GENERAL ORGANIC+BIO...(LL)-W/MOD.ACCESS
3rd Edition
ISBN: 9780134466699
Author: FROST
Publisher: PEARSON
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Chapter 9, Problem 1IA.4Q
Summary Introduction
To determine:
The definition of conjugate acid-base pair.
Introduction:
According to Bronsted-Lowry, an acid is the substance that has the ability to donate a proton in the
The species that are formed by removal of proton are known as conjugate acid.
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Br
HO
?
HO
✓
OH
Use the literature Ka value of the acetic acid, and the data below to answer these questions. Note: You will not use the experimental titration graphs to answer the questions that follow.
Group #1:
Buffer pH = 4.35
Group #2:
Buffer pH = 4.70
Group #3:
Buffer pH = 5.00
Group #4:
Buffer pH = 5.30
Use the Henderson-Hasselbalch equation, the buffer pH provided and the literature pKa value of acetic acid to perform the following:
a) calculate the ratios of [acetate]/[acetic acid] for each of the 4 groups buffer solutions above.
b) using the calculated ratios, which group solution will provide the best optimal buffer (Hint: what [acetate]/[acetic acid] ratio value is expected for an optimal buffer?)
c) explain your choice
How would you prepare 1 liter of a 50 mM Phosphate buffer at pH 7.5 beginning with K3PO4 and 1 M HCl or 1 M NaOH? Please help and show calculations. Thank you
Chapter 9 Solutions
GENERAL ORGANIC+BIO...(LL)-W/MOD.ACCESS
Ch. 9 - Prob. 9.1PPCh. 9 - Indicate if each of the following statements is...Ch. 9 - Prob. 9.3PPCh. 9 - Prob. 9.4PPCh. 9 - Prob. 9.5PPCh. 9 - In each of the following equations, identify the...Ch. 9 - Prob. 9.7PPCh. 9 - Prob. 9.8PPCh. 9 - Prob. 9.9PPCh. 9 - Which of the following are strong bases? a....
Ch. 9 - Prob. 9.11PPCh. 9 - Prob. 9.12PPCh. 9 - Prob. 9.13PPCh. 9 - Prob. 9.14PPCh. 9 - Complete and balance the following neutralization...Ch. 9 - Complete and balance the following neutralization...Ch. 9 - Prob. 9.17PPCh. 9 - Complete and balance the following neutralization...Ch. 9 - Prob. 9.19PPCh. 9 - Prob. 9.20PPCh. 9 - Write an equilibrium constant expression lor the...Ch. 9 - Prob. 9.22PPCh. 9 - Prob. 9.23PPCh. 9 - Prob. 9.24PPCh. 9 - Prob. 9.25PPCh. 9 - Sulfur trioxide is produced by reacting sulfur...Ch. 9 - Prob. 9.27PPCh. 9 - Prob. 9.28PPCh. 9 - Prob. 9.29PPCh. 9 - When you exercise, energy is produced by...Ch. 9 - Using Tables 9.1 and 9.6, identity the stronger...Ch. 9 - Using Tables 9.1 and 9.6, identify the stronger...Ch. 9 - Prob. 9.33PPCh. 9 - Identify the acid and base on the reactant side of...Ch. 9 - Prob. 9.35PPCh. 9 - Prob. 9.36PPCh. 9 - Prob. 9.37PPCh. 9 - Write the formula and name of the conjugate acid...Ch. 9 - Complete the following reactions and identify the...Ch. 9 - Complete the following reactions and identify the...Ch. 9 - State if each of the following solutions is...Ch. 9 - State if each of the following solutions is...Ch. 9 - State if each of these following solutions is...Ch. 9 - Slate if each of the following solutions is...Ch. 9 - Calculate the pH of each of the solutions in...Ch. 9 - Calculate the pH of each of the solutions in...Ch. 9 - Calculate the [H3O+] for each of the following...Ch. 9 - Calculate the [H3O+J lor each of the following...Ch. 9 - Prob. 9.49PPCh. 9 - Using Table 9.8, determine the stronger acid from...Ch. 9 - Prob. 9.51PPCh. 9 - Prob. 9.52PPCh. 9 - Prob. 9.53PPCh. 9 - Prob. 9.54PPCh. 9 - Valine has the zwitterion structure shown in the...Ch. 9 - Glycine has the zwitterion structure shown in the...Ch. 9 - Prob. 9.57PPCh. 9 - Prob. 9.58PPCh. 9 - During stress or trauma, a person can start to...Ch. 9 - A person who overdoses on antacids may neutralize...Ch. 9 - Prob. 9.61APCh. 9 - Prob. 9.62APCh. 9 - Prob. 9.63APCh. 9 - What are some ingredients found in antacids? What...Ch. 9 - Prob. 9.65APCh. 9 - Prob. 9.66APCh. 9 - Prob. 9.67APCh. 9 - Prob. 9.68APCh. 9 - For the following reaction, 2HI(g)H2(g)+I2(g) a....Ch. 9 - Prob. 9.70APCh. 9 - Prob. 9.71APCh. 9 - Prob. 9.72APCh. 9 - Prob. 9.73APCh. 9 - Prob. 9.74APCh. 9 - Prob. 9.75APCh. 9 - Prob. 9.76APCh. 9 - Determine the pH for the following solutions....Ch. 9 - Determine the pi! for the following solutions....Ch. 9 - Prob. 9.79APCh. 9 - Prob. 9.80APCh. 9 - Consider the acetic-acid buffer system with acetic...Ch. 9 - Consider the lactic-acid buffer with lactic acid,...Ch. 9 - In blood plasma, pH is maintained by the carbonic...Ch. 9 - Adding a few drops o! a strong add to water will...Ch. 9 - Consider the amino acid valine shown in its...Ch. 9 - Prob. 9.86CPCh. 9 - Prob. 9.87CPCh. 9 - Prob. 9.88CPCh. 9 - Prob. 9.89CPCh. 9 - Naproxen, the active ingredient in Aleve has the...Ch. 9 - To determine the concentration of an unknown weak...Ch. 9 - Explain why the following amino acid cannot exist...Ch. 9 - Prob. 1IA.1QCh. 9 - Prob. 1IA.2QCh. 9 - Prob. 1IA.3QCh. 9 - Prob. 1IA.4QCh. 9 - Prob. 1IA.5QCh. 9 - Provide the a. conjugate base of H2S. _______ b....Ch. 9 - If the lungs fail to expel normal amounts of CO2...Ch. 9 - If the lungs expel CO2 faster than normally...Ch. 9 - Prob. 2IA.3QCh. 9 - Prob. 2IA.4QCh. 9 - Prob. 1ICCh. 9 - Prob. 2ICCh. 9 - Prob. 3IC
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