ORGANIC CHEMISTRY GGC>CUSTOM<-TEXT
ORGANIC CHEMISTRY GGC>CUSTOM<-TEXT
2nd Edition
ISBN: 9781119288510
Author: Klein
Publisher: WILEY
Question
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Chapter 9.13, Problem 47ATS

  (a)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

  • Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.
    • Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.
    • Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.
    • Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.
    • Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

(b)

Interpretation Introduction

Interpretation:

Reagents should be predicted for the given transformations.

Concept introduction:

  • Reagent: reagent is a compound or compound mixture that is used in the chemical transformation of the reactions. Reagents for some reactions are given below.
    • Elimination reaction: in elimination reaction, two substituents are removed from the substrate to give the product in presence of base.
    • Elimination of compound in presence of bulky base leads to less substituted alkene, in presence of strong base (not bulky) leads to more substituted alkene.
    • Addition reaction: in addition reaction, two substituents are added to the reactant without losing any compound.
    • Hydro halogenation: hydrogen and halogen added across the double bond of the alkene in Markovnikov’s path is called hydro halogenation. This addition reaction proceeds via anti-Markovnikov’s path in presence of peroxides.

To find: the reagent for the given transformation.

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Chapter 9 Solutions

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