General, Organic, and Biological Chemistry - 4th edition
4th Edition
ISBN: 9781259883989
Author: by Janice Smith
Publisher: McGraw-Hill Education
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Chapter 9, Problem 90P
What is the molarity of an
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(11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
Bond A
Bond C
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
Weakest
Bond
Strongest
Bond
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
c. (5pts) Use principles discussed in lecture, supported by relevant structures, to
succinctly explain the why your part b (i) radical is more stable than your part b(ii)
radical. Written explanation can be no more than one-two succinct sentence(s)!
.
3°C
with
TH
12. (10pts total) Provide the major product for each reaction depicted below. If no reaction
occurs write NR. Assume heat dissipation is carefully controlled in the fluorine reaction.
3H
24 total (30)
24
21
2h
• 6H total
● 8H total
34
래
Br2
hv
major product
will be most
Substituted
12
hv
Br
NR
I too weak of a
participate in P-1
F₂
hv
Statistically
most favored
product will be
major
=
most subst =
thermo favored
hydrogen atom abstractor to
LL
F
Five chemistry project topic that does not involve practical
Chapter 9 Solutions
General, Organic, and Biological Chemistry - 4th edition
Ch. 9.1 - Name each acid: (a)HF;(b)HNO3;(c)HCN.Ch. 9.1 - If the polyatomic anion C1O2- is called chlorite,...Ch. 9.1 - Which of the following species can be...Ch. 9.1 - Which of the following species can be...Ch. 9.1 - Classify each reactant as a Brønsted-Lowry acid or...Ch. 9.2 - Determine the conjugate acid of each species:...Ch. 9.2 - Determine the conjugate base of each species:...Ch. 9.2 - Draw the structure of the conjugate base of each...Ch. 9.2 - Label the acid, the base, the conjugate acid, and...Ch. 9.2 - Identify the acid, the base, the conjugate acid,...
Ch. 9.2 - Ammonia, NH3, is amphoteric. (a) Draw the...Ch. 9.2 - Fill in the missing product in each acid-base...Ch. 9.3 - Diagrams A and B represent acids dissolved in...Ch. 9.3 - Diagrams represent three acids (HA) dissolved in...Ch. 9.3 - Label the stronger acid in each pair. Which acid...Ch. 9.3 - Are the reactants or products favored at...Ch. 9.3 - If lactic acid is similar in strength to acetic...Ch. 9.4 - Rank the acids in each group in order of...Ch. 9.4 - Use the acid dissociation constants in Table 9.3...Ch. 9.4 - Consider the weak acids, HCN and H2CO3. Which acid...Ch. 9.5 - Calculate the value of [OH-] from the given [H3O+]...Ch. 9.5 - Calculate the value of [H3O+] from the given [OH-]...Ch. 9.5 - Calculate the value of [H3O+] and [H3O-] in each...Ch. 9.6 - (a) What is the difference in [H3O+] for each pair...Ch. 9.6 - Convert each H3O+ concentration to a pH value. a....Ch. 9.6 - What H3O+ concentration corresponds to each pH...Ch. 9.6 - Convert each H3O+ concentration to a pH value....Ch. 9.6 - What H3O+ concentration corresponds to each pH...Ch. 9.6 - What is the H3O+ concentration in a sports drink...Ch. 9.7 - Write a balanced equation for each acid-base...Ch. 9.7 - Write the net ionic equation for each reaction in...Ch. 9.7 - The acid in acid rain is generally sulfuric acid...Ch. 9.7 - Write a balanced equation for the reaction of...Ch. 9.8 - Determine whether each salt forms an acidic,...Ch. 9.8 - Which of the following salts forms an aqueous...Ch. 9.9 - What is the molarity of an HCI solution if 25.5 mL...Ch. 9.9 - How many milliliters of 2.0MNaOH are needed to...Ch. 9.10 - Determine whether a solution containing each of...Ch. 9.10 - Consider a buffer prepared from the weak acid HCO3...Ch. 9.10 - Calculate the pH of a dihydrogen...Ch. 9.10 - What is the pH of a buffer that contains...Ch. 9 - Which of the following species can be...Ch. 9 - Which of the following species can be...Ch. 9 - Prob. 23PCh. 9 - Which of the following species can be...Ch. 9 - Prob. 25PCh. 9 - Draw the conjugate acid of each base. a. Br- b....Ch. 9 - Draw the conjugate base of each acid. HNO2 NH4+...Ch. 9 - Draw the conjugate base of each acid. H3O+ H2Se...Ch. 9 - Prob. 29PCh. 9 - Prob. 30PCh. 9 - Prob. 31PCh. 9 - Prob. 32PCh. 9 - Label the conjugate acid-base pairs in each...Ch. 9 - Label the conjugate acid-base pairs in each...Ch. 9 - Prob. 35PCh. 9 - Prob. 36PCh. 9 - Fill in the missing product in each acid-base...Ch. 9 - Fill in the missing product in each acid-base...Ch. 9 - Prob. 39PCh. 9 - Write the equation for the acid-base reaction that...Ch. 9 - Prob. 41PCh. 9 - Which diagram represents what happens when HCN...Ch. 9 - Prob. 43PCh. 9 - Prob. 44PCh. 9 - Prob. 45PCh. 9 - Use the data in and 9.2 and 9.3 to label the...Ch. 9 - Prob. 47PCh. 9 - Which acid, A or B, is stronger in each part? a. B...Ch. 9 - Fill in the missing terms (strong or weak) and...Ch. 9 - Fill in the missing terms (strong or weak) and...Ch. 9 - For each pair of acids: [1] Label the stronger...Ch. 9 - For each pair of acids: [1] Label the stronger...Ch. 9 - Prob. 53PCh. 9 - Prob. 54PCh. 9 - Prob. 55PCh. 9 - Calculate Ka forthe weak acid HA dissolved in...Ch. 9 - Prob. 57PCh. 9 - Label the acid in the reactants and the conjugate...Ch. 9 - Prob. 59PCh. 9 - Prob. 60PCh. 9 - Prob. 61PCh. 9 - Prob. 62PCh. 9 - Calculate the value of [OH-] from the given and...Ch. 9 - Calculate the value of [OH-] from the given [H3O+]...Ch. 9 - Calculate the value of [OH-] from the given [HO-]...Ch. 9 - Calculate the value of [H3O+] from the given [OH-]...Ch. 9 - Prob. 67PCh. 9 - Prob. 68PCh. 9 - Prob. 69PCh. 9 - Complete the following table with the needed...Ch. 9 - Prob. 71PCh. 9 - Prob. 72PCh. 9 - Prob. 73PCh. 9 - If pancreaticfluids have a pH of 8.2, calculate...Ch. 9 - Calculate the concentrations of H3O+ and OH in the...Ch. 9 - Prob. 76PCh. 9 - Prob. 77PCh. 9 - Prob. 78PCh. 9 - Prob. 79PCh. 9 - Prob. 80PCh. 9 - Write a balanced equation for each reaction. a....Ch. 9 - Prob. 82PCh. 9 - Prob. 83PCh. 9 - Prob. 84PCh. 9 - Prob. 85PCh. 9 - Prob. 86PCh. 9 - Prob. 87PCh. 9 - Prob. 88PCh. 9 - Whatisthe molarityofanaceticacid (CH3COOH)...Ch. 9 - What is the molarity of an H2SO4 solution if 18.5...Ch. 9 - How many milliliters of 1.0MNaOH solution are...Ch. 9 - How many milliliters of 2.0MNaOH solution are...Ch. 9 - Prob. 93PCh. 9 - Prob. 94PCh. 9 - Prob. 95PCh. 9 - Prob. 96PCh. 9 - Prob. 97PCh. 9 - Prob. 98PCh. 9 - Using the Ka values in Table9.6, calculate the pH...Ch. 9 - Using the Ka values in Table9.6, calculate the pH...Ch. 9 - Calculate the pH of an acetic acid/acetate buffer...Ch. 9 - Calculate the pH of a bicarbonate/carbonate buffer...Ch. 9 - Why is the pH of unpolluted rainwater lower than...Ch. 9 - The optimum pH of a swimming pool is 7.50....Ch. 9 - When an Individual hyperventilates, he is told to...Ch. 9 - A sample of rainwater has a pH of 4.18. (a)...Ch. 9 - How is CO2 concentration related to the pH of the...Ch. 9 - Explain why a lake on a bed of limestone is...Ch. 9 - Prob. 109CPCh. 9 - Prob. 110CP
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- Please correct answer and don't used hand raitingarrow_forwardQ2. Consider the hydrogenation of ethylene C2H4 + H2 = C2H6 The heats of combustion and molar entropies for the three gases at 298 K are given by: C2H4 C2H6 H2 AH comb/kJ mol¹ -1395 -1550 -243 Sº / J K¹ mol-1 220.7 230.4 131.1 The average heat capacity change, ACP, for the reaction over the temperature range 298-1000 K is 10.9 J K¹ mol¹. Using these data, determine: (a) the standard enthalpy change at 800 K (b) the standard entropy change at 800 K (c) the equilibrium constant at 800 K.arrow_forward13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B Bond A Bond C a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. Weakest Bond Strongest Bond b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. c. (5pts) Use principles discussed in lecture, supported by relevant structures, to succinctly explain the why your part b (i) radical is more stable than your part b(ii) radical. Written explanation can be no more than one-two succinct sentence(s)! Googlearrow_forward
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