide reacts with a Bronsted base and forms a double bond. The carbon bearing the halogen in alkyl halide is known as α-carbon and the adjacent carbons of α-carbon is β-carbon. The elimination occurs through the β-carbon therefore elimination is called β-elimination reaction.

Interpretation Introduction

(b)

Interpretation:

The products that are expected in the ethoxide-promoted β-elimination reaction of 1-chloro-1-methylcyclohexane are to be stated.

Concept introduction:

The β-elimination reaction occurs when tertiary alkyl halide reacts with a Bronsted base and forms a double bond. The carbon bearing the halogen in alkyl halide is known as α-carbon and the adjacent carbons of α-carbon is β-carbon. The elimination occurs through the β-carbon therefore elimination is called β-elimination reaction.

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Answer 5

Chapter 9, Problem 9.3P

Interpretation Introduction

(a)

Interpretation:

The products that are expected in the ethoxide-promoted β-elimination reaction of 2-bromo-2, 3-dimethylbutane are to be stated.

Concept introduction:

The β-elimination reaction occurs when tertiary alkyl halide reacts with a Bronsted base and forms a double bond. The carbon bearing the halogen in alkyl halide is known as α-carbon and the adjacent carbons of α-carbon is β-carbon. The elimination occurs through the β-carbon therefore elimination is called β-elimination reaction.

Interpretation Introduction

(b)

Interpretation:

The products that are expected in the ethoxide-promoted β-elimination reaction of 1-chloro-1-methylcyclohexane are to be stated.

Concept introduction:

The β-elimination reaction occurs when tertiary alkyl halide reacts with a Bronsted base and forms a double bond. The carbon bearing the halogen in alkyl halide is known as α-carbon and the adjacent carbons of α-carbon is β-carbon. The elimination occurs through the β-carbon therefore elimination is called β-elimination reaction.

Answer 6

Chapter 9, Problem 9.3P

Interpretation Introduction

(a)

Interpretation:

The products that are expected in the ethoxide-promoted β-elimination reaction of 2-bromo-2, 3-dimethylbutane are to be stated.

Concept introduction:

The β-elimination reaction occurs when tertiary alkyl halide reacts with a Bronsted base and forms a double bond. The carbon bearing the halogen in alkyl halide is known as α-carbon and the adjacent carbons of α-carbon is β-carbon. The elimination occurs through the β-carbon therefore elimination is called β-elimination reaction.

Answer 7

Chapter 9, Problem 9.3P

Interpretation Introduction

(a)

Interpretation:

The products that are expected in the ethoxide-promoted β-elimination reaction of 2-bromo-2, 3-dimethylbutane are to be stated.

Concept introduction:

The β-elimination reaction occurs when tertiary alkyl halide reacts with a Bronsted base and forms a double bond. The carbon bearing the halogen in alkyl halide is known as α-carbon and the adjacent carbons of α-carbon is β-carbon. The elimination occurs through the β-carbon therefore elimination is called β-elimination reaction.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The products that are expected in the ethoxide-promoted β-elimination reaction of 1-chloro-1-methylcyclohexane are to be stated.

Concept introduction:

The β-elimination reaction occurs when tertiary alkyl halide reacts with a Bronsted base and forms a double bond. The carbon bearing the halogen in alkyl halide is known as α-carbon and the adjacent carbons of α-carbon is β-carbon. The elimination occurs through the β-carbon therefore elimination is called β-elimination reaction.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The products that are expected in the ethoxide-promoted β-elimination reaction of 1-chloro-1-methylcyclohexane are to be stated.

Concept introduction:

The β-elimination reaction occurs when tertiary alkyl halide reacts with a Bronsted base and forms a double bond. The carbon bearing the halogen in alkyl halide is known as α-carbon and the adjacent carbons of α-carbon is β-carbon. The elimination occurs through the β-carbon therefore elimination is called β-elimination reaction.

Answer 10

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Answer 11

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Answer 13

Ch. 9 - Prob. 9.1P Ch. 9 - Prob. 9.2P Ch. 9 - Prob. 9.3P Ch. 9 - Prob. 9.4P Ch. 9 - Prob. 9.5P Ch. 9 - Prob. 9.6P Ch. 9 - Prob. 9.7P Ch. 9 - Prob. 9.8P Ch. 9 - Prob. 9.9P Ch. 9 - Prob. 9.10P

Solution Summary: The author describes the ethoxide-promoted -elimination reaction of 2-bromo-2, 3-dimethylbutane.

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