Organic Chemistry - Standalone book
Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Chapter 9, Problem 22P
Interpretation Introduction

Interpretation:

The structures of oleic acid and stearic acid are to be drawn.

Concept introduction:

The reaction of alkynes in the presence a metal catalyst such as platinum, palladium, nickel, or rhodium leads to the addition of two hydrogen atoms across the triple bond of an alkyne to yield an alkane.

Hydrogenation reaction of alkynes to alkenes using the Lindlar catalyst is stereoselective. In this reaction only the cis alkene is produced.

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Propane, C3H8, is a hydrocarbon that is commonly used as a fuel.(a) Write a balanced equation for the complete combustion of propane gas.(b) Calculate the volume of air at 25 °C and 1.00 atmosphere that is needed to completely combust 25.0 grams of propane. Assume that air is 21.0 percent O2 by volume. (Hint:use the information that 1.00 L of air at 25 °C and 1.00 atm contains 0.275 g of O2 per liter.)(c) The heat of combustion of propane is −2,219.2 kJ/mol. Calculate the heat of formation, ΔH°f of propane given that ΔH°f  of H2O(l) = −285.8 kJ/mol and ΔH°f  of CO2(g) = −393.5 kJ/mol.                                                  (d) Assuming that all of the heat released in burning 25.0 grams of propane is transferred to 4.00 kilograms of water, calculate the increase in temperature of the water.

Chapter 9 Solutions

Organic Chemistry - Standalone book

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