(a) Interpretation: The products of the reaction between 1 - bromobutane and sodium methoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated. Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

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Answer 1

Question

Chapter 9, Problem 9.30P

Interpretation Introduction

(a)

Interpretation:

The products of the reaction between 1- bromobutane and sodium methoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(b)

Interpretation:

The products of the reaction between 2- bromobutane and potassium tert-butoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(c)

Interpretation:

The products of the reaction between 2-bromo-1,1-dimethylcyclopentane and ethanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(d)

Interpretation:

The products of the reaction between bromocyclohexane and methanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?

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Answer 2

Question

Chapter 9, Problem 9.30P

Interpretation Introduction

(a)

Interpretation:

The products of the reaction between 1- bromobutane and sodium methoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(b)

Interpretation:

The products of the reaction between 2- bromobutane and potassium tert-butoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(c)

Interpretation:

The products of the reaction between 2-bromo-1,1-dimethylcyclopentane and ethanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(d)

Interpretation:

The products of the reaction between bromocyclohexane and methanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

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Answer 3

Question

Chapter 9, Problem 9.30P

Interpretation Introduction

(a)

Interpretation:

The products of the reaction between 1- bromobutane and sodium methoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(b)

Interpretation:

The products of the reaction between 2- bromobutane and potassium tert-butoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(c)

Interpretation:

The products of the reaction between 2-bromo-1,1-dimethylcyclopentane and ethanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(d)

Interpretation:

The products of the reaction between bromocyclohexane and methanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

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Answer 4

Question

Chapter 9, Problem 9.30P

Interpretation Introduction

(a)

Interpretation:

The products of the reaction between 1- bromobutane and sodium methoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(b)

Interpretation:

The products of the reaction between 2- bromobutane and potassium tert-butoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(c)

Interpretation:

The products of the reaction between 2-bromo-1,1-dimethylcyclopentane and ethanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(d)

Interpretation:

The products of the reaction between bromocyclohexane and methanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

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Answer 5

Chapter 9, Problem 9.30P

Interpretation Introduction

(a)

Interpretation:

The products of the reaction between 1- bromobutane and sodium methoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(b)

Interpretation:

The products of the reaction between 2- bromobutane and potassium tert-butoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(c)

Interpretation:

The products of the reaction between 2-bromo-1,1-dimethylcyclopentane and ethanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Interpretation Introduction

(d)

Interpretation:

The products of the reaction between bromocyclohexane and methanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Answer 6

Chapter 9, Problem 9.30P

Interpretation Introduction

(a)

Interpretation:

The products of the reaction between 1- bromobutane and sodium methoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Answer 7

Chapter 9, Problem 9.30P

Interpretation Introduction

(a)

Interpretation:

The products of the reaction between 1- bromobutane and sodium methoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The products of the reaction between 2- bromobutane and potassium tert-butoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The products of the reaction between 2- bromobutane and potassium tert-butoxide are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The products of the reaction between 2-bromo-1,1-dimethylcyclopentane and ethanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The products of the reaction between 2-bromo-1,1-dimethylcyclopentane and ethanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The products of the reaction between bromocyclohexane and methanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The products of the reaction between bromocyclohexane and methanol are to be predicted and the curved-arrow mechanism of the reaction is to be stated.

Concept introduction:

The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. In nucleophilic substitution reaction, nucleophile takes the position of leaving group by attacking on the electron deficient carbon atom.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 9 - Prob. 9.1P Ch. 9 - Prob. 9.2P Ch. 9 - Prob. 9.3P Ch. 9 - Prob. 9.4P Ch. 9 - Prob. 9.5P Ch. 9 - Prob. 9.6P Ch. 9 - Prob. 9.7P Ch. 9 - Prob. 9.8P Ch. 9 - Prob. 9.9P Ch. 9 - Prob. 9.10P

Solution Summary: The author explains that the products of the reaction between 1- bromobutane and sodium methoxide are to be predicted.

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