Given species has to be rank from best nucleophile to the poorest nucleophile. Concept Introduction: Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen. Protic solvent are polar solvent molecules which have hydrogen bonded to oxygen to nitrogen. The stronger base is always a better nucleophile in an aprotic solvent. When the negatively charged species is placed in aprotic solvent, the solvent molecules arrange themselves with their partially positively charged hydrogens pointing towards the negatively charged species. The interaction between the ion and the dipole of the protic solvent is called an ion-dipole interaction

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Answer 1

Question

Chapter 9, Problem 74P

(a)

Interpretation Introduction

Interpretation:

Given species has to be rank from best nucleophile to the poorest nucleophile.

Concept Introduction:

Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.

Protic solvent are polar solvent molecules which have hydrogen bonded to oxygen to nitrogen.

The stronger base is always a better nucleophile in an aprotic solvent. When the negatively charged species is placed in aprotic solvent, the solvent molecules arrange themselves with their partially positively charged hydrogens pointing towards the negatively charged species. The interaction between the ion and the dipole of the protic solvent is called an ion-dipole interaction

(b)

Interpretation Introduction

Interpretation:

Given species has to be rank from best nucleophile to the poorest nucleophile.

Concept Introduction:

Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.

The stronger base is always a better nucleophile in an aprotic solvent.

(c)

Interpretation Introduction

Interpretation:

Given species has to be rank from best nucleophile to the poorest nucleophile.

Concept Introduction:

Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.

Protic solvent are polar solvent molecules which have hydrogen bonded to oxygen to nitrogen

The stronger base is always a better nucleophile in an aprotic solvent. When the negatively charged species is placed in aprotic solvent, the solvent molecules arrange themselves with their partially positively charged hydrogens pointing towards the negatively charged species. The interaction between the ion and the dipole of the protic solvent is called an ion-dipole interaction

(d)

Interpretation Introduction

Interpretation:

Given species has to be rank from best nucleophile to the poorest nucleophile.

Concept Introduction:

Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.

Protic solvent are polar solvent molecules which do have hydrogen bonded to oxygen to nitrogen

The stronger base is always a better nucleophile in an aprotic solvent.

When the negatively charged species is placed in aprotic solvent, the solvent molecules arrange themselves with their partially positively charged hydrogens pointing towards the negatively charged species. The interaction between the ion and the dipole of the protic solvent is called an ion-dipole interaction.

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Instructions: Complete the questions in the space provided. Show all your work 1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure the initial reaction rate and the starting concentrations of the reactions for 4 trials. BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l) Initial rate Trial [BrO3] [H*] [Br] (mol/L) (mol/L) | (mol/L) (mol/L.s) 1 0.10 0.10 0.10 8.0 2 0.20 0.10 0.10 16 3 0.10 0.20 0.10 16 4 0.10 0.10 0.20 32 a. Based on the above data what is the rate law expression? b. Solve for the value of k (make sure to include proper units) 2. The proposed reaction mechanism is as follows: i. ii. BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq) HBrO³ (aq) + H* (aq) → H₂BrO3* (aq) iii. H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l) [Fast] [Medium] [Slow] iv. Br₂O₂ (aq) + 4H*(aq) + 4Br‍(aq) → 3Br₂ (l) + H2O (l) [Fast] Evaluate the validity of this proposed reaction. Justify your answer.

Answer 2

Question

Chapter 9, Problem 74P

(a)

Interpretation Introduction

Interpretation:

Given species has to be rank from best nucleophile to the poorest nucleophile.

Concept Introduction:

Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.

Protic solvent are polar solvent molecules which have hydrogen bonded to oxygen to nitrogen.

The stronger base is always a better nucleophile in an aprotic solvent. When the negatively charged species is placed in aprotic solvent, the solvent molecules arrange themselves with their partially positively charged hydrogens pointing towards the negatively charged species. The interaction between the ion and the dipole of the protic solvent is called an ion-dipole interaction

(b)

Interpretation Introduction

Interpretation:

Given species has to be rank from best nucleophile to the poorest nucleophile.

Concept Introduction:

Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.

The stronger base is always a better nucleophile in an aprotic solvent.

(c)

Interpretation Introduction

Interpretation:

Given species has to be rank from best nucleophile to the poorest nucleophile.

Concept Introduction:

Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.

Protic solvent are polar solvent molecules which have hydrogen bonded to oxygen to nitrogen

The stronger base is always a better nucleophile in an aprotic solvent. When the negatively charged species is placed in aprotic solvent, the solvent molecules arrange themselves with their partially positively charged hydrogens pointing towards the negatively charged species. The interaction between the ion and the dipole of the protic solvent is called an ion-dipole interaction

(d)

Interpretation Introduction

Interpretation:

Given species has to be rank from best nucleophile to the poorest nucleophile.

Concept Introduction:

Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.

Protic solvent are polar solvent molecules which do have hydrogen bonded to oxygen to nitrogen

The stronger base is always a better nucleophile in an aprotic solvent.

When the negatively charged species is placed in aprotic solvent, the solvent molecules arrange themselves with their partially positively charged hydrogens pointing towards the negatively charged species. The interaction between the ion and the dipole of the protic solvent is called an ion-dipole interaction.

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Answer 3

Question

Chapter 9, Problem 74P

(a)

Interpretation Introduction

Interpretation:

Given species has to be rank from best nucleophile to the poorest nucleophile.

Concept Introduction:

Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.

Protic solvent are polar solvent molecules which have hydrogen bonded to oxygen to nitrogen.

The stronger base is always a better nucleophile in an aprotic solvent. When the negatively charged species is placed in aprotic solvent, the solvent molecules arrange themselves with their partially positively charged hydrogens pointing towards the negatively charged species. The interaction between the ion and the dipole of the protic solvent is called an ion-dipole interaction

(b)

Interpretation Introduction

Interpretation:

Given species has to be rank from best nucleophile to the poorest nucleophile.

Concept Introduction:

Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.

The stronger base is always a better nucleophile in an aprotic solvent.

(c)

Interpretation Introduction

Interpretation:

Given species has to be rank from best nucleophile to the poorest nucleophile.

Concept Introduction:

Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.

Protic solvent are polar solvent molecules which have hydrogen bonded to oxygen to nitrogen

The stronger base is always a better nucleophile in an aprotic solvent. When the negatively charged species is placed in aprotic solvent, the solvent molecules arrange themselves with their partially positively charged hydrogens pointing towards the negatively charged species. The interaction between the ion and the dipole of the protic solvent is called an ion-dipole interaction

(d)

Interpretation Introduction

Interpretation:

Given species has to be rank from best nucleophile to the poorest nucleophile.

Concept Introduction:

Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.

Protic solvent are polar solvent molecules which do have hydrogen bonded to oxygen to nitrogen

The stronger base is always a better nucleophile in an aprotic solvent.

When the negatively charged species is placed in aprotic solvent, the solvent molecules arrange themselves with their partially positively charged hydrogens pointing towards the negatively charged species. The interaction between the ion and the dipole of the protic solvent is called an ion-dipole interaction.

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Answer 4

Question

Chapter 9, Problem 74P

(a)

Interpretation Introduction

Interpretation:

Given species has to be rank from best nucleophile to the poorest nucleophile.

Concept Introduction:

Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.

Protic solvent are polar solvent molecules which have hydrogen bonded to oxygen to nitrogen.

The stronger base is always a better nucleophile in an aprotic solvent. When the negatively charged species is placed in aprotic solvent, the solvent molecules arrange themselves with their partially positively charged hydrogens pointing towards the negatively charged species. The interaction between the ion and the dipole of the protic solvent is called an ion-dipole interaction

(b)

Interpretation Introduction

Interpretation:

Given species has to be rank from best nucleophile to the poorest nucleophile.

Concept Introduction:

Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.

The stronger base is always a better nucleophile in an aprotic solvent.

(c)

Interpretation Introduction

Interpretation:

Given species has to be rank from best nucleophile to the poorest nucleophile.

Concept Introduction:

Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.

Protic solvent are polar solvent molecules which have hydrogen bonded to oxygen to nitrogen

The stronger base is always a better nucleophile in an aprotic solvent. When the negatively charged species is placed in aprotic solvent, the solvent molecules arrange themselves with their partially positively charged hydrogens pointing towards the negatively charged species. The interaction between the ion and the dipole of the protic solvent is called an ion-dipole interaction

(d)

Interpretation Introduction

Interpretation:

Given species has to be rank from best nucleophile to the poorest nucleophile.

Concept Introduction:

Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.

Protic solvent are polar solvent molecules which do have hydrogen bonded to oxygen to nitrogen

The stronger base is always a better nucleophile in an aprotic solvent.

When the negatively charged species is placed in aprotic solvent, the solvent molecules arrange themselves with their partially positively charged hydrogens pointing towards the negatively charged species. The interaction between the ion and the dipole of the protic solvent is called an ion-dipole interaction.

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Answer 5

Chapter 9, Problem 74P

(a)

Interpretation Introduction

Interpretation:

Given species has to be rank from best nucleophile to the poorest nucleophile.

Concept Introduction:

Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.

Protic solvent are polar solvent molecules which have hydrogen bonded to oxygen to nitrogen.

The stronger base is always a better nucleophile in an aprotic solvent. When the negatively charged species is placed in aprotic solvent, the solvent molecules arrange themselves with their partially positively charged hydrogens pointing towards the negatively charged species. The interaction between the ion and the dipole of the protic solvent is called an ion-dipole interaction

(b)

Interpretation Introduction

Interpretation:

Given species has to be rank from best nucleophile to the poorest nucleophile.

Concept Introduction:

Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.

The stronger base is always a better nucleophile in an aprotic solvent.

(c)

Interpretation Introduction

Interpretation:

Given species has to be rank from best nucleophile to the poorest nucleophile.

Concept Introduction:

Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.

Protic solvent are polar solvent molecules which have hydrogen bonded to oxygen to nitrogen

The stronger base is always a better nucleophile in an aprotic solvent. When the negatively charged species is placed in aprotic solvent, the solvent molecules arrange themselves with their partially positively charged hydrogens pointing towards the negatively charged species. The interaction between the ion and the dipole of the protic solvent is called an ion-dipole interaction

(d)

Interpretation Introduction

Interpretation:

Given species has to be rank from best nucleophile to the poorest nucleophile.

Concept Introduction:

Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.

Protic solvent are polar solvent molecules which do have hydrogen bonded to oxygen to nitrogen

The stronger base is always a better nucleophile in an aprotic solvent.

When the negatively charged species is placed in aprotic solvent, the solvent molecules arrange themselves with their partially positively charged hydrogens pointing towards the negatively charged species. The interaction between the ion and the dipole of the protic solvent is called an ion-dipole interaction.

Answer 6

Chapter 9, Problem 74P

(a)

Interpretation Introduction

Interpretation:

Given species has to be rank from best nucleophile to the poorest nucleophile.

Concept Introduction:

Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.

Protic solvent are polar solvent molecules which have hydrogen bonded to oxygen to nitrogen.

The stronger base is always a better nucleophile in an aprotic solvent. When the negatively charged species is placed in aprotic solvent, the solvent molecules arrange themselves with their partially positively charged hydrogens pointing towards the negatively charged species. The interaction between the ion and the dipole of the protic solvent is called an ion-dipole interaction

Answer 7

Chapter 9, Problem 74P

(a)

Interpretation Introduction

Interpretation:

Given species has to be rank from best nucleophile to the poorest nucleophile.

Concept Introduction:

Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.

Protic solvent are polar solvent molecules which have hydrogen bonded to oxygen to nitrogen.

The stronger base is always a better nucleophile in an aprotic solvent. When the negatively charged species is placed in aprotic solvent, the solvent molecules arrange themselves with their partially positively charged hydrogens pointing towards the negatively charged species. The interaction between the ion and the dipole of the protic solvent is called an ion-dipole interaction

Answer 8

(b)

Interpretation Introduction

Interpretation:

Given species has to be rank from best nucleophile to the poorest nucleophile.

Concept Introduction:

Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.

The stronger base is always a better nucleophile in an aprotic solvent.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Given species has to be rank from best nucleophile to the poorest nucleophile.

Concept Introduction:

Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.

The stronger base is always a better nucleophile in an aprotic solvent.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Given species has to be rank from best nucleophile to the poorest nucleophile.

Concept Introduction:

Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.

Protic solvent are polar solvent molecules which have hydrogen bonded to oxygen to nitrogen

The stronger base is always a better nucleophile in an aprotic solvent. When the negatively charged species is placed in aprotic solvent, the solvent molecules arrange themselves with their partially positively charged hydrogens pointing towards the negatively charged species. The interaction between the ion and the dipole of the protic solvent is called an ion-dipole interaction

Answer 11

(c)

Interpretation Introduction

Interpretation:

Given species has to be rank from best nucleophile to the poorest nucleophile.

Concept Introduction:

Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.

Protic solvent are polar solvent molecules which have hydrogen bonded to oxygen to nitrogen

The stronger base is always a better nucleophile in an aprotic solvent. When the negatively charged species is placed in aprotic solvent, the solvent molecules arrange themselves with their partially positively charged hydrogens pointing towards the negatively charged species. The interaction between the ion and the dipole of the protic solvent is called an ion-dipole interaction

Answer 12

(d)

Interpretation Introduction

Interpretation:

Given species has to be rank from best nucleophile to the poorest nucleophile.

Concept Introduction:

Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.

Protic solvent are polar solvent molecules which do have hydrogen bonded to oxygen to nitrogen

The stronger base is always a better nucleophile in an aprotic solvent.

When the negatively charged species is placed in aprotic solvent, the solvent molecules arrange themselves with their partially positively charged hydrogens pointing towards the negatively charged species. The interaction between the ion and the dipole of the protic solvent is called an ion-dipole interaction.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Given species has to be rank from best nucleophile to the poorest nucleophile.

Concept Introduction:

Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.

Protic solvent are polar solvent molecules which do have hydrogen bonded to oxygen to nitrogen

The stronger base is always a better nucleophile in an aprotic solvent.

When the negatively charged species is placed in aprotic solvent, the solvent molecules arrange themselves with their partially positively charged hydrogens pointing towards the negatively charged species. The interaction between the ion and the dipole of the protic solvent is called an ion-dipole interaction.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 9.1 - Prob. 3P Ch. 9.1 - Does increasing the energy barrier for an SN2...Ch. 9.1 - Rank the following alkyl bromides from most...Ch. 9.1 - Prob. 8P Ch. 9.2 - Prob. 9P Ch. 9.2 - Prob. 10P Ch. 9.2 - Prob. 11P Ch. 9.2 - Prob. 12P Ch. 9.2 - Which substitution reaction lakes place more...Ch. 9.2 - Prob. 15P

Solution Summary: The author explains that polar solvent molecules do not have hydrogen bonded to oxygen to nitrogen. Stronger bases are better nucleophiles in aprotic solvents.

Interpretation:

Given species has to be rank from best nucleophile to the poorest nucleophile.

Concept Introduction:

Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.

The stronger base is always a better nucleophile in an aprotic solvent.

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Chapter 9 Solutions

Solution Summary: The author explains that polar solvent molecules do not have hydrogen bonded to oxygen to nitrogen. Stronger bases are better nucleophiles in aprotic solvents.

Interpretation: Given species has to be rank from best nucleophile to the poorest nucleophile. Concept Introduction: Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen. The stronger base is always a better nucleophile in an aprotic solvent.

Want to see the full answer?

Chapter 9 Solutions

Interpretation:

Given species has to be rank from best nucleophile to the poorest nucleophile.

Concept Introduction:

Aprotic solvent are polar solvent molecules which do not have hydrogen bonded to oxygen to nitrogen.

The stronger base is always a better nucleophile in an aprotic solvent.