Basic Chemistry
6th Edition
ISBN: 9780134878119
Author: Timberlake, Karen C. , William
Publisher: Pearson,
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Question
Chapter 9, Problem 60APP
Interpretation Introduction
Interpretation : The mass of
Concept Introduction : If there are more than one reactant present in the
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Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
Chapter 9 Solutions
Basic Chemistry
Ch. 9.1 - Calculate the total mass of the reactants and the...Ch. 9.1 - Calculate the total mass of the reactants and the...Ch. 9.2 - Calculate the total mass of the reactants and the...Ch. 9.2 - Write all of the mole-mole factors for each of the...Ch. 9.2 - For the chemical equations in problem 9.3, write...Ch. 9.2 - For the chemical equations in problem 9.4, write...Ch. 9.2 - The chemical reaction of hydrogen with oxygen...Ch. 9.2 - Ammonia is produced by the chemical reaction of...Ch. 9.2 - Carbon disulfide and carbon monoxide are produced...Ch. 9.2 - In the acetylene torch, acetylene gas burns in...
Ch. 9.3 - Sodium reacts with oxygen to produce sodium oxide....Ch. 9.3 - Nitrogen reacts with hydrogen to produce ammonia....Ch. 9.3 - Ammonia and oxygen react to form nitrogen and...Ch. 9.3 - Iron(III) oxide reacts with carbon to give iron...Ch. 9.3 - Prob. 15PPCh. 9.3 - Calcium cyanamide, CaCN2 , reacts with water to...Ch. 9.3 - Prob. 17PPCh. 9.3 - Prob. 18PPCh. 9.4 - A taxi company has 10 taxis. a. On a certain day,...Ch. 9.4 - Prob. 20PPCh. 9.4 - Prob. 21PPCh. 9.4 - Iron and oxygen react to form iron(III) oxide....Ch. 9.4 - For each of the following reactions, 20.0 g of...Ch. 9.4 - For each of the following reactions, 20.0 g of...Ch. 9.4 - For each of the following reactions, calculate the...Ch. 9.4 - For each of the following reactions, calculate the...Ch. 9.5 - Carbon disulfide is produced by the reaction of...Ch. 9.5 - Iron (III) oxide reacts with carbon monoxide to...Ch. 9.5 - Aluminum reacts with oxygen to produce aluminum...Ch. 9.5 - Propane ( C3H8 ) bums in oxygen to produce carbon...Ch. 9.5 - Prob. 31PPCh. 9.5 - When 56.6 g of calcium is reacted with nitrogen...Ch. 9.6 - In an exothermic reaction, is the energy of the...Ch. 9.6 - In an endothermic reaction, is the energy of the...Ch. 9.6 - Prob. 35PPCh. 9.6 - Prob. 36PPCh. 9.6 - Classify each of the following as exothermic or...Ch. 9.6 - Classify each of the following as exothermic or...Ch. 9.6 - Prob. 39PPCh. 9.6 - a. How many kilojoules are released when 75.0 g of...Ch. 9.6 - Prob. 41PPCh. 9.6 - Calculate the energy change for the reaction...Ch. 9.6 - Prob. 43PPCh. 9.6 - Prob. 44PPCh. 9.6 - In one step in the synthesis of the insecticide...Ch. 9.6 - Another widely used insecticide is carbofuran...Ch. 9 - The chapter sections lo review are shown in...Ch. 9 - The chapter sections lo review are shown in...Ch. 9 - The chapter sections lo review are shown in...Ch. 9 - The chapter sections lo review are shown in...Ch. 9 - The chapter sections lo review are shown in...Ch. 9 - The chapter sections lo review are shown in...Ch. 9 - The chapter sections lo review are shown in...Ch. 9 - The chapter sections lo review are shown in...Ch. 9 - Prob. 55APPCh. 9 - Prob. 56APPCh. 9 - Prob. 57APPCh. 9 - Prob. 58APPCh. 9 - Prob. 59APPCh. 9 - Prob. 60APPCh. 9 - Pentane gas ( C5H12 ) reacts with oxygen to...Ch. 9 - Prob. 62APPCh. 9 - Prob. 63APPCh. 9 - Prob. 64APPCh. 9 - Prob. 65APPCh. 9 - Prob. 66APPCh. 9 - Prob. 67APPCh. 9 - Prob. 68APPCh. 9 - Prob. 69APPCh. 9 - The equation for the reaction of iron and oxygen...Ch. 9 - Prob. 71APPCh. 9 - Prob. 72APPCh. 9 - Prob. 73CPCh. 9 - Prob. 74CPCh. 9 - Prob. 75CPCh. 9 - The following problems are related to the topics...Ch. 9 - Prob. 77CPCh. 9 - Prob. 78CPCh. 9 - Prob. 79CPCh. 9 - Prob. 80CPCh. 9 - The following problems are related to the topics...Ch. 9 - Prob. 82CPCh. 9 - Prob. 83CPCh. 9 - The following problems are related to the topics...Ch. 9 - Prob. 85CPCh. 9 - Prob. 86CP
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