ORGANIC CHEMISTRY GGC>CUSTOM<-TEXT
ORGANIC CHEMISTRY GGC>CUSTOM<-TEXT
2nd Edition
ISBN: 9781119288510
Author: Klein
Publisher: WILEY
Question
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Chapter 9, Problem 51PP

  (a)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given reactions.

Concept introduction:

  • Mechanism: mechanism describes the reaction path and process.
  • Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.
  • Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.
  • Simple hydration in acidic media gives the addition product through carbocation intermediate.

To draw: the mechanism for the given transformation.

(b)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given reactions.

Concept introduction:

  • Mechanism: mechanism describes the reaction path and process.
  • Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.
  • Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.
  • Simple hydration in acidic media gives the addition product through carbocation intermediate.

To draw: the mechanism for the given transformation.

  (c)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given reactions.

Concept introduction:

  • Mechanism: mechanism describes the reaction path and process.
  • Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.
  • Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.
  • Simple hydration in acidic media gives the addition product through carbocation intermediate.

To draw: the mechanism for the given transformation.

(d)

Interpretation Introduction

Interpretation:

Mechanism should be drawn for the given reactions.

Concept introduction:

  • Mechanism: mechanism describes the reaction path and process.
  • Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.
  • Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.
  • Simple hydration in acidic media gives the addition product through carbocation intermediate.

To draw: the mechanism for the given transformation.

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Chapter 9 Solutions

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