Two molecules used in the polymer industry are azodicarbonamide and methyl cyanoacrylate. Their structures are Azodicarbonamide Methyl cyanoracy late Azodicarbonamide is used in forming polystyrene. When added to the molten plastic, it decomposes to nitrogen, carbon monoxide, and ammonia gases, which are captured as bubbles in the molten polymer. Methyl cyanoacrylate is the main ingredient in super glue. As the glue sets, methyl cyanoacrylate polymerizes across the carbon-carbon double bond. (See Chapter 21.) a. Complete the Lewis structures showing all lone pairs of electrons. b. Which hybrid orbitals are used by the carbon atoms in each molecule and the nitrogen atom in azodicarbonamide? c. How many π bonds are present in each molecule? d. Give approximate values for the bond angles marked a through h in the previous structures.
Two molecules used in the polymer industry are azodicarbonamide and methyl cyanoacrylate. Their structures are Azodicarbonamide Methyl cyanoracy late Azodicarbonamide is used in forming polystyrene. When added to the molten plastic, it decomposes to nitrogen, carbon monoxide, and ammonia gases, which are captured as bubbles in the molten polymer. Methyl cyanoacrylate is the main ingredient in super glue. As the glue sets, methyl cyanoacrylate polymerizes across the carbon-carbon double bond. (See Chapter 21.) a. Complete the Lewis structures showing all lone pairs of electrons. b. Which hybrid orbitals are used by the carbon atoms in each molecule and the nitrogen atom in azodicarbonamide? c. How many π bonds are present in each molecule? d. Give approximate values for the bond angles marked a through h in the previous structures.
Solution Summary: The author explains the Lewis structures of Azodicarbonamide and Methyl cyanoacrylate. The approximate value of bond angles and the hybridization of the carbon and nitrogen atoms is to be predicted.
Two molecules used in the polymer industry are azodicarbonamide and methyl cyanoacrylate. Their structures are
Azodicarbonamide
Methyl cyanoracy late
Azodicarbonamide is used in forming polystyrene. When added to the molten plastic, it decomposes to nitrogen, carbon monoxide, and ammonia gases, which are captured as bubbles in the molten polymer. Methyl cyanoacrylate is the main ingredient in super glue. As the glue sets, methyl cyanoacrylate polymerizes across the carbon-carbon double bond. (See Chapter 21.)
a. Complete the Lewis structures showing all lone pairs of electrons.
b. Which hybrid orbitals are used by the carbon atoms in each molecule and the nitrogen atom in azodicarbonamide?
c. How many π bonds are present in each molecule?
d. Give approximate values for the bond angles marked a through h in the previous structures.
Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.
describe the hybridization, bonding and geometry in a molecule of benzene. Explain the stability in terms of two resonance structures.
The molecular structure of hinokitiol is represented below (See attached image)
Draw a complete Lewis structure of the molecule and answer the following questions.
Complete the structure by adding ONLY hydrogen atoms to carbon atoms where needed. You must not create any other bonds. Atoms such as oxygen or nitrogen may have lone pairs to complete their octets.
Each of the non-hydrogen atoms of this skeletal structure has been randomly numbered.
Match the atom number with the orbital hybridization invoked for sigma bonding.
Match these to the below (A)) (Options: sp3, sp2, sp, s, p, d2sp3, dsp3)
A) 12, 9, 7, 2, 4
B) How many pairs of non-bonding electrons are there in the molecule?
C) How many CH3 (methyl) groups are there in the molecule?
D) How many CH2 (methylene) groups are there in the molecule? (i.e. # of C-atoms having exactly two bonded H-atoms)
E) How many CH (methyne) groups are there in the molecule? (i.e. # of C-atoms having exactly one bonded H-atom)
F) How many…
What is the maximum number of double bonds that a nitrogen atom can form?
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