Mention the isomer with a lower boiling point between hexane and 2, 3-dimethylbutane Concept Introduction: Hexane can be defined as the alkane which has six carbon atoms. Chemical formula - Characteristics of hexane are: Colorless liquid In pure form, it is odourless Hexane is one of the constituents of gasoline. One of the isomer of hexane is 2, 3-dimethylbutane. Chemical formula - Characteristics of 2, 3-dimethylbutaneare: Colorless liquid Water insoluble It has a petroleum like odour

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Answer 1

Question

Chapter 9, Problem 64AP

a)

Interpretation Introduction

Interpretation:

Mention the isomer with a lower boiling point between hexane and 2, 3-dimethylbutane

Concept Introduction:

Hexane can be defined as the alkane which has six carbon atoms.

Chemical formula -

Characteristics of hexane are:

Colorless liquid

In pure form, it is odourless
Hexane is one of the constituents of gasoline.
One of the isomer of hexane is 2, 3-dimethylbutane.

Chemical formula -

Characteristics of 2, 3-dimethylbutaneare:

Colorless liquid

Water insoluble

It has a petroleum like odour

b)

Interpretation Introduction

Interpretation:

Mention the isomer with a lower boiling point between pentane and 2, 2-dimethylpropane

Concept Introduction:

Pentane can be defined as the alkane which has five carbon atoms.

Chemical formula -

Characteristics of pentane are:

Colorless liquid

Water insoluble

It has petroleum like odor
2, 2-dimethylpropane can be defined as the alkane having double-chained-branch with five carbon atoms.

c)

Interpretation Introduction

Interpretation:

Mention the isomer with a lower boiling point between heptane and 2, 4-dimethylpentane

Concept Introduction:

Heptane can be defined as the alkane which is straight-chain.

Chemical formula -

Characteristics of heptane are:

Colorless liquid

Water insoluble

It has petroleum like odour

2, 4-dimethylpentane can be defined as the alkane having chemical formula

d)

Interpretation Introduction

Interpretation:

Mention the isomer with a lower boiling point between octane and 2, 2, 4-trimethylpentane

Concept Introduction:

Octane can be defined as the alkane and the hydrocarbon.

Chemical formula -

Characteristics of octane are:

Volatile

Very flammable

2, 2, 4-trimethylpentanecan be defined as the organic compound having chemical formula

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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10

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Answer 2

Question

Chapter 9, Problem 64AP

a)

Interpretation Introduction

Interpretation:

Mention the isomer with a lower boiling point between hexane and 2, 3-dimethylbutane

Concept Introduction:

Hexane can be defined as the alkane which has six carbon atoms.

Chemical formula -

Characteristics of hexane are:

Colorless liquid

In pure form, it is odourless
Hexane is one of the constituents of gasoline.
One of the isomer of hexane is 2, 3-dimethylbutane.

Chemical formula -

Characteristics of 2, 3-dimethylbutaneare:

Colorless liquid

Water insoluble

It has a petroleum like odour

b)

Interpretation Introduction

Interpretation:

Mention the isomer with a lower boiling point between pentane and 2, 2-dimethylpropane

Concept Introduction:

Pentane can be defined as the alkane which has five carbon atoms.

Chemical formula -

Characteristics of pentane are:

Colorless liquid

Water insoluble

It has petroleum like odor
2, 2-dimethylpropane can be defined as the alkane having double-chained-branch with five carbon atoms.

c)

Interpretation Introduction

Interpretation:

Mention the isomer with a lower boiling point between heptane and 2, 4-dimethylpentane

Concept Introduction:

Heptane can be defined as the alkane which is straight-chain.

Chemical formula -

Characteristics of heptane are:

Colorless liquid

Water insoluble

It has petroleum like odour

2, 4-dimethylpentane can be defined as the alkane having chemical formula

d)

Interpretation Introduction

Interpretation:

Mention the isomer with a lower boiling point between octane and 2, 2, 4-trimethylpentane

Concept Introduction:

Octane can be defined as the alkane and the hydrocarbon.

Chemical formula -

Characteristics of octane are:

Volatile

Very flammable

2, 2, 4-trimethylpentanecan be defined as the organic compound having chemical formula

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Answer 3

Question

Chapter 9, Problem 64AP

a)

Interpretation Introduction

Interpretation:

Mention the isomer with a lower boiling point between hexane and 2, 3-dimethylbutane

Concept Introduction:

Hexane can be defined as the alkane which has six carbon atoms.

Chemical formula -

Characteristics of hexane are:

Colorless liquid

In pure form, it is odourless
Hexane is one of the constituents of gasoline.
One of the isomer of hexane is 2, 3-dimethylbutane.

Chemical formula -

Characteristics of 2, 3-dimethylbutaneare:

Colorless liquid

Water insoluble

It has a petroleum like odour

b)

Interpretation Introduction

Interpretation:

Mention the isomer with a lower boiling point between pentane and 2, 2-dimethylpropane

Concept Introduction:

Pentane can be defined as the alkane which has five carbon atoms.

Chemical formula -

Characteristics of pentane are:

Colorless liquid

Water insoluble

It has petroleum like odor
2, 2-dimethylpropane can be defined as the alkane having double-chained-branch with five carbon atoms.

c)

Interpretation Introduction

Interpretation:

Mention the isomer with a lower boiling point between heptane and 2, 4-dimethylpentane

Concept Introduction:

Heptane can be defined as the alkane which is straight-chain.

Chemical formula -

Characteristics of heptane are:

Colorless liquid

Water insoluble

It has petroleum like odour

2, 4-dimethylpentane can be defined as the alkane having chemical formula

d)

Interpretation Introduction

Interpretation:

Mention the isomer with a lower boiling point between octane and 2, 2, 4-trimethylpentane

Concept Introduction:

Octane can be defined as the alkane and the hydrocarbon.

Chemical formula -

Characteristics of octane are:

Volatile

Very flammable

2, 2, 4-trimethylpentanecan be defined as the organic compound having chemical formula

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Answer 4

Question

Chapter 9, Problem 64AP

a)

Interpretation Introduction

Interpretation:

Mention the isomer with a lower boiling point between hexane and 2, 3-dimethylbutane

Concept Introduction:

Hexane can be defined as the alkane which has six carbon atoms.

Chemical formula -

Characteristics of hexane are:

Colorless liquid

In pure form, it is odourless
Hexane is one of the constituents of gasoline.
One of the isomer of hexane is 2, 3-dimethylbutane.

Chemical formula -

Characteristics of 2, 3-dimethylbutaneare:

Colorless liquid

Water insoluble

It has a petroleum like odour

b)

Interpretation Introduction

Interpretation:

Mention the isomer with a lower boiling point between pentane and 2, 2-dimethylpropane

Concept Introduction:

Pentane can be defined as the alkane which has five carbon atoms.

Chemical formula -

Characteristics of pentane are:

Colorless liquid

Water insoluble

It has petroleum like odor
2, 2-dimethylpropane can be defined as the alkane having double-chained-branch with five carbon atoms.

c)

Interpretation Introduction

Interpretation:

Mention the isomer with a lower boiling point between heptane and 2, 4-dimethylpentane

Concept Introduction:

Heptane can be defined as the alkane which is straight-chain.

Chemical formula -

Characteristics of heptane are:

Colorless liquid

Water insoluble

It has petroleum like odour

2, 4-dimethylpentane can be defined as the alkane having chemical formula

d)

Interpretation Introduction

Interpretation:

Mention the isomer with a lower boiling point between octane and 2, 2, 4-trimethylpentane

Concept Introduction:

Octane can be defined as the alkane and the hydrocarbon.

Chemical formula -

Characteristics of octane are:

Volatile

Very flammable

2, 2, 4-trimethylpentanecan be defined as the organic compound having chemical formula

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Answer 5

Chapter 9, Problem 64AP

a)

Interpretation Introduction

Interpretation:

Mention the isomer with a lower boiling point between hexane and 2, 3-dimethylbutane

Concept Introduction:

Hexane can be defined as the alkane which has six carbon atoms.

Chemical formula -

Characteristics of hexane are:

Colorless liquid

In pure form, it is odourless
Hexane is one of the constituents of gasoline.
One of the isomer of hexane is 2, 3-dimethylbutane.

Chemical formula -

Characteristics of 2, 3-dimethylbutaneare:

Colorless liquid

Water insoluble

It has a petroleum like odour

b)

Interpretation Introduction

Interpretation:

Mention the isomer with a lower boiling point between pentane and 2, 2-dimethylpropane

Concept Introduction:

Pentane can be defined as the alkane which has five carbon atoms.

Chemical formula -

Characteristics of pentane are:

Colorless liquid

Water insoluble

It has petroleum like odor
2, 2-dimethylpropane can be defined as the alkane having double-chained-branch with five carbon atoms.

c)

Interpretation Introduction

Interpretation:

Mention the isomer with a lower boiling point between heptane and 2, 4-dimethylpentane

Concept Introduction:

Heptane can be defined as the alkane which is straight-chain.

Chemical formula -

Characteristics of heptane are:

Colorless liquid

Water insoluble

It has petroleum like odour

2, 4-dimethylpentane can be defined as the alkane having chemical formula

d)

Interpretation Introduction

Interpretation:

Mention the isomer with a lower boiling point between octane and 2, 2, 4-trimethylpentane

Concept Introduction:

Octane can be defined as the alkane and the hydrocarbon.

Chemical formula -

Characteristics of octane are:

Volatile

Very flammable

2, 2, 4-trimethylpentanecan be defined as the organic compound having chemical formula

Answer 6

Chapter 9, Problem 64AP

a)

Interpretation Introduction

Interpretation:

Mention the isomer with a lower boiling point between hexane and 2, 3-dimethylbutane

Concept Introduction:

Hexane can be defined as the alkane which has six carbon atoms.

Chemical formula -

Characteristics of hexane are:

Colorless liquid

In pure form, it is odourless
Hexane is one of the constituents of gasoline.
One of the isomer of hexane is 2, 3-dimethylbutane.

Chemical formula -

Characteristics of 2, 3-dimethylbutaneare:

Colorless liquid

Water insoluble

It has a petroleum like odour

Answer 7

Chapter 9, Problem 64AP

a)

Interpretation Introduction

Interpretation:

Mention the isomer with a lower boiling point between hexane and 2, 3-dimethylbutane

Concept Introduction:

Hexane can be defined as the alkane which has six carbon atoms.

Chemical formula -

Characteristics of hexane are:

Colorless liquid

In pure form, it is odourless
Hexane is one of the constituents of gasoline.
One of the isomer of hexane is 2, 3-dimethylbutane.

Chemical formula -

Characteristics of 2, 3-dimethylbutaneare:

Colorless liquid

Water insoluble

It has a petroleum like odour

Answer 8

b)

Interpretation Introduction

Interpretation:

Mention the isomer with a lower boiling point between pentane and 2, 2-dimethylpropane

Concept Introduction:

Pentane can be defined as the alkane which has five carbon atoms.

Chemical formula -

Characteristics of pentane are:

Colorless liquid

Water insoluble

It has petroleum like odor
2, 2-dimethylpropane can be defined as the alkane having double-chained-branch with five carbon atoms.

Answer 9

b)

Interpretation Introduction

Interpretation:

Mention the isomer with a lower boiling point between pentane and 2, 2-dimethylpropane

Concept Introduction:

Pentane can be defined as the alkane which has five carbon atoms.

Chemical formula -

Characteristics of pentane are:

Colorless liquid

Water insoluble

It has petroleum like odor
2, 2-dimethylpropane can be defined as the alkane having double-chained-branch with five carbon atoms.

Answer 10

c)

Interpretation Introduction

Interpretation:

Mention the isomer with a lower boiling point between heptane and 2, 4-dimethylpentane

Concept Introduction:

Heptane can be defined as the alkane which is straight-chain.

Chemical formula -

Characteristics of heptane are:

Colorless liquid

Water insoluble

It has petroleum like odour

2, 4-dimethylpentane can be defined as the alkane having chemical formula

Answer 11

c)

Interpretation Introduction

Interpretation:

Mention the isomer with a lower boiling point between heptane and 2, 4-dimethylpentane

Concept Introduction:

Heptane can be defined as the alkane which is straight-chain.

Chemical formula -

Characteristics of heptane are:

Colorless liquid

Water insoluble

It has petroleum like odour

2, 4-dimethylpentane can be defined as the alkane having chemical formula

Answer 12

d)

Interpretation Introduction

Interpretation:

Mention the isomer with a lower boiling point between octane and 2, 2, 4-trimethylpentane

Concept Introduction:

Octane can be defined as the alkane and the hydrocarbon.

Chemical formula -

Characteristics of octane are:

Volatile

Very flammable

2, 2, 4-trimethylpentanecan be defined as the organic compound having chemical formula

Answer 13

d)

Interpretation Introduction

Interpretation:

Mention the isomer with a lower boiling point between octane and 2, 2, 4-trimethylpentane

Concept Introduction:

Octane can be defined as the alkane and the hydrocarbon.

Chemical formula -

Characteristics of octane are:

Volatile

Very flammable

2, 2, 4-trimethylpentanecan be defined as the organic compound having chemical formula

Answer 14

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Answer 16

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Answer 17

Ch. 9 - Prob. 1RQ Ch. 9 - Prob. 2RQ Ch. 9 - Prob. 3RQ Ch. 9 - Prob. 4RQ Ch. 9 - Prob. 5RQ Ch. 9 - Prob. 6RQ Ch. 9 - Prob. 7RQ Ch. 9 - Prob. 8RQ Ch. 9 - Prob. 9RQ Ch. 9 - Prob. 10RQ

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Chapter 9 Solutions