ORGANIC CHEMISTRY-STD.WILEY PLUS CARD
ORGANIC CHEMISTRY-STD.WILEY PLUS CARD
3rd Edition
ISBN: 9781119340515
Author: Klein
Publisher: WILEY
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Chapter 9, Problem 55PP
Interpretation Introduction

Interpretation:

The target molecule should be drawn for the given statements by using its molecular formula.

Concept introduction:

Isomeric structures: The many chemical compounds exist in different isomeric forms, which can be different enantiomeric structures but the same chemical formula. These type of isomers differ in the order in which the atoms are connected so they can contain different functional groups and (or) bonding patterns.

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1. Use standard reduction potentials to rationalize quantitatively why: (6 points) (a) Al liberates H2 from dilute HCl, but Ag does not; (b) Cl2 liberates Br2 from aqueous KBr solution, but does not liberate C12 from aqueous KCl solution; c) a method of growing Ag crystals is to immerse a zinc foil in an aqueous solution of AgNO3.
What would be the best choices for the missing reagents 1 and 3 in this synthesis? 1 1. PPh3 2. n-BuLi 3 2 • Draw the missing reagents in the drawing area below. You can draw them in any arrangement you like. • Do not draw the missing reagent 2. If you draw 1 correctly, we'll know what it is. • Note: if one of your reagents needs to contain a halogen, use bromine. Click and drag to start drawing a structure. X
What is the missing reactant R in this organic reaction? N N H3O+ +R + • Draw the structure of R in the drawing area below. • Be sure to use wedge and dash bonds if it's necessary to draw one particular enantiomer. Click and drag to start drawing a structure. fm

Chapter 9 Solutions

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