INTRODUCTION TO CHEMISTRY(LL)-W/CONNECT
5th Edition
ISBN: 9781260264920
Author: BAUER
Publisher: MCG
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Chapter 9, Problem 48QP
Interpretation Introduction
Interpretation:
The effect on gas particles and the volume of gas on cooling is to be determined.
Concept Introduction:
Charles’s law states that at constant pressure, an increase in temperature of the gas also increases the volume of the gas. The temperature of gas is directly proportional to the volume of gas.
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Identify and provide an explanation of the operational principles behind a Atomic Absorption Spectrometer (AAS). List the steps involved.
Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
Chapter 9 Solutions
INTRODUCTION TO CHEMISTRY(LL)-W/CONNECT
Ch. 9 - Prob. 1QCCh. 9 - Prob. 2QCCh. 9 - Prob. 3QCCh. 9 - Prob. 4QCCh. 9 - Prob. 5QCCh. 9 - Prob. 1PPCh. 9 - Prob. 2PPCh. 9 - What pressure is needed to compress 455 mL of...Ch. 9 - Prob. 4PPCh. 9 - Prob. 5PP
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